Standard Practice for Chemical Protective Clothing Program

SIGNIFICANCE AND USE
This practice presents those elements that constitute a chemical protective clothing (CPC) program and conditions to be used in establishing a program for the selection and use of CPC. Adherence to this practice requires that a written program be developed for any use of CPC.
Although much remains to be determined regarding the toxicity of vapor and liquid exposure to the skin, this practice outlines the essential information necessary and suggested methods for hazard assessment prior to the selection of CPC (see Practice F 1154).
This practice does not address the various methods for testing CPC or obtaining the data upon which CPC assessments are made. These test methods are listed in Section 2 of this practice.
This practice does not include recommendations that may apply to personal protection from nuclear radiation, radioactive contamination, or microbiological organisms, or to clothing that is worn to protect a particular environment from the entry of chemicals, particles, or living matter that may arise from the wearer.
CPC should be used when other means of control are not available. Its major uses should be limited to the following:
4.5.1 Maintenance operations;
4.5.2 Upset or emergency conditions;
4.5.3 Use in lieu of engineering controls when they are not feasible or are being installed;
4.5.4 Supplementing feasible engineering controls when they fail to control the hazard completely; and
4.5.5 Use in the event that engineering controls fail.
Engineering controls and substitution of materials should be stressed as the first line of defense in all control situations since effective use of CPC depends on worker compliance, proper selection, quality control, and other variables that may prove to be weak links in an overall control process.
SCOPE
1.1 This practice is intended to promote the proper selection, use, maintenance, and understanding of the limitations of chemical protective clothing (CPC) by users, employers, employees, and other persons involved in programs requiring CPC, thereby limiting potentially harmful and unnecessary skin exposures.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

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Publication Date
31-Jan-2007
Current Stage
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:F1461–07
Standard Practice for
1
Chemical Protective Clothing Program
This standard is issued under the fixed designation F1461; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 3.1.1 analytical detection limit, n—a number, expressed in
units of concentration (or amount), that describes the lowest
1.1 This practice is intended to promote the proper selec-
concentration level (or amount) that an analyst can determine
tion, use, maintenance, and understanding of the limitations of
to be different from an analytical blank (background level).
chemical protective clothing (CPC) by users, employers, em-
3.1.2 biological monitoring, n—the chemical analysis of
ployees, and other persons involved in programs requiring
chemicals or metabolites, or both, from a worker’s blood,
CPC, thereby limiting potentially harmful and unnecessary
urine, fingernails, sweat, breath, and so forth.
skin exposures.
3.1.3 buddy system, n—a means of organizing employee
1.2 This standard does not purport to address all of the
work groups whereby each participant is matched with another
safety concerns, if any, associated with its use. It is the
so that prompt assistance can be rendered in the case of any
responsibility of the user of this standard to establish appro-
emergency.
priate safety and health practices and determine the applica-
3.1.4 chemical protective clothing (CPC), n—any material
bility of regulatory limitations prior to use.
or combination of materials used in an item of clothing or the
2. Referenced Documents purpose of isolating parts of the body from direct contact with
2
a potentially hazardous chemical.
2.1 ASTM Standards:
3.1.5 decontamination, n—removal or neutralization of a
F739 Test Method for Permeation of Liquids and Gases
contaminant(s) from the protective clothing to the extent
through Protective Clothing Materials under Conditions of
necessary to safely permit the protective clothing to be doffed
Continuous Contact
(taken off), or reused, or disposed of.
F903 Test Method for Resistance of Materials Used in
3.1.6 elastomer, n—a term often used for rubber and poly-
Protective Clothing to Penetration by Liquids
mers that have properties similar to rubber.
F1001 Guide for Selection of Chemicals to Evaluate Pro-
3.1.7 fabric, n—a planar structure consisting of yarns or
tective Clothing Materials
fibers.
F1052 Test Method for Pressure Testing Vapor Protective
3.1.7.1 Discussion—Unlike a polymer sheet, a fabric is
Suits
normally subject to penetration by gases and liquids.
F1154 Practices for Qualitatively Evaluating the Comfort,
3.1.8 Fick’s laws of diffusion, n—mathematical descriptions
Fit, Function, and Integrity of Chemical-Protective Suit
of the movement of one type of molecule through another.
Ensembles
3.1.8.1 Discussion—Diffusionisnotduetoholesorporesin
F1194 Guide for Documenting the Results of Chemical
CPC.
Permeation Testing of Materials Used in Protective Cloth-
3.1.9 hazard assessment, n—the determination of the lack
ing
of safety or degree of risk based on all integral parts of an
3. Terminology
exposure situation, including the characteristics of the chemi-
cal(s) to which one is exposed and the conditions that deter-
3.1 Definitions of Terms Specific to This Standard:
mine degree of exposure.
3.1.10 industrial hygienist, n—a person who, by experience
1
This practice is under the jurisdiction of ASTM Committee F23 on Personal
and academic training, is qualified to recognize, evaluate, and
Protective Clothing and Equipment and is the direct responsibility of Subcommittee
control chemical, physical, and biological agents in the work-
F23.30 on Chemicals.
Current edition approved Feb. 1, 2007. Published February 2007. Originally place, or a person certified by theAmerican Board of Industrial
´1
approved in 1993. Last previous edition approved in 2005 as F1461 - 93 (2005) .
Hygiene.
DOI: 10.1520/F1461-07.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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F1461–07
3.1.11 occlusion, n—the physical process of covering a 4.5.4 Supplementing feasible engineering controls when
chemicalthathasbeenappliedtoorspilledontheskin,thereby they fail to control the hazard completely; and
disallowingitsevaporationandgenerallyincrea
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