Standard Practice for Active Soil Gas Sampling in the Vadose Zone for Vapor Intrusion Evaluations

SIGNIFICANCE AND USE
Soil-gas sampling results can be dependent on numerous factors both within and outside the control of the sampling personnel. Key variables are identified and briefly discussed below. Please see the documents listed in the Bibliography for more detailed information on the effect of various variables.
Application—The techniques described in this standard practice are suitable for collecting samples for subsequent analysis for VOCs by US EPA Method TO-15, US EPA Method TO-17, Test Method D5466, Practice D6196, or other VOC methods (for example, ISO 16017-1, US EPA Methods TO-3 and TO-12). In general, off-site analysis is employed when data are needed for input to a human health risk assessment and low- or sub-ppbv analytical sensitivity is required. On-site analysis typically has lesser analytical sensitivity and tends to be employed for screening level studies. The techniques also may prove useful for analytical categories other than VOCs, such as methane, ammonia, mercury, or hydrogen sulfide (See Test Method D5504).
Limitations:
This method only addresses collection of gas-phase species. Less volatile compounds, such as SVOCs, may be present in the environment both in the gas phase and sorbed onto particulate matter, as well as in liquid phase. In soil gas, the gas-phase fraction is the primary concern. In other potential sampling locations (for example, ambient or indoor air), however, sampling for the particulate phase fraction may also be of interest.
The data produced using this method should be representative of the soil gas concentrations in the geological materials in the immediate vicinity of the sample probe or well at the time of sample collection (that is, they represent a point-in-time and point-in-space measurement). The degree to which these data are representative of any larger areas or different times depends on numerous site-specific factors.
Effect of Purging of Dead Space—If a soil gas probe is to be sampled soon after installation, ...
SCOPE
1.1 Purpose—This practice covers standardized techniques for actively collecting soil gas samples from the vadose zone beneath or near dwellings and other buildings.
1.2 Objectives—Objectives guiding the development of this practice are: (1) to synthesize and put in writing good commercial and customary practice for active soil gas sampling, (2) to provide an industry standard for soil gas sampling performed in support of vapor intrusion evaluations that is practical and reasonable.
1.3 This practice allows a variety of techniques to be used for collecting soil gas samples because different techniques may offer certain advantages for specific applications. Three techniques are presented: sampling at discrete depths, sampling over a small screened interval, and sampling using permanent vapor monitoring wells.
1.4 Some of the recommendations require knowledge of pressure differential and tracer gas concentration measurements.
1.5 The values stated in SI units shall be regarded as standard. Other units are shown for information only.
1.6 This practice does not address requirements of any federal, state, or local regulations or guidance, or both, with respect to soil gas sampling. Users are cautioned that federal, state, and local guidance may impose specific requirements that differ from those of this practice.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
1.8 This practice offers a set of instructions for performing one or more specific operations. This document cannot replace education or experience and should be used in conjunction with professional judgment. Not all aspects of this practice may be applicable in all circumstances. This ASTM practice is not intended to rep...

