EN 16319:2013

Fertilizers - Determination of trace elements - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution

This European Standard specifies a method for the determination of the content of cadmium, chromium, nickel and lead in fertilizers with inductively coupled plasma atomic emission spectrometry (ICP-AES) after extraction with aqua regia. Limits of quantification are dependent on the sample matrix as well as on the instrument, but can roughly be expected to be 0,3 mg/kg for Cd and 1 mg/kg for Cr, Ni and Pb.
NOTE   Due to significant interference from Cu, Fe and Mn, no valid results can be reported using this method for fertilizer matrices containing high concentrations (>/= 10 %) of these micro-nutrients.

Düngemittel - Bestimmung von Elementspuren - Bestimmung von Cadmium, Chrom, Blei und Nickel mit Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach Königswasseraufschluss

Diese Europäische Norm legt ein Verfahren zur Bestimmung des Gehalts an Cadmium, Chrom, Nickel und Blei in Düngemitteln mit Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach Königswasseraufschluss fest. Die Bestimmungsgrenzen sind sowohl von der Probenmatrix als auch vom verwendeten Gerät abhängig, werden jedoch etwa bei 0,3 mg/kg für Cd und 1 mg/kg für Cr, Ni und Pb erwartet.
ANMERKUNG   Aufgrund signifikanter Störungen durch Cu, Fe und Mn können bei Anwendung dieses Verfahrens für Düngemittelmatrizes mit hohen Konzentrationen (≥ 10 %) dieser Spurennährstoffe keine zuverlässigen Ergebnisse ausgewiesen werden.

Engrais - Dosage des éléments trace - Détermination du cadmium, chrome, plomb et nickel par spectrométrie d'émission atomique avec plasma induit par haute fréquence (ICP-AES) après digestion à l'eau régale

La présente norme européenne spécifie une méthode permettant de déterminer la teneur en cadmium, chrome, nickel et plomb dans les engrais par spectrométrie d’émission atomique avec plasma à couplage inductif (ICP-AES) après extraction à l’eau régale. Les limites de quantification dépendent de la matrice de l’échantillon ainsi que de l’instrument, mais peuvent être attendues de l’ordre de 0,3 mg/kg pour Cd et 1 mg/kg pour Cr, Ni et Pb.
NOTE Du fait d’une interférence significative du Cu, Fe et Mn, aucun résultat valide ne peut être donné en utilisant cette méthode pour les matrices engrais contenants des concentrations élevés (≥ 10%) en ces oligo-éléments.

Gnojila - Določevanje elementov v sledovih - Določevanje kadmija, kroma, svinca in niklja z atomsko emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP-AES) po raztapljanju v zlatotopki

Ta evropski standard določa metodo za določevanje vsebnosti kadmija, kroma, niklja in svinca v gnojilih z atomsko emisijsko spektrometrijo z induktivno sklopljeno plazmo (ICP-AES) po ekstrakciji z zlatotopko. Meje kvantifikacije so odvisne od matrice vzorca in instrumenta, vendar za Cd običajno znašajo približno 0,3 mg/kg, za Cr, Ni in Pb pa 1 mg/kg.

General Information

• Status: Withdrawn
• Publication Date: 22-Oct-2013
• Withdrawal Date: 22-Dec-2015
• ICS: 65.080 - Fertilizers
• Technical Committee: CEN/TC 260 - Fertilizers and liming materials
• Drafting Committee: CEN/TC 260/WG 7 - Chemical analysis
• Current Stage: 9960 - Withdrawal effective - Withdrawal
• Completion Date: 23-Dec-2015
• Directive: 2003/2003 - Regulation (EC) N° 2003/2003 of the European Parlament and of the council of 13 October 2003 relating to fertilisers
• Directive: 2019/1009 - Regulation (EU) 2019/1009 of the European Parliament and of the Council of 5 June 2019 laying down rules on the making available on the market of EU fertilising products and amending Regulations (EC) No 1069/2009 and (EC) No 1107/2009 and repealing Regulation (EC) No 2003/2003
• Mandate: M/418 - Standardization mandate M/335 assigned to CEN concerning the modernisation of the methods of analysis of fertilizers
• Ref Project: SIST EN 16319:2013 - Fertilizers - Determination of trace elements - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution

Relations

• Replaces: CEN/TS 16319:2012 - Fertilizers - Determination of trace elements - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution
• Effective Date: 30-Oct-2013
• Merged Into: EN 16319:2013+A1:2015 - Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution
• Effective Date: 21-Oct-2015
• Amended By: EN 16319:2013/FprA1:2015 - Fertilizers and liming materials - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution
• Effective Date: 18-Sep-2013

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Düngemittel - Bestimmung von Elementspuren - Bestimmung von Cadmium, Chrom, Blei und Nickel mit Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach KönigswasseraufschlussEngrais - Dosage des éléments traces - Détermination du cadmium, chromium, plomb et nickel par spectrométrie d'émission atomique avec plasma induit par haute fréquence (ICP-AES) après digestion à l'eau régaleFertilizers - Determination of trace elements - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution65.080GnojilaFertilizersICS:Ta slovenski standard je istoveten z:EN 16319:2013SIST EN 16319:2013en,fr,de01-december-2013SIST EN 16319:2013SLOVENSKI
STANDARDSIST-TS CEN/TS 16319:20121DGRPHãþD



SIST EN 16319:2013



EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16319
October 2013 ICS 65.080 Supersedes CEN/TS 16319:2012English Version
Fertilizers - Determination of trace elements - Determination of cadmium, chromium, lead and nickel by inductively coupled plasma-atomic emission spectrometry (ICP-AES) after aqua regia dissolution
Engrais - Dosage des éléments trace - Détermination du cadmium, chrome, plomb et nickel par spectrométrie d'émission atomique avec plasma induit par haute fréquence (ICP-AES) après digestion à l'eau régale
Düngemittel - Bestimmung von Elementspuren - Bestimmung von Cadmium, Chrom, Blei und Nickel mit Atomemissionsspektrometrie mit induktiv gekoppeltem Plasma (ICP-AES) nach Königswasseraufschluss This European Standard was approved by CEN on 15 September 2013.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16319:2013: ESIST EN 16319:2013



EN 16319:2013 (E) 2 Contents Page Foreword .3 1 Scope .4 2 Normative references .4 3 Terms and definitions .4 4 Principle .4 5 Sampling and sample preparation .4 6 Reagents .4 7 Apparatus .5 8 Procedure .6 8.1 General .6 8.2 Preparation of the test solution .6 8.2.1 General .
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