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ASTM C760-90(2002)

(Test Method)

Standard Test Methods for Chemical and Spectrochemical Analysis of Nuclear-Grade Silver-Indium-Cadmium Alloys

Standard Test Methods for Chemical and Spectrochemical Analysis of Nuclear-Grade Silver-Indium-Cadmium Alloys

SCOPE
1.1 These test methods cover procedures for the chemical and spectrochemical analysis of nuclear grade silver-indium-cadmium (Ag-In-Cd) alloys to determine compliance with specifications.
1.2 The analytical procedures appear in the following order:SectionsSilver, Indium, and Cadmium by a Titration MethodTrace Impurities by Carrier-Distillation Spectro-chemical Method
1.3 The values stated in SI units are to be regarded as the standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard and precautionary statements, see Section 5 and Practices E 50.

General Information

Status
Historical
Publication Date
24-May-1990
ICS
77.040.30 - Chemical analysis of metals
Technical Committee
C26 - Nuclear Fuel Cycle
Drafting Committee
C26.03 - Neutron Absorber Materials Specifications
Current Stage
Ref Project

Relations

Replaces
ASTM C760-90(1996) - Standard Test Methods for Chemical and Spectrochemical Analysis of Nuclear-Grade Silver-Indium-Cadmium Alloys
Effective Date
25-May-1990
Replaced By
ASTM C760-90(2007) - Standard Test Methods for Chemical and Spectrochemical Analysis of Nuclear-Grade Silver-Indium-Cadmium Alloys
Effective Date
01-Jul-2007
Referred By
ASTM C752-18 - Standard Specification for Nuclear-Grade Silver-Indium-Cadmium Alloy
Effective Date
25-May-1990

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ASTM C760-90(2002) - Standard Test Methods for Chemical and Spectrochemical Analysis of Nuclear-Grade Silver-Indium-Cadmium AlloysASTM C760-90(2002) - Standard Test Methods for Chemical and Spectrochemical Analysis of Nuclear-Grade Silver-Indium-Cadmium Alloys
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ASTM C760-90(2002) - Standard Test Methods for Chemical and Spectrochemical Analysis of Nuclear-Grade Silver-Indium-Cadmium Alloys
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:C760–90(Reapproved 2002)
Standard Test Methods for
Chemical and Spectrochemical Analysis of Nuclear-Grade
1
Silver-Indium-Cadmium Alloys
This standard is issued under the fixed designation C760; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope 3. Significance and Use
1.1 These test methods cover procedures for the chemical 3.1 Silver-indium-cadmium alloy is used as a control mate-
and spectrochemical analysis of nuclear grade silver-indium- rial in nuclear reactors. In order to be suitable for this purpose,
cadmium (Ag-In-Cd) alloys to determine compliance with the material must meet the specifications for assay and impu-
specifications. rity content. These test methods are designed to show whether
1.2 Theanalyticalproceduresappearinthefollowingorder: or not a given material meets the specifications as given in
Specification C752.
Sections
Silver, Indium, and Cadmium by a Titration Method 7-15
3.1.1 An assay is performed to determine whether the
Trace Impurities by Carrier-Distillation Spectro- 16-22
material has the chemical composition specified.
chemical Method
3.1.2 The impurity content is determined to ensure that the
1.3 The values stated in SI units are to be regarded as the
maximum concentration limit of impurities is not exceeded.
standard.
1.4 This standard does not purport to address all of the 4. Purity of Reagents
safety concerns, if any, associated with its use. It is the
4.1 Reagent grade chemicals shall be used in all tests.
responsibility of the user of this standard to establish appro-
Unlessotherwiseindicated,itisintendedthatallreagentsshall
priate safety and health practices and determine the applica-
conform to the specifications of the Committee on Analytical
6
bility of regulatory limitations prior to use. For specific hazard
Reagents of the American Chemical Society, where such
andprecautionarystatements,seeSection5andPracticesE50.
specifications are available. Other grades may be used, pro-
vided it is first ascertained that the reagent is of sufficiently
2. Referenced Documents
high purity to permit its use without lessening the accuracy of
2.1 ASTM Standards:
the determination.
C 752 Specification for Nuclear-Grade Silver-
4.2 Purity of Water—Unlessotherwiseindicated,references
2
IndiumCadmium Alloy
towatershallbeunderstoodtomeanreagentwaterconforming
3
D1193 Specification for Reagent Water
to Specification D1193.
E50 Practices forApparatus, Reagents, and Safety Precau-
4
tions for Chemical Analysis of Metals 5. Hazards
E115 Practice for Photographic Processing in Optical
5.1 Properprecautionsshouldbetakentopreventinhalation
4
Emission Spectrographic Analysis
or ingestion of heavy element (silver, indium, or cadmium)
2.2 Other Document:
powder or dust during handling.
5
NBS Circular 602
5.2 Workers should observe precautions as specified in
vendor-supplied Material Safety Data Sheets (MSDS).
6. Sampling
1
These test methods are under the jurisdiction of ASTM Committee C26 on
6.1 Suggestions for sampling this alloy are given in Speci-
Nuclear Fuel Cycle and are the direct responsibility of Subcommittee C26.03 on
Neuron Absorber Materials. fication C752.
Current edition approved May 25, 1990. Published July 1990. Originally
published as C760–71. Last previous edition C760–79.
2 6
Annual Book of ASTM Standards, Vol 12.01. “ReagentChemicals,AmericanChemicalSocietySpecifications,”Am.Chemi-
3
Annual Book of ASTM Standards, Vol 11.01. calSoc.Washington,DC.Forsuggestionsonthetestingofreagentsnotlistedbythe
4
Annual Book of ASTM Standards, Vol 03.05. American Chemical Society, see “Reagent Chemicals and Standards,” by Joseph
5
Available from National Institute of Standards and Technology, Gaithersburg, Rosin, D. Van Nostrand Co., Inc., New York, NY, and the “United States
MD 20899. Pharmacopeia.”
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
C760–90 (2002)
SILVER, INDIUM, AND CADMIUM BY A TITRATION 11.6 Nitric Acid (sp gr 1.42)—Concentrated nitric acid
METHOD (HNO ).
3
11.7 PAN Indicator Solution (0.1% PAN in Methanol)—
7. Scope
Dissolve 100 mg of 1-(2-pyridylazo)-2-naphthol in 100 mLof
methyl alcohol and mix until completely dissolved.
7.1 This test method is applicable to the determination of
11.8 Silver (Ag)—Metal, >99.99% pure.
silver, indium, and cadmium in alloys of approximately 80%
silver, 15% indium, and 5% cadmium used in nuclear reactor 11.9 Sodium Chloride (NaCl).
,
78
11.10 Sodium Chloride Solution (0.0500 M)—Dry sodium
control rod applic
...