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Publication Date
14-Mar-2012
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D7663 − 12
Standard Practice for
Active Soil Gas Sampling in the Vadose Zone for Vapor
1
Intrusion Evaluations
This standard is issued under the fixed designation D7663; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope professional judgment. Not all aspects of this practice may be
applicable in all circumstances. This ASTM practice is not
1.1 Purpose—This practice covers standardized techniques
intended to represent or replace the standard of care by which
for actively collecting soil gas samples from the vadose zone
the adequacy of a given professional service must be judged,
beneath or near dwellings and other buildings.
nor should this document be applied without consideration of
1.2 Objectives—Objectives guiding the development of this
a project’s many unique aspects. The word “Standard” in the
practice are: (1) to synthesize and put in writing good com-
title means only that the document has been approved through
mercialandcustomarypracticeforactivesoilgassampling,(2)
the ASTM consensus process.
toprovideanindustrystandardforsoilgassamplingperformed
in support of vapor intrusion evaluations that is practical and
2. Referenced Documents
reasonable.
2
2.1 ASTM Standards:
1.3 This practice allows a variety of techniques to be used
D653 Terminology Relating to Soil, Rock, and Contained
for collecting soil gas samples because different techniques
Fluids
may offer certain advantages for specific applications. Three
D854 Test Methods for Specific Gravity of Soil Solids by
techniquesarepresented:samplingatdiscretedepths,sampling
Water Pycnometer
over a small screened interval, and sampling using permanent
D1356 Terminology Relating to Sampling and Analysis of
vapor monitoring wells.
Atmospheres
D1946 Practice for Analysis of Reformed Gas by Gas
1.4 Some of the recommendations require knowledge of
Chromatography
pressure differential and tracer gas concentration measure-
D2216 Test Methods for Laboratory Determination ofWater
ments.
(Moisture) Content of Soil and Rock by Mass
1.5 The values stated in SI units shall be regarded as
D2487 Practice for Classification of Soils for Engineering
standard. Other units are shown for information only.
Purposes (Unified Soil Classification System)
1.6 This practice does not address requirements of any
D3404 Guide for Measuring Matric Potential in Vadose
federal, state, or local regulations or guidance, or both, with
Zone Using Tensiometers
respect to soil gas sampling. Users are cautioned that federal,
D4696 Guide for Pore-Liquid Sampling from the Vadose
state, and local guidance may impose specific requirements
Zone
that differ from those of this practice.
D4700 Guide for Soil Sampling from the Vadose Zone
1.7 This standard does not purport to address all of the D5088 Practice for Decontamination of Field Equipment
safety concerns, if any, associated with its use. It is the Used at Waste Sites
responsibility of the user of this standard to establish appro- D5092 Practice for Design and Installation of Groundwater
priate safety and health practices and determine the applica- Monitoring Wells
bility of regulatory limitations prior to use. D5314 Guide for Soil Gas Monitoring in the Vadose Zone
1.8 This practice offers a set of instructions for performing D5466 Test Method for Determination of Volatile Organic
one or more specific operations. This document cannot replace Chemicals inAtmospheres (Canister Sampling Methodol-
ogy)
educationorexperienceandshouldbeusedinconjunctionwith
D5504 TestMethodforDeterminationofSulfurCompounds
1
This practice is under the jurisdiction of ASTM Committee D18 on Soil and
Rock and is the direct responsibility of Subcommittee D18.21 on Groundwater and
2
Vadose Zone Investigations. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved March 15, 2012. Published April 2012. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 2011. Last previous edition approved in 2011 as D7663–11. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D7663-12. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D7663 − 12
in Natural Gas and Gaseous Fuels by Gas Chromatogra- 3.2.10 effective porosity, n—the amount of interconnected
phy and Chemiluminescence voidspace(withinintergranularpores,fractures,openings,and
the like) available for fluid movement: generally less than total
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D7663 − 11 D7663 − 12
Standard Practice for
Active Soil Gas Sampling in the Vadose Zone for Vapor
1
Intrusion Evaluations
This standard is issued under the fixed designation D7663; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 Purpose—This practice covers standardized techniques for actively collecting soil gas samples from the vadose zone
beneath or near dwellings and other buildings.
1.2 Objectives—Objectives guiding the development of this practice are: (1) to synthesize and put in writing good commercial
and customary practice for active soil gas sampling, (2) to provide an industry standard for soil gas sampling performed in support
of vapor intrusion evaluations that is practical and reasonable.
1.3 This practice allows a variety of techniques to be used for collecting soil gas samples because different techniques may offer
certain advantages for specific applications. Three techniques are presented: sampling at discrete depths, sampling over a small
screened interval, and sampling using permanent vapor monitoring wells.
1.4 Some of the recommendations require knowledge of pressure differential and tracer gas concentration measurements.
1.5 The values stated in SI units are to shall be regarded as standard. Other units are shown for information only.
1.6 This practice does not address requirements of any federal, state, or local regulations or guidance, or both, with respect to
soil gas sampling. Users are cautioned that federal, state, and local guidance may impose specific requirements that differ from
those of this practice.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
1.8 This practice offers a set of instructions for performing one or more specific operations. This document cannot replace
education or experience and should be used in conjunction with professional judgment. Not all aspects of this practice may be
applicable in all circumstances. This ASTM practice is not intended to represent or replace the standard of care by which the
adequacy of a given professional service must be judged, nor should this document be applied without consideration of a project’s
many unique aspects. The word “Standard” in the title means only that the document has been approved through the ASTM
consensus process.
2. Referenced Documents
2
2.1 ASTM Standards:
D653 Terminology Relating to Soil, Rock, and Contained Fluids
D854 Test Methods for Specific Gravity of Soil Solids by Water Pycnometer
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D1946 Practice for Analysis of Reformed Gas by Gas Chromatography
D2216 Test Methods for Laboratory Determination of Water (Moisture) Content of Soil and Rock by Mass
D2487 Practice for Classification of Soils for Engineering Purposes (Unified Soil Classification System)
D3404 Guide for Measuring Matric Potential in Vadose Zone Using Tensiometers
D4696 Guide for Pore-Liquid Sampling from the Vadose Zone
D4700 Guide for Soil Sampling from the Vadose Zone
1
This practice is under the jurisdiction of ASTM Committee D18 on Soil and Rock and is the direct responsibility of Subcommittee D18.21 on Groundwater and Vadose
Zone Investigations.
Current edition approved April 15, 2011March 15, 2012. Published May 2011April 2012. Originally approved in 2011. Last previous edition approved in 2011 as
D7663–11. DOI: 10.1520/D7663-11.10.1520/D7663-12.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D7663 − 12
D5088 Practice for Decontamination of Field Equipment Used at Waste Sites
D5092 Practice for Design and Installation of Ground Water Monitoring Wells
D5314 Guide for Soil Gas Monitoring in the Vadose Zone
D5466 Test Method for Determination of Volatile Organic Che
...

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