ASTM B708-12(2019)

Standard Specification for Tantalum and Tantalum Alloy Plate, Sheet, and Strip

ABSTRACT
This specification covers the standard requirements for tantalum and tantalum alloy plate, sheet, and strip in the following grades: R05200, R05400, R05255, R05252, and R05240. The various tantalum mill products covered by this specification shall be formed with the conventional extrusion, forging, and rolling equipment normally available in metal working plants. Materials shall be made from vacuum-arc or electron-beam melted ingots or powder metallurgy consolidated unalloyed tantalum and shall be supplied in the annealed condition. Chemical analysis shall be conducted to determine the chemical composition of the materials which shall conform to the requirements for carbon, oxygen, nitrogen, hydrogen, iron, molybdenum, niobium, nickel, silicon, titanium, tungsten, and tantalum. The mechanical properties of the materials shall also meet the specified tensile strength, yield strength, and elongation limits as shall be determined by a longitudinal or transverse tension test method.
SCOPE
1.1 This specification covers unalloyed and alloyed tantalum plate, sheet, and strip as follows.  
1.1.1 R05200, unalloyed tantalum, electron-beam furnace or vacuum-arc melt, or both,  
1.1.2 R05400, unalloyed tantalum, powder-metallurgy consolidation,  
1.1.3 R05255, tantalum alloy, 90 % tantalum, 10 % tungsten, electron-beam furnace of vacuum-arc melt, or both,  
1.1.4 R05252, tantalum alloy, 97.5 % tantalum, 2.5 % tungsten, electron-beam furnace or vacuum-arc melt, or both, and  
1.1.5 R05240, tantalum alloy, 60 % tantalum, 40 % niobium, electron-beam furnace or vacuum-arc melt.  
1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.3 This standard does not purport to address all of the safety and/or health problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

• Status: Published
• Publication Date: 31-Oct-2019
• ICS: 77.150.99 - Other products of non-ferrous metals
• Technical Committee: B10 - Reactive and Refractory Metals and Alloys
• Drafting Committee: B10.03 - Niobium, Tantalum, and Vanadium

Relations

• Replaces: ASTM B708-12 - Standard Specification for Tantalum and Tantalum Alloy Plate, Sheet, and Strip
• Effective Date: 01-Nov-2019
• Refers: ASTM E112-12 - Standard Test Methods for Determining Average Grain Size
• Effective Date: 15-Nov-2012
• Refers: ASTM E112-10 - Standard Test Methods for Determining Average Grain Size
• Effective Date: 01-Nov-2010
• Refers: ASTM E29-08 - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 01-Oct-2008
• Refers: ASTM E29-06b - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 15-Nov-2006
• Refers: ASTM E112-96(2004)e2 - Standard Test Methods for Determining Average Grain Size
• Effective Date: 23-Oct-2006
• Refers: ASTM E29-06a - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 15-Sep-2006
• Refers: ASTM E29-06 - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 01-May-2006
• Refers: ASTM E29-04 - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 01-Dec-2004
• Refers: ASTM E112-96(2004) - Standard Test Methods for Determining Average Grain Size
• Effective Date: 01-Nov-2004
• Refers: ASTM E112-96(2004)e1 - Standard Test Methods for Determining Average Grain Size
• Effective Date: 01-Nov-2004
• Refers: ASTM E8-04 - Standard Test Methods for Tension Testing of Metallic Materials
• Effective Date: 01-Apr-2004
• Refers: ASTM E8-03 - Standard Test Methods for Tension Testing of Metallic Materials
• Effective Date: 10-Jul-2003
• Refers: ASTM E29-02e1 - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
• Effective Date: 10-May-2002
• Refers: ASTM E8-00b - Standard Test Methods for Tension Testing of Metallic Materials
• Effective Date: 10-Oct-2001

Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation:B708 −12 (Reapproved 2019)
Standard Specification for
Tantalum and Tantalum Alloy Plate, Sheet, and Strip
This standard is issued under the fixed designation B708; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope E8 Test Methods for Tension Testing of Metallic Materials
[Metric] E0008_E0008M
1.1 This specification covers unalloyed and alloyed tanta-
E29 Practice for Using Significant Digits in Test Data to
lum plate, sheet, and strip as follows.
