Standard Practice for Operating Fluorescent Light Apparatus for UV Exposure of Nonmetallic Materials

SCOPE
1.1 This practice covers the basic principles and operating procedures for using fluorescent UV light, and water apparatus intended to reproduce the weathering effects that occur when materials are exposed to sunlight (either direct or through window glass) and moisture as rain or dew in actual usage. This practice is limited to the procedures for obtaining, measuring, and controlling conditions of exposure. A number of exposure procedures are listed in an appendix; however, this practice does not specify the exposure conditions best suited for the material to be tested.
Note 1—Practice G151 describes performance criteria for all exposure devices that use laboratory light sources. This practice replaces Practice G53, which describes very specific designs for devices used for fluorescent UV exposures. The apparatus described in Practice G53 is covered by this practice.
1.2 Test specimens are exposed to fluorescent UV light under controlled environmental conditions. Different types of fluorescent UV light sources are described.
1.3 Specimen preparation and evaluation of the results are covered in ASTM methods or specifications for specific materials. General guidance is given in Practice G151 and ISO 4892-1. More specific information about methods for determining the change in properties after exposure and reporting these results is described in ISO 4582.
1.4 The values stated in SI units are to be regarded as the standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
1.6 This standard is technically similar to ISO 4892-3 and ISO DIS 11507.

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NOTICE: This standard has either been superseded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: G 154 – 00
Standard Practice for
Operating Fluorescent Light Apparatus for UV Exposure of
Nonmetallic Materials
This standard is issued under the fixed designation G 154; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope 2. Referenced Documents
1.1 This practice covers the basic principles and operating 2.1 ASTM Standards:
procedures for using fluorescent UV light, and water apparatus D 3980 Practice for Interlaboratory Testing of Paint and
intended to reproduce the weathering effects that occur when Related Materials
materials are exposed to sunlight (either direct or through E 691 Practice for Conducting an Interlaboratory Study to
window glass) and moisture as rain or dew in actual usage. Determine the Precision of a Test Method
This practice is limited to the procedures for obtaining, G 53 Practice for Operating Light- and Water-Exposure
measuring, and controlling conditions of exposure. A number Apparatus (Fluorescent UV-Condensation Type) for Expo-
of exposure procedures are listed in an appendix; however, this sure of Nonmetallic Materials
practice does not specify the exposure conditions best suited G 113 Terminology Relating to Natural and Artificial
for the material to be tested. Weathering Tests for Nonmetallic Materials
G 151 Practice for Exposing Nonmetallic Materials in Ac-
NOTE 1—Practice G 151 describes performance criteria for all exposure
celerated Test Devices That Use Laboratory Light
devices that use laboratory light sources. This practice replaces Practice
Sources
G 53, which describes very specific designs for devices used for fluores-
cent UV exposures. The apparatus described in Practice G 53 is covered 2.2 CIE Standard:
by this practice.
CIE-Publ. No. 85: Recommendations for the Integrated
Irradiance and the Spectral Distribution of Simulated
1.2 Test specimens are exposed to fluorescent UV light
Solar Radiation for Testing Purposes
under controlled environmental conditions. Different types of
2.3 ISO Standards:
fluorescent UV light sources are described.
ISO 4582, Plastics—Determination of the Changes of Co-
1.3 Specimen preparation and evaluation of the results are
lour and Variations in Properties After Exposure to Day-
covered in ASTM methods or specifications for specific
light Under Glass, Natural Weathering or Artificial Light
materials. General guidance is given in Practice G 151 and ISO
ISO 4892-1, Plastics—Methods of Exposure to Laboratory
4892-1. More specific information about methods for deter-
Light Sources, Part 1, Guidance
mining the change in properties after exposure and reporting
ISO 4892-3, Plastics—Methods of Exposure to Laboratory
these results is described in ISO 4582.
Light Sources, Part 3, Fluorescent UV lamps
1.4 The values stated in SI units are to be regarded as the
ISO DIS 11507, Paint and Varnishes—Exposure of Coat-
standard.
ings to Artificial Weathering in Apparatus—Exposure to
1.5 This standard does not purport to address all of the
Fluorescent Ultraviolet and Condensation Apparatus
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
3. Terminology
priate safety and health practices and determine the applica-
3.1 Definitions—The definitions given in Terminology
bility of regulatory limitations prior to use.
G 113 are applicable to this practice.
1.6 This standard is technically similar to ISO 4892-3 and
3.2 Definitions of Terms Specific to This Standard—As used
ISO DIS 11507.
Discontinued 1998. See 1998 Annual Book of ASTM Standards, Vol 06.01.
Annual Book of ASTM Standards, Vol 14.02.
1 4
This practice is under the jurisdiction of ASTM Committee G-3 on Weathering Annual Book of ASTM Standards, Vol 14.04.
and Durability and is the direct responsibility of Subcommittee G03.03 on Available from Secretary, U.S. National Committee, CIE, National Institute of
Simulated and Controlled Exposure Tests. Standards and Technology (NIST), Gaithersburg, MD 20899.
