ASTM D5564-95(2018)
(Test Method)Standard Test Method for Determination of the Total Ammonia Contained in Sulfonated or Sulfated Oils
Standard Test Method for Determination of the Total Ammonia Contained in Sulfonated or Sulfated Oils
SIGNIFICANCE AND USE
3.1 This test method of analysis is intended to determine the total ammonia in a sample of sulfonated or sulfated oil, or both, by boiling a water solution of the sample with excess alkali and determining by titration the loss in alkali after the boiling.
SCOPE
1.1 This test method covers determination of the total ammonia contained in sulfonated or sulfated oils.
1.2 The values stated in SI units are to be regarded as the standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
Relations
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D5564 − 95 (Reapproved 2018)
Standard Test Method for
Determination of the Total Ammonia Contained in
Sulfonated or Sulfated Oils
This standard is issued under the fixed designation D5564; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope between the flask and the condenser shall be a ground joint.
Perforated glass beads shall be used to prevent bumping.
1.1 This test method covers determination of the total
4.1.1 Flask—An Erlenmeyer flask (Fig. 1) made of a boro-
ammonia contained in sulfonated or sulfated oils.
silicate glass, having a capacity of approximately 300 mL and
1.2 The values stated in SI units are to be regarded as the
provided with a glass stopper.
standard.
4.1.2 Condenser, consisting of a glass tube, 915 mm (36 in.)
1.3 This standard does not purport to address all of the
in length and 8 mm ( ⁄16 in.) in outside diameter.The lower end
safety concerns, if any, associated with its use. It is the of the tube shall be flared and ground to fit the mouth of the
responsibility of the user of this standard to establish appro-
Erlenmeyer flask.
priate safety, health, and environmental practices and deter- 4.1.3 Glass Beads—Perforated glass beads, made of chemi-
mine the applicability of regulatory limitations prior to use.
cally resistant glass, approximately 4 mm ( ⁄32 in.) in diameter.
1.4 This international standard was developed in accor- Before using, the glass beads shall be boiled thoroughly in
dance with internationally recognized principles on standard-
several portions of water or until the wash water reacts neutral
ization established in the Decision on Principles for the to a methyl orange indicator.
Development of International Standards, Guides and Recom-
5. Reagents
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee. 5.1 Ethyl Ether.
5.2 MethylOrangeIndicatorSolution(1g/L)—Dissolve 0.1
2. Referenced Documents
g of methyl orange in 100 mL of water.
2.1 ASTM Standards:
5.3 Sodium Chloride (NaCl), solid.
D5350 Test Method for Determination of Organically Com-
5.4 Sodium Hydroxide, Standard Solution (1 N)—
bined Sulfuric Anhydride by Titration, Test Method A
Accurately prepare and standardize a 1 N sodium hydroxide
3. Significance and Use
(NaOH) solution. Express the strength or concentration of the
solution as mg of KOH per mL; 1 mL of 1 N NaOH solution
3.1 This test method of analysis is intended to determine the
is equivalent to 56.1 mg of KOH.
totalammoniainasampleofsulfonatedorsulfatedoil,orboth,
by boiling a water solution of the sample with excess alkali and
5.5 Sodium Hydroxide, Standard Solution (0.5 N)—
determining by titration the loss in alkali after the boiling.
Accurately prepare and standardize a 0.5 N NaOH solution.
Express the strength of the solution as mg of KOH per mL; 1
4. Apparatus
mLof 0.5N NaOH solution is equivalent to 28.05 mg of KOH.
4.1 The apparatus required consists of a glass flask provided
5.6 SulfuricAcid,Standard(0.5N)—Accuratelyprepareand
with a glass stopper and an air condenser. The connection
standardize a 0.5N sulfuric acid (H SO ) solution. Express the
2 4
strength of the solution as mg of KOH per mL; 1 mL of 0.5 N
H SO is equivalent to 28.05 mg of KOH.
1 2 4
This test method is under the jurisdiction ofASTM Committee D31 on Leather
and is the direct responsibility of Subcommittee D31.08 on Fats and Oils. This test
5.7 Sulfuric Acid (1+19)—Carefully mix 1 volume of con-
method was developed in cooperation with the American Leather Chemists Assn.
centrated sulfuric acid (H SO , sp gr 1.84) into 19 volumes of
2 4
(Meth
...
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