Standard Test Method for Specific Gravity of Soil Solids by Gas Pycnometer

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1.1 This test method covers the determination of the specific gravity of soil solids by means of a gas pycnometer. Particle size is limited by the dimensions of the specimen container of the particular pycnometer being used.
1.2 Test Method D854 may be used instead of or in conjunction with this test method for performing specific gravity tests on soils. Note that Test Method D854 does not require the specialized test apparatus needed by this test method. However, Test Method D854 may not be used if the specimen contains matter that can readily dissolve in water, whereas this test method does not have that limitation.
1.3 The values stated in acceptable SI units are to be regarded as the standard. The inch-pound units given in parentheses are for information only.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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ASTM D5550-94 - Standard Test Method for Specific Gravity of Soil Solids by Gas Pycnometer
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NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: D 5550 – 94
AMERICAN SOCIETY FOR TESTING AND MATERIALS
100 Barr Harbor Dr., West Conshohocken, PA 19428
Reprinted from the Annual Book of ASTM Standards. Copyright ASTM
Standard Test Method for
Specific Gravity of Soil Solids by Gas Pycnometer
This standard is issued under the fixed designation D 5550; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope volume of solids to the mass in air of an equal volume of
distilled water at a temperature of 4°C (in accordance with
1.1 This test method covers the determination of the specific
Terminology D 653).
gravity of soil solids by means of a gas pycnometer. Particle
size is limited by the dimensions of the specimen container of
NOTE 1—Distilled water at a temperature of 4°C has a density of 1.000
the particular pycnometer being used.
g/cm . It is recommended that this test method be performed at or near
room temperature. The temperature at which the soil volume is measured
1.2 Test Method D 854 may be used instead of or in
can be reported but is not required by this test method because of the
conjunction with this test method for performing specific
negligible effect of temperature on the volume of soil solids. However,
gravity tests on soils. Note that Test Method D 854 does not
temperature may have a significant effect on performance of the gas
require the specialized test apparatus needed by this test
pycnometer. Therefore, testing should be conducted within the specified
method. However, Test Method D 854 may not be used if the
operating temperature range of the apparatus.
specimen contains matter that can readily dissolve in water,
4. Summary of Test Method
whereas this test method does not have that limitation.
1.3 The values stated in acceptable SI units are to be
4.1 This test method is used to determine the specific
regarded as the standard. The inch-pound units given in
gravity of soil grains using a gas pycnometer. This test method
parentheses are for information only.
also contains equations for correcting the initial specific gravity
1.4 This standard does not purport to address all of the
value for dissolved matter within the pore fluid.
safety concerns, if any, associated with its use. It is the
5. Significance and Use
responsibility of the user of this standard to establish appro-
priate safety and health practices and determine the applica-
5.1 The specific gravity value is used in many phase relation
bility of regulatory limitations prior to use.
equations to determine relative volumes of particle, water, and
gas mixtures.
2. Referenced Documents
5.2 The term soil particle typically refers to a naturally
2.1 ASTM Standards:
occurring mineral grain that is not readily soluble in water.
C 670 Practice for Precision and Bias Statements for Test
Therefore, the specific gravity of soils that contain extraneous
Methods for Construction Materials
matter (such as cement, lime, and the like) or water-soluble
D 653 Terminology Relating to Soil, Rock, and Contained
material (such as salt) must be corrected for the precipitate that
Fluids
forms on the specimen after drying. If the precipitate has a
D 854 Test Method for Specific Gravity of Soils
specific gravity less than the parent soil grains, the uncorrected
D 4753 Specification for Evaluating, Selecting, and Speci-
test result will be too low. If the precipitate has a higher
fying Balances and Scales for Use in Soil, Rock, and
specific gravity, then the uncorrected test value will be too
Related Construction Materials
high.
3. Terminology
6. Apparatus
3.1 Definitions:
6.1 Pycnometer—The gas pycnometer shall be one of the
3.1.1 The definitions of terms used in this test method shall
commercially available models that determines the volume of
be in accordance with Terminology D 653.
a solid by one of two methods. One measures the pressure drop
3.2 Definitions of Terms Specific to This Standard:
that occurs after a gas at a known pressure is allowed to flow
3.2.1 specific gravity—the ratio of the mass in air of a given
into another chamber (typically the first chamber contains the
solid material being tested). The amount of pressure drop is
related to the volume of soil present. The other type of
This test method is under the jurisdiction of ASTM Committee D-18 on Soil
instrument puts a known volume of gas into a chamber
and Rock and is the direct responsibility of Subcommittee D18.13 on Marine and
containing the specimen. The increase in pressure is related to
Coastal Geotechnical.