Current edition approved Feb. 10, 2000. Published May 2000. Originally Available from American National Standards Institute, 11 W. 42nd St., 13th
published as G 154 – 97. Last previous edition G 154 – 98. Floor, New York, NY 10036.
Copyright © ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959, United States.
G 154
in this practice, the term sunlight is identical to the terms detailed description of the type(s) of lamp(s) used should be
daylight and solar irradiance, global as they are defined in stated in detail in the test report. The particular testing
Terminology G 113. application determines which lamp should be used. See Ap-
pendix X1 for lamp application guidelines.
4. Summary of Practice
NOTE 3—Do not mix different types of lamps. Mixing different types of
4.1 Specimens are exposed to repetitive cycles of light and
lamps in a fluorescent UV light apparatus may produce major inconsis-
moisture under controlled environmental conditions.
tencies in the light falling on the samples, unless the apparatus has been
specifically designed to ensure a uniform spectral distribution.
4.1.1 Moisture is usually produced by condensation of
NOTE 4—Many fluorescent lamps age significantly with extended use.
water vapor onto the test specimen or by spraying the speci-
Follow the apparatus manufacturer’s instructions on the procedure neces-
mens with demineralized/deionized water.
sary to maintain desired irradiance (1,2).
4.2 The exposure condition may be varied by selection of:
6.1.1 Actual irradiance levels at the test specimen surface
4.2.1 The fluorescent lamp,
may vary due to the type or manufacturer of the lamp used, or
4.2.2 The lamp’s irradiance level,
both, the age of the lamps, the distance to the lamp array, and
4.2.3 The type of moisture exposure,
the air temperature within the chamber and the ambient
4.2.4 The timing of the light and moisture exposure,
laboratory temperature. Consequently, the use of a radiometer
4.2.5 The temperature of light exposure, and
to monitor and control the radiant energy is recommended.
4.2.6 The temperature of moisture exposure, and
6.1.2 Several factors can affect the spectral power distribu-
4.2.7 The timing of a light/dark cycle.
tion of fluorescent UV lamps:
4.3 Comparison of results obtained from specimens exposed
6.1.2.1 Aging of the glass used in some types of lamps can
in same model of apparatus should not be made unless
result in changes in transmission. Aging of glass can result in
reproducibility has been established among devices for the
a significant reduction in the short wavelength UV emission of
material to be tested.
some lamp types,
4.4 Comparison of results obtained from specimens exposed
6.1.2.2 Accumulation of dirt or other residue on lamps can
in different models of apparatus should not be made unless
affect irradiance,
correlation has been established among devices for the material
6.1.2.3 Thickness of glass used for lamp tube can have large
to be tested.
effects on the amount of short wavelength UV radiation
5. Significance and Use transmitted, and
6.1.2.4 Uniformity and durability of phosphor coating.
5.1 The use of this apparatus is intended to induce property
6.1.3 Spectral Irradiance:
changes associated with the end use conditions, including the
effects of the UV portion of sunlight, moisture, and heat. These
NOTE 5—Fluorescent UVA lamps are available with a choice of spectral
exposures may include a means to introduce moisture to the power distributions that vary significantly. The more common may be
identified as UVA-340 and UVA-351. These numbers represent the
test specimen. Exposures are not intended to simulate the
characteristic nominal wavelength (in nm) of peak emission for each of
deterioration caused by localized weather phenomena, such as
these lamp types. The actual peak emissions are at 343 and 350 nm,
atmospheric pollution, biological attack, and saltwater expo-
respectively.
sure. Alternatively, the exposure may simulate the effects of
6.1.3.1 Spectral Irradiance of UVA-340 Lamps for Daylight
sunlight through window glass. Typically, these exposures
UV—The spectral power distribution of UVA-340 fluorescent
would include moisture in the form of condensing humidity.
lamps shall comply with the requirements specified in Table 1.
NOTE 2—Caution: Refer to Practice G 151 for full cautionary guidance
NOTE 6—The main application for UVA-340 lamps is for simulation of
applicable to all laboratory weathering devices.
the short and middle UV wavelength region of daylight.
5.2 Variation in results may be expected when operating
6.1.3.2 Spectral Irradiance of UVA-351 Lamps for Daylight
conditions are varied within the accepted limits of this practice.
UV Behind Window Glass—The spectral power UV behind
Therefore, no reference shall be made to results from the use of
window glass of UVA-351 fluorescent lamps shall comply with
this practice unless accompanied by a report detailing the
the requirements specified in Table 2.
specific operating conditions in conformance with the Section
10.
NOTE 7—The main application for UVA-351 lamps is for simulation of
5.2.1 It is recommended that a similar material of known the short and middle UV wavelength region of daylight which has been
filtered through window glass (3).
performance (a control) be exposed simultaneously with the
test specimen to provide a standard for comparative purposes.
6.1.3.3 Spectral Irradiance of UVB-313 Lamps—The spec-
It is recommended that at least three replicates of each material tral power distribution of UVB-313 fluorescent lamps shall
evaluated be exposed in each test to allow for statistical
comply with the requirements specified in Table 2.
evaluation of results.
