Standard Guide for Evaluation of Alternative Supplementary Cementitious Materials (ASCM) for Use in Concrete

SIGNIFICANCE AND USE
Common types of SCM include fly ash, slag cement, calcined clays, and silica fume. The introduction and widespread use of fly ash, slag cement, calcined clay, and silica fume have been characterized and supported by significant research and development programs, preconstruction testing, field testing and long term performance monitoring. As the technical and economic benefits of SCM have been recognized, and as sustainability and environmental awareness resulted in the need to develop new materials and new ways to use materials not previously utilized, new sources of potential SCM are being proposed for use in concrete as ASCM.
If an ASCM does not yet have a significant record of performance in concrete, a comprehensive evaluation based on this Guide should be undertaken, and it should be recognized that this ASCM might be introduced for a specific project or into a limited marketplace to initially demonstrate its performance. The user should bear in mind the intended end use of the ASCM and use appropriate test methods to establish its suitability. An ASCM that demonstrates good performance through a comprehensive evaluation as outlined in this guide could then be considered to have access to broader markets and could be considered for inclusion in an ASTM standard for SCM. For this reason, the test program to demonstrate acceptable performance should include concrete mixtures with a range of characteristics specific to the ASCM’s intended use.
In the absence of long-term durability or acceptable field performance, prospective users are advised to apply appropriate risk management and engineering practice in the use of an ASCM.
SCOPE
1.1 This Guide is intended to provide a technical approach to the evaluation of alternative supplementary cementitious materials such as pozzolans and hydraulic materials that fall outside the scope of Specifications C618, C989, and C1240. This Guide provides the initial steps for a comprehensive evaluation of an ASCM that provides due diligence for its specific intended uses in concrete; however, it does not evaluate conformance to all possible performance criteria for all types of concrete mixtures.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 Performing the tests or meeting the test limits in this guide should not imply that the material tested meets the requirements of Specifications C618, C989, and C1240. These materials should not be represented as such and each specific source is to be evaluated separately.
1.4 This guide does not purport to address all environmental and safety concerns, if any, associated with its use. It is the responsibility of the user of this guide to establish the appropriate environmental, health, and safety issues, and identify appropriate risk management procedures.

