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ASTM D5394-02(2007)

(Specification)

Standard Specification for Reclaimed 1,1,1-Trichloroethane

Standard Specification for Reclaimed 1,1,1-Trichloroethane

ABSTRACT
This specification defines reclaimed 1,1,1-trichloroethane, also known commercially as methyl chloroform. The types are defined: Type I - high quality reclaimed 1,1,1-trichloroethane, approximating MIL Specification; Type II - good quality reclaimed solvent; and Type III - minimal acceptable reclaimed solvent. The solvent shall be subject to tests for amine acid acceptance or alkalinity, color and appearance, nonvolatile matter content, total acid acceptance, aluminum scratch, water-soluble halide ion content, acidity-alkalinity, and water content.
SCOPE
1.1 This specification defines Type I (high quality reclaimed 1,1,1-trichloroethane, approximating MIL Specification), Type II (good quality reclaimed solvent), Type III (minimal acceptable reclaimed solvent).
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific hazards statement see Section 4.
1.2 1,1,1-trichloroethane also is known commercially as methyl chloroform.

General Information

Status
Historical
Publication Date
31-Jan-2007
ICS
71.080.20 - Halogenated hydrocarbons
Technical Committee
D26 - Halogenated Organic Solvents and Fire Extinguishing Agents
Drafting Committee
D26.02 - Vapor Degreasing
Current Stage
Ref Project

Relations

Replaces
ASTM D5394-02 - Standard Specification for Reclaimed 1,1,1-Trichloroethane
Effective Date
01-Feb-2007
Replaced By
ASTM D5394-02(2012) - Standard Specification for Reclaimed 1,1,1-Trichloroethane (Withdrawn 2017)
Effective Date
01-Mar-2012

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ASTM D5394-02(2007) - Standard Specification for Reclaimed 1,1,1-TrichloroethaneASTM D5394-02(2007) - Standard Specification for Reclaimed 1,1,1-Trichloroethane
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ASTM D5394-02(2007) - Standard Specification for Reclaimed 1,1,1-Trichloroethane
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Standards Content (Sample)


NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D5394 – 02 (Reapproved 2007)
Standard Specification for
Reclaimed 1,1,1-Trichloroethane
This standard is issued under the fixed designation D5394; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
TABLE 1 Properties, Type I
1. Scope
Property Specification Test Method
1.1 This specification definesType I (high quality reclaimed
Appearance Free of turbidity and D3741
1,1,1-trichloroethane, approximating MIL Specification), Type
suspended matter
II (good quality reclaimed solvent), Type III (minimal accept-
1,1,1-trichloroethane, weight %, 92 D6806
able reclaimed solvent).
min
Nonvolatile residue, weight 0.0040 D2109
1.2 This standard does not purport to address all of the
%, max
safety concerns, if any, associated with its use. It is the
Color, Pt-Co, max 25 D2108
responsibility of the user of this standard to establish appro-
Water, weight %, max 0.015 D3401
Acid acceptance as NaOH, weight 0.20 D2942
priate safety and health practices and determine the applica-
%, min
bility of regulatory limitations prior to use. For a specific
A
Aluminum scratch test Passes D2943
hazards statement see Section 4. Acidity as HCl, weight %, max 0.001 D2989
Alkalinity as NaOH, weight %, max 0.020 D2106
1.3 1,1,1-trichloroethane also is known commercially as
Halide as Cl, weight %, max 0.0005 D2988
methyl chloroform.
A
Distill 100 mL solvent, collect 50 mL distillate, and conduct scratch test on
distillate and portion remaining in distillation flask.
2. Referenced Documents
2.1 ASTM Standards:
vents and Their Admixtures by Gas Chromatography
D2106 Test Methods for Determination of Amine Acid
2.2 Other Documents:
Acceptance (Alkalinity) of Halogenated Organic Solvents
STP-310A Handbook of Vapor Degreasing
D2108 Test Method for Color of Halogenated Organic
STP-403A Cold Cleaning with Halogenated Solvents
Solvents and Their Admixtures (Platinum-Cobalt Scale)
D2109 Test Methods for Nonvolatile Matter in Halogenated
3. Properties
Organic Solvents and Their Admixtures
3.1 Reclaimed 1,1,1-trichloroethane, Type I, shall conform
D2942 Test Method for Total Acid Acceptance of Haloge-
to the requirements of Table 1.
nated Organic Solvents (Nonreflux Methods)
3.2 Reclaimed 1,1,1-trichloroethane, Type II, shall conform
D2943 Test Method for Aluminum Scratch of 1,1,1-
to the requirements of Table 2. See STP-310A.
Trichloroethane to Determine Stability
3.3 Reclaimed 1,1,1-trichloroethane, Type III, shall con-
D2988 Test Methods for Water-Soluble Halide Ion in Ha-
form to the requirements of Table 3. See STP-403A.
logenated Organic Solvents and Their Admixtures
3.4 This specification does not address the possibility of
D2989 Test Method for Acidity-Alkalinity of Halogenated
product flash points due to the presence of flammable constitu-
Organic Solvents and Their Admixtures
ents. However, flash point must be determined for proper
D3401 Test Methods for Water in Halogenated Organic
labeling and shipment. The Tag closed-cup procedure is
Solvents and Their Admixtures
recommended.
D3741 Test Methods for Appearance of Admixtures Con-
3.5 Specific gravity for these grades typically will be
taining Halogenated Organic Solvents
between 1.25 and 1.37.
D6806 Practice for Analysis of Halogenated Organic Sol-
4. Hazards
4.1 Due to the possible presence of low level foreign
This specification is under the jurisdiction of ASTM Committee D26 on
Halogenated Organic Solvents and Fire Extinguishing Agents and is the direct
contaminants in reclaimed 1,1,1-trichloroethane, th
...

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