Standard Guide for Evaluating Chemical Protective Clothing

SCOPE
1.1 This guide is intended to promote the use of standards in the development, specification, and selection of chemical protective clothing with the ultimate goal of improving the safety and health of workers who come into contact with hazardous chemicals.
1.2 Proposed Standards Under Development by ASTM Committee F-23: Test Method for Resistance to Cut Modification of Test Method F739 to include permeation testing under conditions of intermittent chemical contact (Test) Test Method for Resistance to Chemical Protective Clothing Materials to Liquid Contact-Permeation Cup Method Guide for Contaminating, Decontaminating, Evaluating Residual Contamination in Chemical Protective Clothing Reference Materials (Reference Material) Guide for Documenting the Results of Chemical Permeation Testing of Protective Clothing Materials Guide for Classification of Types of Chemical Protective Clothing Guide for Classification of Materials Used in Chemical Protective Clothing Guide for Classification of Chemicals According to Functional Groups Guide for Minimum Documentation and Test Methods for Chemical Protective Clothing Test Method for Quantitatively Measuring Leak Rate of Chemical Protective and Totally-Encapsulating Chemical Protective Suits Practice for Determining the Liquid-Tight Integrity of Chemical Protective Suits Guide for Chemical Protective Clothing Labelling for User Information Practice for Use of Chemical Protective Clothing 1.3 Standards relevant to the work of Committee F-23 are described along with their key reporting elements and limitations.
1.4 Proposed standards of Committee F-23 are also described in order to provide insight into possible future products of the committee.  
1.5 The standards and proposed standards are organized under the following headings: Physical Properties, Chemical Resistance, Classification, Chemical Protective Suits, and General.  
1.6 Appendix X1 is an example of how the standards can be combined into a protocol for selection of the most suitable protective clothing for a given application. Briefly, the process is one of defining the requirements of the application and then (by testing) eliminating those candidatesthat are unsuitable. No protocol can yield protective clothing that "guarantees" worker protection, rather the purpose of testing is to generate data and information that will allow the selection of the most appropriate clothing. Ultimately, clothing selection is based on professional judgement and trade-offs.  
1.7 The values stated in inch-pound units are to be regarded as standard. The SI units given in parentheses are for information only.
1.8 This standard does not purport to address the safety problems associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Publication Date
09-Jun-1998
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NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
Designation: F 1296 – 98
Standard Guide for
Evaluating Chemical Protective Clothing
This standard is issued under the fixed designation F 1296; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
INTRODUCTION
ASTM Committee F-23 was established in 1976 for the purpose of producing standards for use in
the evaluation of protective clothing; in particular, clothing that is used for protection from potentially
hazardous chemicals. Such clothing ranges from aprons and gloves to totally encapsulating ensembles.
The clothing is widely used throughout industry, agriculture, government, and academia in, for
example, chemical research, pesticide application, hazardous waste cleanup, and chemical production.
Committee F-23 is also concerned with clothing for protection from molten metals, but that aspect
of the committee’s activities is not addressed in this guide.
The effective development and selection of chemical protective clothing requires information on
several aspects of the clothing, including chemical resistance, physical integrity, comfort, and fit.
Some of these characteristics can be evaluated using swatches of the materials from which the clothing
is fabricated; other characteristics require testing of the finished items of clothing. Both types of test
methods have been addressed by Committee F-23.
The successful use of Committee F-23’s standards requires an awareness and understanding of each
standard as well as the interrelationship of the standards.
The successful application of chemical protective clothing requires the careful matching of the
proper level of protection and performance characteristics of clothing with the potential hazard and the
functional requirements of the tasks to be performed while wearing the clothing.
1. Scope 1.4 Proposed standards of Committee F-23 are also de-
scribed to provide insight into possible future products of the
1.1 This guide is intended to promote the use of standards in
committee.
the development, specification, and selection of chemical
1.5 The standards and proposed standards are organized
protective clothing with the ultimate goal of improving the
under the following headings: Physical Properties, Chemical
safety and health of workers who come into contact with
Resistance, Classification, Chemical Protective Suits, and Gen-
hazardous chemicals.
eral.
1.2 Proposed standards under development by ASTM Com-
1.6 Appendix X1 is an example of how the standards can be
mittee F-23:
combined into a protocol for selection of the most suitable
1.2.1 Test Methods for Measuring the Performance Charac-
protective clothing for a given application. Briefly, the process
teristics of Exhaust Valves Used in Chemical Protective Suits
is one of defining the requirements of the application and then
1.2.2 Test Method for Measuring the Thermal and Evapo-
(by testing) eliminating those candidates that are unsuitable.
rative Resistance of Textile Materials Using a Sweating Hot
No protocol can ensure the selection of protective clothing that
Plate
guarantees worker protection. The purpose of testing is to
1.2.3 Test Method for Testing Protective Clothing Materials
generate data and information that will allow the selection of
for Particle Penetration and Air Flow Resistance
the most appropriate clothing. Ultimately, clothing selection is
1.2.4 Practice for Protective Clothing Maintenance Instruc-
based on technical evaluation of available information and
tions
professional assessment of risk.