Determine Conformance with Specifications
1.1.1 R05200, unalloyed tantalum, electron-beam furnace
E112 Test Methods for Determining Average Grain Size
or vacuum-arc melt, or both,
1.1.2 R05400, unalloyed tantalum, powder-metallurgy
3. Terminology
consolidation,
1.1.3 R05255, tantalum alloy, 90 % tantalum, 10 %
3.1 Definitions of Terms Specific to This Standard:
tungsten, electron-beam furnace of vacuum-arc melt, or both,
3.1.1 annealed material, n—plate, sheet, or strip that has
1.1.4 R05252, tantalum alloy, 97.5 % tantalum, 2.5 %
been annealed.
tungsten, electron-beam furnace or vacuum-arc melt, or both,
3.1.2 annealing (annealed), n—the act of heat treating to
and
soften plate, sheet, or strip.
1.1.5 R05240, tantalum alloy, 60 % tantalum, 40 %
3.1.3 lot, n—all material produced from the same ingot or a
niobium, electron-beam furnace or vacuum-arc melt.
single powder blend at one time with the same cross section,
1.2 The values stated in inch-pound units are to be regarded
and with the same nominal metallurgical parameters.
as standard. The values given in parentheses are mathematical
3.1.4 plate, n—a flat product more than 0.1853 in. (4.7 mm)
conversions to SI units that are provided for information only
in thickness.
and are not considered standard.
3.1.5 sheet, n—a flat product 6 in. (152.4 mm) or more in
1.3 This standard does not purport to address all of the
width and from 0.005 in. (0.13 mm) to 0.1875 in. (4.76 mm) in
safety and/or health problems, if any, associated with its use. It
thickness.
is the responsibility of the user of this standard to establish
3.1.6 strip, n—a flat product, may be supplied in coil, less
appropriate safety, health, and environmental practices and
than 6 in. (152.4 mm) in width and from 0.005 in. (0.13 mm)
determine the applicability of regulatory limitations prior to
to 0.1875 in. (4.76 mm) in thickness.
use.
1.4 This international standard was developed in accor-
4. Classifications
dance with internationally recognized principles on standard-
ization established in the Decision on Principles for the
4.1 The strip, sheet or plate is to be furnished in the
Development of International Standards, Guides and Recom-
following grades:
mendations issued by the World Trade Organization Technical
4.1.1 R05200, unalloyed tantalum, electron-beam furnace
Barriers to Trade (TBT) Committee.
or vacuum-arc melted, or both,
4.1.2 R05400, unalloyed tantalum, powder-metallurgy
2. Referenced Documents
consolidation,
2.1 ASTM Standards:
4.1.3 R05255, tantalum alloy, 90 % tantalum, 10 %
tungsten, electron-beam furnace or vacuum-arc melted, or
both,
This specification is under the jurisdiction of ASTM Committee B10 on 4.1.4 R05252, tantalum alloy, 97.5 % tantalum, 2.5 %
Reactive and Refractory Metals and Alloys and is the direct responsibility of
tungsten, electron-beam furnace or vacuum-arc melted, or
Subcommittee B10.03 on Niobium and Tantalum.
both,
Current edition approved Nov. 1, 2019. Published November 2019. Originally
4.1.5 R05240, tantalum alloy, 60 % tantalum, 40 %
approved in 1982. Last previous edition approved in 2012 as B708 – 12. DOI:
10.1520/B0708-12R19.
niobium, electron-beam furnace or vacuum-arc melted, or
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
both.