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ASTM C760-90(2020)(Test Method)
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SIGNIFICANCE AND USE
3.1 Silver-indium-cadmium alloy is used as a control material in nuclear reactors. In order to be suitable for this purpose, the material must meet the specifications for assay and impurity content. These test methods are designed to show whether or not a given material meets the specifications as given in Specification C752.  
3.1.1 An assay is performed to determine whether the material has the chemical composition specified.  
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1.2 The analytical procedures appear in the following order:    
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Silver, Indium, and Cadmium by a Titration Method  
7 – 15  
Trace Impurities by Carrier-Distillation Spectro-
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16 – 22  
1.3 The values stated in SI units are to be regarded as the standard.  
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4.1 These test methods for the chemical analysis of beryllium metal are primarily intended as referee methods to test such materials for compliance with compositional specifications. It is assumed that all who use these test methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory.
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1.1 These test methods cover the chemical analysis of beryllium having chemical compositions within the following limits:    
Element  
Range, %  
Aluminum  
0.05 to 0.30  
Beryllium  
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Beryllium Oxide  
0.3 to 3    
Carbon  
0.05 to 0.30  
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0.005 to 0.10  
Iron  
0.05 to 0.30  
Magnesium  
0.02 to 0.15  
Nickel  
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Silicon  
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1.2 The test methods in this standard are contained in the sections as follows.    
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Chromium by the Diphenylcarbazide Spectrophotometric Test Method
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10 – 19  
Iron by the 1,10-Phenanthroline Spectrophotometric Test Method
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[0.008 % to 0.04 %]  
30 – 39  
Nickel by the Dimethylglyoxime Spectrophotometric Test Method
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1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Standard Test Methods for Chemical Analysis of Chromium and Ferrochromium