NOTE 8—Fluorescent UVB lamps have the spectral distribution of
radiation peaking near the 313-nm mercury line. They emit significant
6. Apparatus
amounts of radiation below 300 nm, the nominal cut on wavelength of
6.1 Laboratory Light Source—The light source shall be global solar radiation, that may result in aging processes not occurring
outdoors. Use of this lamp is not recommended for sunlight simulation.
fluorescent UV lamps. A variety of fluorescent UV lamps can
See Table 3.
be used for this procedure. Differences in lamp intensity or
spectrum may cause significant differences in test results. A 6.2 Test Chamber—The design of the test chamber may
G 154
TABLE 1 Relative Spectral Power Distribution Specification for TABLE 2 Relative Spectral Power Distribution Specification for
UVA-340 Lamps for Daylight UV UVA-351 Lamps for Daylight UV Behind Window Glass
A B
Bandpass, nm Fluorescent UVA-340 Lamp Sunlight Estimated Window Glass
A
Bandpass, nm Fluorescent UVA-351 Lamp
B
Filtered Sunlight
Ultraviolet Wavelength Region
Irradiance as a percentage of total irradiance from 260 to 400 nm Ultraviolet Wavelength Region
Irradiance as a percentage of total irradiance from 260 to 400 nm
260–270 0.0 % 0
271–280 0.0 % 0 260–270 0.0 % 0 %
281–290 0.0 % 0 271–280 0.0 % 0 %
291–300 < 0.2 % 0 281–290 0.0 % 0 %
301–320 6.2–8.6 % 5.6 % 290–300 < 0.1 % 0 %
321–340 27.1–30.7 % 18.5 % 301–320 0.9–3.3 % 0.1–1.5 %
321–340 18.3–22.7 % 9.4–14.8 %
341–360 34.2–35.4 % 21.7 %
361–380 19.5–23.7 % 26.6 % 341–360 42.7–44.5 % 23.2–23.5 %
381–400 6.6–7.8 % 27.6 % 361–380 24.8–28.2 % 29.6–32.5 %
381–400 5.8–7.6 % 30.9 –34.5 %
Ultraviolet and Visible Wavelength Region
C
Irradiance as a percentage of total irradiance from 300 to 800 nm Ultraviolet and Visible Wavelength Region
C
Irradiance as a percentage of total irradiance from 300 to 800 nm
D E
300–400 87.3 % 11 %
D E D E
401–700 12.7 % 72 % 300–400 90.1 % 9.0–11.1 %
D E
401–700 9.9 % 71.3–73.1 %
A
UVA-340 data—The ranges given are based on spectral power distribution
A
measurements made for lamps of different ages and operating at different levels of UVA-351 data—The ranges given are based on spectral power distribution
controlled irradiance. The ranges given are based on three sigma limits from the measurements made for lamps of different ages and operating at different levels of
averages of this data. controlled irradiance. The ranges given are based on three sigma limits from the
B
Sunlight data—The sunlight data is for global irradiance on a horizontal surface averages of this data.
B
with a air mass of 1.2, column ozone 0.294 atm cm, 30 % relative humidity, altitude Sunlight data—The sunlight data is for global irradiance on a horizontal surface
2100 m (atmopsheric pressure of 787.8 mb), and an aerosol represented by an with an air mass of 1.2, column ozone 0.294 atm cm, 30 % relative humidity,
optical thickness of 0.81 at 300 nm and 0.62 at 400 nm. altitude 2100 m (atmospheric pressure of 787.8 mb), and an aerosol represented
C
Data from 701 to 800 nm is not shown. by an optical thickness of 0.081 at 300 nm and 0.62 at 400 nm. The range is
D
UVA-340 data—Because the primary emission of fluorescent UV lamps is determined by multiplying solar irradiance by the upper and lower limits for
concentrated in the 300- to 400-nm bandpass, there are limited data available for transmission of single strength window glass samples used for studies conducted
visible light emissions of fluorescent UV lamps. Therefore, the data in this table are by ASTM Subcommittee G03.02.
C
based on very few measurements and are representative only. Data from 701 to 800 nm is not shown.
E D
Sunlight data—The sunlight data is from Table 4 of CIE Publication Number 85, UVA-351 data—Because the primary emission of fluorescent UV lamps is
global solar irradiance on a horizontal surface with an air mass of 1.0, column concentrated in the 300- to 400-nm bandpass, there are limited data available for
ozone of 0.34 atm cm, 1.42-cm precipitable water vapor, and an aerosol visible light emissions of fluorescent UV lamps. Therefore, the data in this table are
represented by an optical thickness of 0.1 at 500 nm. based on very few measurements and are representative only.
E
Sunlight data—The sunlight data is from Table 4 of CIE Publication Number 85,
global solar irradiance on a horizontal surface with an air mass of 1.0, column
vary, but it should be constructed from corrosion resistant ozone of 0.34 atm cm, 1.42-cm precipitable water vapor, and an aerosol
represented by an optical thickness of 0.1 at 500 nm. The range is determined by
material and, in addition to the radiant source, may provide for
multiplying solar irradiance by the upper and lower limits for transmission of single
means of controlling temperatu
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