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
4.1.6 For sputtering application see supplemental require-
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. ments to grades R05200 and R05400.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
B708−12 (2019)
5. Ordering Information 7.2 The manufacturer’s ingot (or powder metallurgy con-
solidated bar) analysis may be considered the chemical analy-
5.1 Orders for material under this specification shall include
sis for products supplied under this specification. Alternately,
the following information as applicable:
an analysis of a representative sample of in-process material
5.1.1 Quantity (weight, number of pieces or other suitable
(or the final product) from the same ingot may be substituted.
measure of quantity),
5.1.2 Name of material (tantalum plate, sheet, or strip),
7.3 When requested by the purchaser at the time of
5.1.3 Grade (alloy and method of manufacture) (see 4.1.1 –
purchase, the seller shall furnish a report certifying the values
4.1.6),
of carbon, oxygen, nitrogen, and hydrogen of the finished
5.1.4 ASTM Standard (Specification B708) and year of
productasspecifiedinTable2foreachlotofmaterialsupplied.
issue, and
The performance of this special provision shall be negotiated.
5.1.5 Additions to the specification and supplementary re-
quirements if required.
8. Mechanical Properties
6. Materials and Manufacture
8.1 Annealed materials supplied under this specification
6.1 Material covered by this specification shall be made shall conform to the requirements for mechanical properties as
from vacuum-arc melted or electron-beam melted ingots or
specified in Table 3. No mechanical property requirements for
powder metallurgy consolidated unalloyed tantalum. unannealed (not heat treated) plate, sheet, or strip have been
established by this specification. Unless otherwise specified,
6.2 The various tantalum mill products covered by this
material supplied under this specification will be supplied in
specification are formed with the conventional extrusion,
the annealed condition.
forging, and rolling equipment normally available in metal
working plants.
9. Metallurgical Properties
6.3 All material shall be supplied in the annealed condition
unless otherwise specified by the purchaser.
9.1 Unless otherwise stated, the materials supplied under
6.3.1 If specified on the purchase order, the material can be
these specifications shall be in the fully annealed condition.
supplied in the “fully recrystallized” condition. In this case the
9.2 Other conditions, such as cold-worked or stress-
plate, sheet, strip, or foil shall be 90 % minimum recrystallized
relieved, can be specified as agreed upon between the pur-
as measured in accordance with 16.3. The terms “fully
chaser and the manufacturer at the time of the purchase.
annealed,” “completely,” and other similar terms shall be
considered the same as “fully recrystallized.”
10. Special Requirements
7. Chemical Composition
10.1 None specified.
7.1 The tantalum and tantalum alloy ingots and the tantalum
powder metallurgy consolidated ingots for conversion to fin-
11. Significance of Numerical Limits
ished products covered by this specification shall conform to
11.1 For the purpose of determining compliance with the
the requirements for chemical composition as prescribed in
specified limits for requirements of the properties listed in the
Table 1.
following table, an observed value or a calculated value shall
7.1.1 Analysis for elements not listed in Table 1 and not
normally expected in tantalum shall not be required unless be rounded as indicated in accordance with the rounding
specified at time of purchase. methods of Practice E29.