SIGNIFICANCE AND USE
4.1 These test methods for the chemical analysis of chromium metal and ferrochromium alloy are primarily intended to test such materials for compliance with compositional specifications such as Specifications A101 and A481. It is assumed that all who use these test methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory.
SCOPE
1.1 These test methods cover the chemical analysis of chromium and ferrochromium having chemical compositions within the following limits:    
Element  
Composition, %  
Aluminum  
0.25 max  
Antimony  
0.005 max  
Arsenic  
0.005 max  
Bismuth  
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Boron  
0.005 max  
Carbon  
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Chromium  
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Columbium  
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Copper  
0.05 max  
Lead  
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Manganese  
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Molybdenum  
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Nickel  
0.50 max  
Nitrogen  
6.00 max  
Phosphorus  
0.03 max  
Silicon  
12.00 max  
Silver  
0.005 max  
Sulfur  
0.07 max  
Tantalum  
0.05 max  
Tin  
0.005 max  
Titanium  
0.50 max  
Vanadium  
0.50 max  
Zinc  
0.005 max  
Zirconium  
0.05 max  
1.2 The analytical procedures appear in the following order:    
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Arsenic by the Molybdenum Blue Spectrophotometric Test Method
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Lead by the Dithizone Spectrophotometric Test Method
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5.1 This test method for the chemical analysis of metals and alloys is primarily intended to test such materials for compliance with compositional specifications. It is assumed that all who use these test methods will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory.
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1.1 This test method describes the determination of beryllium in copper-beryllium alloys in percentages from 0.1 % to 3.0 % by phosphate gravimetry.  
1.2 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 9.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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4.1 This practice is intended primarily for the sampling of copper and copper alloys for compliance with compositional specification requirements.  
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5.1 This test method for the chemical analysis of metals and alloys is primarily intended to test such materials for compliance with compositional specifications. It is assumed that all those who use this test method will be trained analysts capable of performing common laboratory procedures skillfully and safely. It is expected that work will be performed in a properly equipped laboratory.
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1.3 Included are procedures for elements in the following composition ranges:    
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0.002–0.026  
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Standard Test Method for Analysis of Magnesium and Magnesium Alloys by Atomic Emission Spectrometry