1.3 Standards relevant to the work of Committee F-23 are
1.7 The values stated in inch-pound units are to be regarded
described along with their key reporting elements and limita-
as standard. The SI units given in parentheses are for informa-
tions.
tion only.
1.8 This standard does not purport to address the safety
This guide is under the jurisdiction of ASTM Committee F-23 on Protective
concerns, if any, associated with its use. It is the responsibility
Clothing and is the direct responsibility of Subcommittee F23.70 on Use.
of the user of this standard to establish appropriate safety and
Current edition approved June 10, 1998. Published August 1998. Originally
published as F 1296 –91. Last previous edition F 1296 – 91.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
F1296–98
health practices and determine the applicability of regulatory 3.2 The standards are intended as a means by which
limitations prior to use. information can be requested, generated, and reported in a
consistent, comparable manner.
3.3 The information on clothing performance must be com-
2. Referenced Documents
bined, by means of professional judgment, with a clear
2.1 ASTM Standards:
understanding of the clothing application to provide the best
F 739 Test Method for Resistance of Protective Clothing
protection to the worker.
Materials to Permeation by Liquids or Gases Under Con-
ditions of Continuous Contact
4. Physical Properties of Clothing Materials
F 903 Test Method for Resistance of Materials Used In
4.1 Standards:
Protective Clothing to Penetration by Liquids
4.1.1 F 1358 Test Method for Effects of Flame Impingement
F 1001 Guide for Selection of Chemicals to Evaluate Pro-
on Materials Used in Protective Clothing Not Designated
tective Clothing Materials
Primarily for Flame Resistance—This test method is intended
F 1052 Test Method for Pressure Testing Vapor Protective
to determine the ignition resistance and burning characteristics
Ensembles
of materials used in protective clothing, where flame resistance
F 1154 Practices for Qualitatively Evaluating the Comfort,
is not the primary form of protection designated. A test
Fit, Function, and Integrity of Chemical-Protective Suit
specimen is exposed to a flame for 3 s. If the material ignites,
Ensembles
the after-flame time, afterglow time, and burn distance are
F 1186 Classification System for Chemicals According to
measured. If the material does not ignite, the test is repeated
Functional Groups
using a flame exposure period of 12 s.
F 1194 Guide for Documenting the Results of Chemical
4.1.1.1 When flame resistance is the primary protection
Permeation Testing on Materials Used in Protective Cloth-
offered by the protective clothing, alternative test methods
ing
should be used.
F 1291 Test Method for Measuring the Thermal Insulation
4.1.2 F 1342 Test Method for Protective Clothing Material
of Clothing Using a Heated Manikin
Resistance to Puncture—This test method evaluates puncture
F 1301 Practice for Labeling Chemical Protective Clothing
resistance of protective clothing materials that may include
F 1342 Test Method for Protective Clothing Material Resis-
plastics or elastomeric films, coated fabrics, flexible materials,
tance to Puncture
laminates, or textile materials.
F 1358 Test Method for Effects of Flame Impingement on
4.1.2.1 It is not intended to measure puncture resistance of
Materials Used in Protective Clothing Not Designated
all types of punctures encountered using protective clothing
Primarily for Flame Resistance
materials. This test method involves a procedure where a
F 1359 Test Method for Liquid Penetration Resistance of
puncture probe of specified dimensions is used for puncturing
Protective Clothing or Protective Ensembles Under a
specimens.
Shower Spray While on a Mannequin
4.1.2.2 The method evaluates puncture resistance of protec-
F 1383 Test Method for Resistance of Protective Clothing
tive clothing materials, specifically for puncture forced on
Materials to Permeation by Liquids or Gases Under Con-
specimens perpendicular to material surface. There is no
ditions of Intermittent Contact
supporting structure under the material specimen.
F 1407 Test Method for Resistance of Chemical Protective
4.1.3 F 1790 Test Method for Measuring Cut Resistance of
Clothing Materials to Liquid Permeation—Permeation Cup
Materials Used in Protective Clothing—This test method
Method
assesses the cut resistance of a material when exposed to a
F 1461 Practice for Chemical Protective Clothing Program
cutting edge under specified loads. Data obtained using this test
F 1494 Terminology Relating to Protective Clothing
method can be used to compare the cut resistance of different
F 1790 Test Method for Measuring Cut Resistance of Ma-
materials.
terials Used in Protective Clothing
4.1.3.1 This test method only addresses that range of cutting
F 1818 Specification for Foot Protection for Chain Saw
hazards that are related to a cutting action across the surface of
Users
the material. It is not representative of any other cutting hazard
F 1819 Test Method for Resistance of Materials Used in
to which the material may be exposed.