TABLE 1 Chemical Requirements
Content, max, weight %
Electron-Beam Electron-Beam
Electron Beam Cast
Electron-Beam Cast Sintered Cast (R05255) Cast (R05252)
(R05240) Vacuum-Arc
(R05200) Vacuum-Arc (R05400) Vacuum-Arc Vacuum-Arc Cast
Element Cast (R05240) 60 %
Cast (R05200) Unalloyed Cast (R05255) (R05252) 97.5 %
Tantalum 40 %
Unalloyed Tantalum Tantalum 90 % Tantalum Tantalum 2.5 %
Niobium
10 % Tungsten Tungsten
C 0.010 0.010 0.010 0.010 0.010
O 0.015 0.03 0.015 0.015 0.020
N 0.010 0.010 0.010 0.010 0.010
H 0.0015 0.0015 0.0015 0.0015 0.0015
Fe 0.010 0.010 0.010 0.010 0.010
Mo 0.020 0.020 0.020 0.020 0.020
Nb 0.100 0.100 0.100 0.50 35.0–42.0
Ni 0.010 0.010 0.010 0.010 0.010
Si 0.005 0.005 0.005 0.005 0.005
Ti 0.010 0.010 0.010 0.010 0.010
W 0.05 0.05 9.0–11.0 2.0–3.5 0.050
Ta remainder remainder remainder remainder remainder
B708−12 (2019)
TABLE 2 Additional Chemical Requirements for Finished Product (When Specified by the Purchaser)
Content, max, weight %
Electron-Beam Electron Beam
Electron-Beam Cast
Electron-Beam Cast Cast (R05252) Cast (R05240)
(R05255) Vacuum-
(R05200) Vacuum- Sintered (R05400) Vacuum-Arc Cast Vacuum-Arc Cast
Element Arc Cast (R05255)
Arc Cast (R05200) Unalloyed Tantalum (R05252) (R05240) 60 %
90 % Tantalum 10 %
Unalloyed Tantalum 97.5 % Tantalum Tantalum 40 %
Tungsten
2.5 % Tungsten Niobium
O 0.025 0.035 0.025 0.025 0.025
N 0.010 0.010 0.010 0.010 0.010
H 0.0015 0.0015 0.0015 0.0015 0.0015
C 0.020 0.020 0.020 0.020 0.020
TABLE 3 Mechanical Properties for Annealed Plate, Sheet, and Strip
Annealed Condition
Grade and Form
Ultimate Tensile Strength, Yield Strength, min, psi Elongation, min, %
min, psi (MPa) (MPa) (2 % Offset) (1-in. Gage Length)
Unalloyed tantalum
(R05200)
(R05400)
Plate, sheet and strip
<0.060 in. thick 30 000 (207) 20 000 (138) 20
$0.060 in. thick 25 000 (172) 15 000 (103) 30
90 % tantalum –
10 % tungsten
(R05255)
Sheet and strip 70 000 (482) 60 000 (414) 15
Plate 70 000 (482) 55 000 (379) 20
97.5 % tantalum –
2.5 % tungsten
(R05252)
<0.125 in. thick 40 000 (276) 30 000 (207) 20
$0.125 in. thick 40 000 (276) 22 000 (152) 25
60 % tantalum –
40 % niobium
(R05240)
<0.060 in. thick 35 000 (241) 20 000 (138) 25
$0.060 in. thick 35 000 (241) 15 000 (103) 25
TABLE 4 Dimensional Tolerances for Tantalum Sheet and Plate
A B
Tolerance on Thickness, plus or Tolerance on Width (Slit), Tolerance on Sheared Lengths,
minus, in. (mm) plus or minus, in. (mm)
in. (mm)
Thickness of
Tantalum in. Width under 6 in Width6to24in. Width under 6 in. Width6to24in. Length 12 in. (304.8 Length over 12 in.
(mm) (152.4 mm) (152.4 to 609.6 mm) (152.4 mm) (152.4 to 609.6 mm) mm) and Under (304.8 mm)
Plus Minus Plus Minus
1 1
0.0051 to 0.010 0.0005 (0.0127) 0.012 (0.305) ⁄16 0 ⁄4 0
(0.129 to 0.254) (1.59) (6.35)
1 1
0.011 to 0.015 0.0007 (0.0178) 0.001 (0.0254) 0.015 (0.381) 0.015 (0.381) ⁄16 0 ⁄4 0
(0.279 to 0.381) (1.59) (6.35)
1 1
0.016 to 0.020 0.0008 (0.0203) 0.0015 (0.0381) 0.015 (0.381) 0.015 (0.381) ⁄16 0 ⁄4 0
(0.406 to 0.508) (1.59) (6.35)
1 1
0.021 to 0.030 0.0015 (0.0381) 0.0025 (0.0635) 0.020 (0.508) 0.025 (0.635) ⁄16 0 ⁄4 0
(0.533 to 0.762) (1.59) (6.35)
1 1
0.031 to 0.060 0.0025 (0.0635) 0.0035 (0.0889) 0.025 (0.635) 0.030 (0.762) ⁄16 0 ⁄4 0
(0.787 to 1.524) (1.59) (6.35)
1 1
0.061 to 0.090 0.004 (0.1016) 0.005 (0.1270) 0.025 (0.635) 0.035 (0.889) ⁄16 0 ⁄4 0
(1.549 to 2.286) (1.59) (6.35)
1 1
0.091 to 0.125 0.006 (0.1524) 0.007 (0.1778) . . ⁄16 0 ⁄4 0
(2.311 to 3.175) (1.59) (6.35)
1 1
0.126 to 0.187 0.010 (0.2540) 0.010 (0.2540) . . ⁄16 0 ⁄4 0
(3.200 to 4.750) (1.59) (6.35)
A
Tolerance on thickness of sheet over 24 in. (609.6 mm) wide shall be ±10 % of the thickness.