Current edition approved May 15, 1994. Published July 1994.
the volume of the material. Either type of instrument is
Annual Book of ASTM Standards, Vol 04.08.
D 5550
acceptable provided that the required accuracy of the instru- 7. Reagents and Materials
ment produces a volume measurement that is 60.2 % of the
7.1 Unless otherwise specified as being acceptable by the
specimen volume.
manufacturer, research grade helium should be used in con-
junction with the instrument.
NOTE 2—All of the commercially available instruments can provide
acceptable accuracy. However, some instruments require an operator to
8. Test Specimen
manually perform the test (that is, physically move the working compo-
nents of the apparatus), whereas, other instruments are fully automatic
8.1 The test specimen must be oven dried and shall be
(after the specimen has been loaded) and can produce a digital display of
representative of the total sample. Typically a greater specimen
the volume and specific gravity value (the specimen mass has to be input).
mass used in the instrument will produce a more accurate
Some instruments can also send the test results to a separate printer.
measured volume. The sample container within the available
Obviously, inherent errors are more possible with one type of equipment
than another. Furthermore, some instruments are constructed differently pycnometers varies in size from 1 to 135 cm . Because of the
than others and can therefore produce more accurate and reproducible
principles involved with instrument function, most manufac-
results.
turers require that a majority of the specimen cup be filled with
soil to produce acceptably accurate volume results. Soil grains
6.2 Balance—Balance meeting the requirements of Speci-
fications D 4753 and readable, without estimation, to at least of any size are acceptable to test provided that they are easily
placed within and do not protrude from the specimen container.
0.1 % of the specimen mass.
6.3 Compressed Gas System—Typically research grade he-
NOTE 8—Using a small sample container may require the use of a more
lium is required by the instruments. A tank capable of storing
accurate balance with higher precision to attain the specified accuracy
the required volume of gas and associated pressure regulator(s)
required by this test method.
required to deliver the gas at the specified pressure.
9. Calibration
NOTE 3—Other inert gas may be substituted for helium; refer to
9.1 The calibration of each type of pycnometer is different.
manufacturer’s suggestions. Helium is often used because it obeys the
The manufacturer’s instructions should be followed. However,
ideal gas law and is able to penetrate small soil pores. Ordinary air may
produce acceptable results for non-reactive specimens in some instru- all of them have two common calibration checks. The first one
ments, however, that practice should be discouraged because of the
requires the specimen holder cup be checked when empty. The
uncertainty introduced into the test results.
determined volume should be within manufacturer’s tolerances
of zero. Each pycnometer should also be supplied with an
6.4 Drying Oven—Thermostatically-controlled oven, ca-
pable of maintaining a uniform temperature of 110 6 5°C (230 object of known volume (6 manufacturer’s tolerances) that
can be placed in the specimen cup. The measured object’s
6 9°F) throughout the drying chamber.
6.5 Desiccator—A desiccating cabinet or jar with air-tight volume should fall within specifications.
9.2 The zero check should be made at the beginning of
seal containing silica gel or an anhydrous calcium sulfate
desiccant. testing on a daily basis. The calibration volume check should
be performed after twenty-five soil specimens are tested.
NOTE 4—Anhydrous calcium sulfate is sold under the trade name
Depending on its configuration, a pycnometer may also require
Drierite.
the periodic checking of an internal chamber volume(s). If any
NOTE 5—Indicating desiccant changes color when it is no longer able to
calibration check falls outside the tolerances set forth by the
absorb moisture. However, indicating desiccant is more expensive than
the non-indicating variety. To save cost, indicating desiccant can be mixed manufacturer, the problem must be found and rectified before
in with the non-indicating type. A ratio of one part indicating desiccant to
testing on soil specimens resumes.
approximately four parts non-indicating has proven to be acceptable in
NOTE 9—It may be beneficial to have a number of soil specimens that
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