Protective Clothing to Penetration by Synthetic Blood
4.2 Proposed Standards:
Using a Mechanical Pressure Technique
4.2.1 Test Method for Testing Protective Clothing Materials
for Particle Penetration and Air Flow Resistance—The pur-
3. Significance and Use
pose of this test method is to provide a means to compare a
fabric’s particulate penetration behavior. An aerosol generator
3.1 The standards under the jurisdiction of Committee F-23
is used to generate a uniform aerosol. The generator is coupled
can be used individually or as part of an integrated protocol in
to a laser particle counter that counts and records the number
the development, selection, specification, and application of
of aerosol particles before and after the test fabric at specified
chemical protective clothing.
air flows.
5. Chemical Resistance of Clothing Materials
Annual Book of ASTM Standards, Vol 11.03. 5.1 Standards:
NOTICE: This standard has either been superceded and replaced by a new version or discontinued.
Contact ASTM International (www.astm.org) for the latest information.
F1296–98
5.1.1 F 739 Test Method for Resistance of Protective Cloth- 6. Classification
ing Materials to Permeation by Liquids or Gases Under
6.1 Standards:
Conditions of Continuous Contact—The resistance of a pro-
6.1.1 F 1186 Classification System for Chemicals According
tective clothing material to permeation by a test chemical is
to Functional Groups—In many situations where chemicals
assessed by measuring the breakthrough detection time, nor-
are interacting with other chemicals or materials, the interac-
malized breakthrough detection time, and subsequent perme-
tion is strongly dependent and often correlated with the
ation rate through replicate specimens of the material.
functional group(s) present. For this reason it is useful to have
5.1.1.1 In the permeation test apparatus, the protective a standard means for classifying chemicals.
clothing material specimens partition the test chemical from
6.1.1.1 Chemical resistance data are available for only a
the collection medium. The collection medium, which may be very small fraction of the chemicals for which protective
liquid or gas, is analyzed quantitatively for its concentration of clothing is used. However, for chemicals for which no data are
the chemical and thereby the amount of the chemical that has available, a knowledge of the chemical class can sometimes
give insight into the expected resistance of prospective clothing
permeated the test specimen as a function of time after its
material.
initial contact with the material.
6.2 Proposed Standards: None
5.1.2 F 903 Test Method for Resistance of Materials Used In
Protective Clothing to Penetration by Liquids—This test
7. Chemical Protective Suits
method is normally used to evaluate the barrier effectiveness
against liquids of materials used for protective clothing and
7.1 Standards:
specimens from finished items of protective clothing. A mate-
7.1.1 F 1052 Test Method for Pressure Testing Vapor Pro-
rial specimen is subjected to a liquid contact for a specified tective Ensembles—This test method evaluates the gas-tight
time and pressure sequence and observed for visible penetra-
integrity of a totally encapsulating, chemical protective suit.
tion of the liquid. If the liquid passes through the material, the The test apparatus is attached to the suit to permit inflation to
material fails the test for resistance to penetration of the liquid. the pre-test suit expansion pressure for removal of suit wrinkles
and creases and to equalize/stabilize the air temperatures
5.1.3 F 1001 Guide for Selection of Chemicals to Evaluate
internal and external to the VPE. The pressure is lowered to the
Protective Clothing Materials—This guide lists recommended
test pressure and monitored for 4 min. If the pressure drop is
challenge chemicals to be used in testing programs to evaluate
excessive, the suit fails the test and is removed from service.
chemical protective clothing materials. The guide contains a
7.1.2 F 1154 Practices for Qualitatively Evaluating the
list of 15 liquid and 6 gases representing many different classes
Comfort, Fit, Function, and Integrity of Chemical-Protective
of chemicals: acids, bases, ketones, aldehydes, amines, hydro-
Suit Ensembles—These practices establish standard procedures
carbons, and so forth.
designed for quantitatively evaluating the performance charac-
5.1.4 F 1383 Test Method for Resistance of Protective
teristics of chemical–protective suit ensembles in terms of
Clothing Materials to Permeation by Liquids or Gases Under
comfort, fit, function, and overall integrity.
Conditions of Intermittent Contact—This test method is used
7.1.2.1 Option A evaluates the integrity of the suit and its
to measure breakthrough detection time and chemical perme-
materials and seams by subjecting the suit to manned exercise
ation through specimens of protective clothing under the
scenarios. The exercise routine includes kneeling, squatting,
conditions of intermittent contact of a test chemical with the
twisting, reaching overhead, and crawling.
specimen.
7.1.2.2 Option B evaluates the function of the suit by
5.1.5 F 1407 Test Method for Resistance of Chemical Pro-
observing the ability of a test subject to perform routine work
tective Clothing Materials to Liquid Permeation - Permeation
tasks while wearing the suit. Routine tasks involve lifting
Cup Method—Permeation of chemicals through a clothing
boxes, moving a 55-gal drum, operating an overhead valve,
specimen is measured by gravimetry. The chemical is placed in
usin
...

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