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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: C1709 − 11
Standard Guide for
Evaluation of Alternative Supplementary Cementitious
Materials (ASCM) for Use in Concrete
This standard is issued under the fixed designation C1709; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope C114 Test Methods for Chemical Analysis of Hydraulic
Cement
1.1 This Guide is intended to provide a technical approach
C125 Terminology Relating to Concrete and Concrete Ag-
to the evaluation of alternative supplementary cementitious
gregates
materials such as pozzolans and hydraulic materials that fall
C138/C138M Test Method for Density (Unit Weight),Yield,
outside the scope of Specifications C618, C989, and C1240.
and Air Content (Gravimetric) of Concrete
This Guide provides the initial steps for a comprehensive
C143/C143M Test Method for Slump of Hydraulic-Cement
evaluation of an ASCM that provides due diligence for its
Concrete
specific intended uses in concrete; however, it does not
C157/C157M Test Method for Length Change of Hardened
evaluate conformance to all possible performance criteria for
Hydraulic-Cement Mortar and Concrete
all types of concrete mixtures.
C186 Test Method for Heat of Hydration of Hydraulic
1.2 The values stated in SI units are to be regarded as
Cement
standard. No other units of measurement are included in this
C204 Test Methods for Fineness of Hydraulic Cement by
standard.
Air-Permeability Apparatus
1.3 Performing the tests or meeting the test limits in this
C231/C231M Test Method forAir Content of Freshly Mixed
guide should not imply that the material tested meets the
Concrete by the Pressure Method
requirements of Specifications C618, C989, and C1240. These
C232/C232M Test Method for Bleeding of Concrete
materials should not be represented as such and each specific
C311 Test Methods for Sampling and Testing Fly Ash or
source is to be evaluated separately.
Natural Pozzolans for Use in Portland-Cement Concrete
1.4 This guide does not purport to address all environmen-
C403/C403M Test Method for Time of Setting of Concrete
tal and safety concerns, if any, associated with its use. It is the
Mixtures by Penetration Resistance
responsibility of the user of this guide to establish the appro-
C430 Test Method for Fineness of Hydraulic Cement by the
priate environmental, health, and safety issues, and identify
45-µm (No. 325) Sieve
appropriate risk management procedures.
C457/C457M Test Method for Microscopical Determination
of Parameters of the Air-Void System in Hardened Con-
2. Referenced Documents
crete
2.1 ASTM Standards:
C469 Test Method for Static Modulus of Elasticity and
C39/C39M Test Method for Compressive Strength of Cylin-
Poisson’s Ratio of Concrete in Compression
drical Concrete Specimens
C618 Specification for Coal Fly Ash and Raw or Calcined
C78 Test Method for Flexural Strength of Concrete (Using
Natural Pozzolan for Use in Concrete
Simple Beam with Third-Point Loading)
C666/C666M Test Method for Resistance of Concrete to
C109/C109M Test Method for Compressive Strength of
Rapid Freezing and Thawing
Hydraulic Cement Mortars (Using 2-in. or [50-mm] Cube
C672/C672M Test Method for Scaling Resistance of Con-
Specimens)
crete Surfaces Exposed to Deicing Chemicals
C989 Specification for Slag Cement for Use in Concrete and
This guide is under the jurisdiction ofASTM Committee C09 on Concrete and
Mortars
Concrete Aggregates and is the direct responsibility of Subcommittee C09.24 on
C1012/C1012M Test Method for Length Change of
Supplementary Cementitious Materials.
Hydraulic-Cement Mortars Exposed to a Sulfate Solution
Current edition approved Aug. 1, 2011. Published September 2011. DOI:
10.1520/C1709-11.
C1064/C1064M Test Method for Temperature of Freshly
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Mixed Hydraulic-Cement Concrete
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
C1202 Test Method for Electrical Indication of Concrete’s
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. Ability to Resist Chloride Ion Penetration
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
C1709 − 11
C1218/C1218M Test Method for Water-Soluble Chloride in technicalandeconomicbenefitsofSCMhavebeenrecognized,
Mortar and Concrete and as sustainability and environmental awareness resulted in
C1240 Specification for Silica Fume Used in Cementitious the need to develop new materials and new ways to use
Mixtures materials not previously utilized, new sources of potential
C1293 Test Method for Determination of Length Change of SCM are being proposed for use in concrete as ASCM.
Concrete Due to Alkali-Silica Reaction
4.2 If an ASCM does not yet have a significant record of
C1543 Test Method for Determining the Penetration of
performance in concrete, a comprehensive evaluation based on
Chloride Ion into Concrete by Ponding
this Guide should be undertaken, and it should be recognized
C1556 Test Method for Determining the Apparent Chloride
that this ASCM might be introduced for a specific project or
Diffusion Coefficient of Cementitious Mixtures by Bulk
into a limited marketplace to initially demonstrate its perfor-
Diffusion
mance. The user should bear in mind the intended end use of
C1567 Test Method for Determining the Potential Alkali-
the ASCM and use appropriate test methods to establish its
Silica Reactivity of Combinations of Cementitious Mate-
suitability. An ASCM that demonstrates good performance
rials and Aggregate (Accelerated Mortar-Bar Method)
through a comprehensive evaluation as outlined in this guide
C1585 Test Method for Measurement of Rate ofAbsorption
couldthenbeconsideredtohaveaccesstobroadermarketsand
of Water by Hydraulic-Cement Concretes
could be considered for inclusion in an ASTM standard for
C1679 Practice for Measuring Hydration Kinetics of Hy-
SCM. For this reason, the test program to demonstrate accept-
draulic Cementitious Mixtures Using Isothermal Calorim-
able performance should include concrete mixtures with a
etry
range of characteristics specific to the ASCM’s intended use.
C1702 Test Method for Measurement of Heat of Hydration
4.3 Intheabsenceoflong-termdurabilityoracceptablefield
of Hydraulic Cementitious Materials Using Isothermal
performance, prospective users are advised to apply appropri-
Conduction Calorimetry
ate risk management and engineering practice in the use of an
D3987 Practice for Shake Extraction of Solid Waste with
ASCM.
Water
D4326 Test Method for Major and Minor Elements in Coal
5. Evaluation Program
and Coke Ash By X-Ray Fluorescence
2.2 ACI Standards:
5.1 Classification of Materials—The performance of the
ACI 211.1 Standard Practice for Selecting Proportions for
evaluated ASCM should be compared to that of one of the
Normal, Heavyweight and Mass Concrete
existing types of SCM as listed in 1.1. The ASCM should not
ACI 318 Building Code Requirements for Structural Con-
be classified as being a variant of, or equivalent to, an existing
crete and Commentary
type of SCM. The material should be described as an “alter-
native supplementary cementitious material (ASCM).” The
3. Terminology
process that is responsible for generating theASCM should be
3.1 Definitions:
indicated on any reports such that any significant variations in
3.1.1 For definitions of terms used in this guide, refer to
that process would be noted when it occurs.
Terminology C125.
5.2 Evaluation of the Material:
3.2 Definitions of Terms Specific to This Standard:
5.2.1 General—Evaluate the ASCM in a comprehensive
3.2.1 alternative supplementary cementitious materials
laboratorytestprogramfollowedbyfieldtrials.Asampleofthe
(ASCM), n—inorganic materials that react pozzolanically or
ASCM used for this evaluation should be representative of its
hydraulically, and beneficially contribute to the strength,
source. A phased program suitable for many types of ASCMs
durability, workability, or other characteristics of concrete, and
is as follows:
does not meet Specifications C618, C989, and C1240.
Stage I—Characterization of the Material
3.2.2 supplementary cementitious materials (SCM), n—a Stage II—Determination of Suitable Fineness
slag cement or pozzolan that contributes to the properties of
Stage III—Testing to Specification C618, C989,or C1240
concrete or mortar through hydraulic or pozzolanic activity or
Stage IV—Concrete Performance Tests
both; and meets one of the following: Specification C618,
Stage V—Field Trials and Long-Term Performance and
C989,or C1240.
Durability
5.2.2 Stage I: Characterization of the Material—Conduct a
4. Significance and Use
chemical analysis of the material. The chemical analysis
4.1 Common types of SCM include fly ash, slag cement,
should include the quantity of major, minor, and trace element
calcined clays, and silica fume. The introduction and wide-
constituents using any relevant method including x-ray
spread use of fly ash, slag cement, calcined clay, and silica
fluorescence, atomic absorption spectroscopy, inductively
fume have been characterized and supported by significant
coupled plasma spectroscopy, and any appropriate standard
research and development programs, preconstruction testing,
methods in Test Methods C114, C311, and D4326. When
field testing and long term performance monitoring. As the
interpreting the data, consideration should be given to the
potential for the compounds present to be injurious to the
hydration of cement or properties of the concrete. If such
Available fromAmerican Concrete Institute (ACI), P.O. Box 9094, Farmington
Hills, MI 48333-9094, http://www.concrete.org. compoundsarepresent,thensuitabletestsshouldbeconducted
C1709 − 11
to determine the “availability” of these compounds to partici- should be evaluated in a broad range of concr
...

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