B
Tolerance on width of sheared sheet shall be + ⁄4 in. (6.35 mm), − 0 in. (0 mm).
B708−12 (2019)
14. Workmanship and Appearance
Rounded Unit for Observed
Property
or Calculated Value
14.1 Cracks, seams, slivers, blisters, burrs, and other inju-
Chemical composition, and nearest unit in the last right-hand place of
tolerances (when expressed as figures of the specified limit
rious imperfections shall not exceed standards of acceptability
decimals)
agreed upon by the manufacturer and the purchaser.
Tensile strength and yield nearest 1000 psi (10 MPa)
strength
14.2 Finishedstrip,sheet,andplateshallbefreeofinjurious
Elongation nearest 1 %
internal and external imperfections of a nature that will
interfere with the purpose for which it was intended.
12. Permissible Variations in Dimensions
12.1 Thickness—The variation in thickness of strip, sheet, 14.3 Thefinishedstrip,sheet,orplateshallbevisiblyfreeof
oxide, grease, oil, residual lubricants, and other extraneous
and plate is given in the following table:
materials.
12.1.1 Plate, Sheet and Strip, Table 4.
12.2 Width—The variation in width is give in the following 14.4 Methods of testing for these defects and standards of
table:
acceptabilityshallbeasagreeduponbetweenthemanufacturer
12.2.1 Plate, Sheet and Strip, Table 4. and the purchaser.
12.3 Length—The variation in length is given in the follow-
14.5 The manufacturer shall be permitted to remove surface
ing table:
imperfections provided such removal does not reduce any
12.3.1 Plate, Sheet and Strip, Table 4.
dimension below the minimum permitted by the tolerances for
that dimension.
12.4 Flatness—The permissible variation from a flat sur-
face.
15. Number of Tests and Results
12.4.1 The flatness tolerance for sheet and plate products
supplied under this specification shall be a maximum of 6 % as
15.1 Unless otherwise specified one sample per lot shall be
determined by the procedure in Fig. 1.
sufficient for conformance to this specification.
12.5 Quantity or Weight:
15.2 If mechanical testing is required (see 8.1), perform a
12.5.1 For orders requiring up to 100 lb (45.4 kg), the
longitudinal or transverse tension test on each lot of material.
manufacturer may overship by 10 %. When the order is for
15.3 If end-product chemical tests are required (see 7.3),
guarantees up to 500 lb (226.8 kg), the manufacturer may
one chemical test from each lot of finished product shall be
overship an order by 5 %. The permissible overshipment for
performed.
quantities larger than this shall be negotiated between the
purchaser and the manufacturer.
15.4 If any sample or specimen exhibits obvious surface
contamination or improper preparation, disqualifying it as a
13. Condition and Finish
truly representative sample, it shall be discarded and a new
13.1 None specified. sample or specimen substituted.
H = maximum distance between flat surface and lower surface of sheet.
L = minimum distance between highest point on sheet and point of contact with flat surface.
Flatness, percent = (H/L) × 100
FIG. 1Plate and Sh
...