ASTM D2109-01(2022)
(Test Method)Standard Test Methods for Nonvolatile Matter in Halogenated Organic Solvents and Their Admixtures
Standard Test Methods for Nonvolatile Matter in Halogenated Organic<brk/> Solvents and Their Admixtures
SIGNIFICANCE AND USE
3.1 Nonvolatile matter in solvents can adversely affect their cleaning properties. These test methods can be used to control soil contamination in the boiling solvent, which if allowed to become too high, can decrease the stability of the solvent.
3.2 These test methods can be used to establish manufacturing and purchasing specifications.
SCOPE
1.1 These test methods cover the determination of nonvolatile matter in halogenated organic solvents and admixtures.
1.2 Five test methods are covered, as follows:
1.2.1 Test Method A—For halogenated organic solvents or admixtures having less than 50 ppm nonvolatile matter; or where precision better than ±10 ppm is required.
1.2.2 Test Method B—For halogenated organic solvents or admixtures having more than 50 ppm nonvolatile matter or where precision of ±0.001 % (10 ppm) is satisfactory.
1.2.3 Test Method C—For low-boiling halogenated organic solvents or their admixtures (for example, methylene chloride, trichlorotrifluoroethane) that may superheat and cause bumping while evaporating to dryness with steam. A precision of greater than ±10 ppm can be attained.
1.2.4 Test Method D—For rapid measurement of nonvolatile matter in halogenated organic solvents and their admixtures and where precision better than ±10 ppm is required.
1.2.5 Test Method E—For halogenated organic solvents or admixtures and where precision better than ±10 ppm is required.
1.3 The values stated in SI units are to be regarded as standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D2109 − 01 (Reapproved 2022)
Standard Test Methods for
Nonvolatile Matter in Halogenated Organic
1
Solvents and Their Admixtures
This standard is issued under the fixed designation D2109; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope 2. Terminology
1.1 These test methods cover the determination of nonvola- 2.1 Definitions of Terms Specific to This Standard:
tile matter in halogenated organic solvents and admixtures. 2.1.1 The term nonvolatile matter should not be construed
as equivalent to residue on ignition, ignition residue, or ash
1.2 Five test methods are covered, as follows:
content. Particulates, sediments, and suspended matter should
1.2.1 Test Method A—For halogenated organic solvents or
not be considered part of nonvolatile matter. If these solids are
admixtures having less than 50 ppm nonvolatile matter; or
present in the sample, they should be removed by filtration or
where precision better than 610 ppm is required.
decantation prior to beginning this test method. Nonvolatile
1.2.2 Test Method B—For halogenated organic solvents or
matter is considered to be “in solution” with the solvent and
admixtures having more than 50 ppm nonvolatile matter or
that which will become residual upon drying the solvent at a
where precision of 60.001% (10 ppm) is satisfactory.
specified temperature.
1.2.3 Test Method C—For low-boiling halogenated organic
2.1.2 Nonvolatile matter and nonvolatile residue are inter-
solvents or their admixtures (for example, methylene chloride,
changeable terms.
trichlorotrifluoroethane) that may superheat and cause bump-
ing while evaporating to dryness with steam. A precision of
3. Significance and Use
greater than 610 ppm can be attained.
3.1 Nonvolatile matter in solvents can adversely affect their
1.2.4 Test Method D—Forrapidmeasurementofnonvolatile
cleaning properties. These test methods can be used to control
matter in halogenated organic solvents and their admixtures
soil contamination in the boiling solvent, which if allowed to
and where precision better than 610 ppm is required.
become too high, can decrease the stability of the solvent.
1.2.5 Test Method E—For halogenated organic solvents or
admixtures and where precision better than 610 ppm is
3.2 These test methods can be used to establish manufac-
required.
turing and purchasing specifications.
1.3 The values stated in SI units are to be regarded as
4. Apparatus
standard.
4.1 Oven, thermostatically controlled at 105°C 6 5°C.
1.4 This standard does not purport to address all of the
4.2 Evaporating Dish, 125mL capacity, platinum or high-
safety concerns, if any, associated with its use. It is the
silica glass, Methods A, B, C.
responsibility of the user of this standard to establish appro-
priate safety, health, and environmental practices and deter-
4.3 Evaporating Dish (80 × 45 or 115 × 50) (Method D).
mine the applicability of regulatory limitations prior to use.
4.4 Steam Bath (or hot plate).
1.5 This international standard was developed in accor-
4.5 Hot Plate, (Method D).
dance with internationally recognized principles on standard-
ization established in the Decision on Principles for the
4.6 Heat Lamp, 250 W, (Method E).
Development of International Standards, Guides and Recom-
4.7 Analytical Balance, capable of measuring to 0.0001 g.
mendations issued by the World Trade Organization Technical
4.8 Top Loading Balance, capable of weighing to 0.01 g.
Barriers to Trade (TBT) Committee.
4.9 Aluminum Weighing Dish, 57 × 18 mm, (Method D).
1
These test methods are under the jurisdiction of ASTM Committee D26 on
4.10 Aluminum Weighing Dish, 200 mL capacity, (Method
Halogenated Organic Solvents and Fire Extinguishing Agents and are the direct
E).
responsibility of Subcommittee D26.04 on Test Methods.
Current edition approved May 1, 2022. Published May 2022. Originally
4.11 1000 mL Volumetric Flask (Test Method A).
approved in 1962 as D2109-62 T. Last previous edition approved in 2016 as
D2109-01(2016). DOI: 10.1520/D2109-01R22. 4.12 100 mL Volumetric Pipet (Test Method B and E).
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
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D2109 − 01 (2022)
4.13 1000 mL Graduated Cylinder (Test Method C). 8.2 Evaporate the sample to dryness as in
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