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5.1 The metallurgical properties of magnesium and its alloys are highly dependant on chemical composition. Precise and accurate analyses are essential to obtaining desired properties, meeting customer specifications and helping to reduce scrap due to off-grade material.  
5.2 This test method is applicable to chill cast specimens as defined in Practice B953 and can also be applied to other types of samples provided that suitable reference materials are available.
SCOPE
1.1 This test method describes the analysis of magnesium and its alloys by atomic emission spectrometry. The magnesium specimen to be analyzed may be in the form of a chill cast disk, casting, sheet, plate, extrusion or some other wrought form or shape. The elements covered in the scope of this method are listed in the table below.    
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0.001 to 12.0  
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Cadmium  
0.0001 to 0.05  
Calcium  
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Cerium  
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0.001 to 0.05  
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0.01 to 3.0  
Iron  
0.001 to 0.06  
Lanthanum  
0.01 to 1.5  
Lead  
0.005 to 0.1  
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0.001 to 0.05  
Manganese  
0.001 to 2.0  
Neodymium  
0.01 to 3.0  
Nickel  
0.0005 to 0.05  
Phosphorus  
0.0002 to 0.01  
Praseodymium  
0.01 to 0.5  
Samarium  
0.01 to 1.0  
Silicon  
0.002 to 5.0  
Silver  
0.001 to 0.2  
Sodium  
0.0005 to 0.01  
Strontium  
0.01 to 4.0  
Tin  
0.002 to 0.05  
Titanium  
0.001 to 0.02  
Yttrium  
0.02 to 7.0  
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0.01 to 1.0  
Zinc  
0.001 to 10.0  
Zirconium  
0.001 to 1.0
Note 1: The mass fraction ranges given in the above scope are estimates based on two manufacturers observations and data provided by a supplier of atomic emission spectrometers. The range shown for each element does not demonstrate the actual usable analytical range for that element. The usable analytical range may be extended higher or lower based on individual instrument capability, spectral characteristics of the specific element wavelength being used and the availability of appropriate reference materials.  
1.2 This test method is suitable primarily for the analysis of chill cast disks as described in Sampling Practice B953. Other forms may be analyzed, provided that: (1) they are sufficiently massive to prevent undue heating, (2) they allow machining to provide a clean, flat surface which creates a seal between the specimen and the spark stand, and (3) reference materials of a similar metallurgical condition (spectrochemical response) and chemical composition are available.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific safety and health statements are given in Section 10.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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SIGNIFICANCE AND USE
5.1 The chemical measurement processes covered by this guide are used for determination of Carbon, Sulfur, Nitrogen, Oxygen and Hydrogen in metals, ores and related materials. A test method utilizing this guidance is used to test such materials, and also form the basis for quality assurance of these materials. Thus, it is economically and scientifically critical that these instruments be understood by the laboratories that use them.  
5.2 It is assumed that all who use this guide will be trained analysts, capable of performing common laboratory procedures skillfully, and safely. It is expected that any work will be performed in a properly equipped laboratory.  
5.3 It is expected that the laboratory will prepare their own work procedures for any of the information described in this guide.  
5.4 This guide contains numerous references to “manufacturer’s recommendations”. The user of this guide is expected to refer to the instrument operation manual for the specific instrument being used or consult directly with the manufacturer to obtain instructions or recommendations.  
5.5 This guide stresses the conservation of certified reference materials (CRMs). CRMs should not be used for drift checks or conditioning measurments. Other materials should be developed and used for these operations.
SCOPE
1.1 This guide covers information for using Combustion, Inert Gas Fusion and Hot Extraction instruments to determine the mass fraction of the non-metallic elements Carbon, Sulfur, Nitrogen, Oxygen and Hydrogen in metals, ores and related materials.  
1.2 This guide does not specify all the operating conditions because of the differences among different manufacturer’s instruments. Laboratories should follow instructions provided by the manufacturer of the instrument.  
1.3 Units—The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 The information in this guide is contained in the sections indicated as follows:    
Sections  
Carbon/Sulfur by Combustion/Infrared Detection  
14 – 19  
Nitrogen/Oxygen by Inert Gas Fusion/Thermal Conductivity and Infrared Detection  
20 – 25  
Hydrogen by Inert Gas Fusion Instrumental Measurement and Hot Extraction/Various Detection Cell Technology  
26 – 31  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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Standard Test Method for Analysis of Low-Alloy Steels by Wavelength Dispersive X-Ray Fluorescence Spectrometry

SIGNIFICANCE AND USE
5.1 This test method is suitable for manufacturing control and for verifying that a product meets specifications. This test method provides rapid, multi-element determinations with sufficient accuracy to ensure product quality and to minimize production delays. The analytical performance data may be used as a benchmark to determine if similar X-ray spectrometers provide equivalent precision and accuracy, or if the performance of a particular X-ray spectrometer has changed.  
5.2 Calcium is sometimes added to steel to affect inclusion shape which enhances certain mechanical properties of steel. This test method is useful for determining the residual calcium in the steel after such treatment.  
5.2.1 Because calcium occurs primarily in inclusions, the precision of this test method is a function of the distribution of the calcium-bearing inclusions in the steel. The variation of determinations on freshly prepared surfaces will give some indication of the distribution of these inclusions.
SCOPE
1.1 This test method covers the wavelength dispersive X-ray fluorescence analysis of low-alloy steels for the following elements:    
Element  
Mass Fraction
Range, %  
Calcium  
0.001 to 0.007  
Chromium  
0.04 to 2.5  
Cobalt  
0.03 to 0.2  
Copper  
0.03 to 0.6  
Manganese  
0.04 to 2.5  
Molybdenum  
0.005 to 1.5  
Nickel  
0.04 to 3.0  
Niobium  
0.002 to 0.1  
Phosphorus  
0.010 to 0.08  
Silicon  
0.06 to 1.5  
Sulfur  
0.009 to 0.1  
Vanadium  
0.012 to 0.6  
1.1.1 Unless exceptions are noted, mass fraction ranges can be extended and additional elements can be included by the use of suitable reference materials and measurement conditions. Deviations from the published scope must be validated by experimental means. See Guide E2857 for information on validation options.  
1.2 The values stated in the International System of Units (SI) are to be regarded as standard. The values given in parentheses are mathematical conversions to other units that are provided for information only, because they may be used in older software and laboratory procedures.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 10.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
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  • Standard
    6 pages
    English language
    sale 15% off