Agglomerated stone - Test methods - Part 10: Determination of chemical resistance

This document specifies a method for determination of the chemical resistance and the resistance to stains of agglomerated stones (see prEN 14618) with polished surface after a prolonged contact with chemical materials.
NOTE   It is reminded that the agglomerated stone containing calcium carbonate aggregates are sensitive to any acid attack.

Künstlich hergestellter Stein - Prüfverfahren - Teil 10: Bestimmung der chemischen Beständigkeit

Dieses Dokument legt ein Verfahren zur Bestimmung der chemischen Beständigkeit und der Beständigkeit
gegen Verfärbung von künstlich hergestellten Steinen (siehe prEN 14618) mit polierter Oberfläche fest, die
über eine längere Dauer mit Chemikalien in Kontakt gekommen sind.
ANMERKUNG Es wird daran erinnert, dass künstlich hergestellter Stein, der Calciumcarbonat enthält, für Säureangriffe
anfällig ist.

Pierre agglomérée - Méthodes d'essai - Partie 10: Détermination de la résistance chimique

Le présent document spécifie une méthode de détermination de la résistance chimique et de la résistance aux taches après un contact prolongé avec des produits chimiques des pierres agglomérées polies (voir EN 14618).
NOTE   Il est rappelé que les pierres agglomérées contenant des granulats en carbonate de calcium sont sensibles à toute attaque acide.

Aglomeriran kamen - Preskusne metode - 10. del: Ugotavljanje kemijske odpornosti

General Information

Status
Withdrawn
Publication Date
15-Mar-2005
Withdrawal Date
10-Apr-2012
Current Stage
9960 - Withdrawal effective - Withdrawal
Start Date
11-Apr-2012
Completion Date
11-Apr-2012

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SLOVENSKI STANDARD
01-julij-2005
Aglomeriran kamen - Preskusne metode - 10. del: Ugotavljanje kemijske
odpornosti
Agglomerated stone - Test methods - Part 10: Determination of chemical resistance
Künstlich hergestellter Stein - Prüfverfahren - Teil 10: Bestimmung der chemischen
Beständigkeit
Pierre agglomérée - Méthodes d'essai - Partie 10: Détermination de la résistance
chimique
Ta slovenski standard je istoveten z: EN 14617-10:2005
ICS:
91.100.15 Mineralni materiali in izdelki Mineral materials and
products
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN 14617-10
NORME EUROPÉENNE
EUROPÄISCHE NORM
March 2005
ICS 91.100.15
English version
Agglomerated stone - Test methods - Part 10: Determination of
chemical resistance
Pierre agglomérée - Méthodes d'essai - Partie 10: Künstlich hergestellter Stein - Prüfverfahren - Teil 10:
Détermination de la résistance chimique Bestimmung der chemischen Beständigkeit
This European Standard was approved by CEN on 3 February 2005.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official
versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,
Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,
Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36  B-1050 Brussels
© 2005 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 14617-10:2005: E
worldwide for CEN national Members.

Contents
Page
Foreword.3
1 Scope .4
2 Normative references .4
3 Principle.4
4 Determination of the chemical resistance .4
Annex A (informative) Determination of the resistance to stains .8
Bibliography .11

Foreword
This document (EN 14617-10:2005) has been prepared by Technical Committee CEN/TC 246 “Natural stones”, the
secretariat of which is held by UNI.
This European Standard shall be given the status of a national standard, either by publication of an identical text or
by endorsement, at the latest by September 2005, and conflicting national standards shall be withdrawn at the
latest by September 2005.
Test methods for agglomerated stones consist of the following:
EN 14617-1, Agglomerated stone - Test methods – Part 1: Determination of apparent density and water absorption
EN 14617-2, Agglomerated stone – Test methods – Part 2: Determination of flexural strength (bending)
prEN 14617-3, Agglomerated stone - Test methods – Part 3: Determination of slipperiness
EN 14617-4, Agglomerated stone - Test methods – Part 4: Determination of the abrasion resistance
EN 14617-5, Agglomerated stone - Test methods – Part 5: Determination of freeze and thaw resistance
EN 14617-6, Agglomerated stone - Test methods – Part 6: Determination of thermal shock resistance
prEN 14617-7, Agglomerated stone – Test methods – Part 7: Determination of ageing
prEN 14617-8, Agglomerated stone – Test methods – Part 8: Determination of resistance to fixing (dowel hole)
EN 14617-9, Agglomerated stone - Test methods – Part 9: Determination of impact resistance
EN 14617-10, Agglomerated stone – Test methods – Part 10: Determination of chemical resistance
EN 14617-11, Agglomerated stone – Test methods – Part 11: Determination of linear thermal expansion coefficient
EN 14617-12, Agglomerated stone – Test methods – Part 12: Determination of dimensional stability
EN 14617-13, Agglomerated stone – Test methods – Part 13: Determination of electrical resistivity
prEN 14617-14, Agglomerated stone – Test methods – Part 14: Determination of surface hardness
EN 14617-15, Agglomerated stone – Test methods – Part 15: Determination of compressive strength
EN 14617-16, Agglomerated stone – Test methods – Part 16: Determination of dimensions, geometric characteristics
and surface quality of modular tiles
prEN 14617-17, Agglomerated stone – Test methods – Part 17: Determination of biological resistance
According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries
are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
1 Scope
This document specifies a method for determination of the chemical resistance and the resistance to stains of
agglomerated stones (see EN 14618) with polished surface after a prolonged contact with chemical materials.
NOTE It is reminded that the agglomerated stone containing calcium carbonate aggregates are sensitive to any acid
attack.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated references,
only the edition cited applies. For undated references, the latest edition of the referenced document (including any
amendments) applies.
Not applicable.
3 Principle
The resistance to a chemical attack is the characteristic which defines the behaviour of a floor/wall covering
material in contact with chemically aggressive agents, that is potentially able, to react with the surface itself,
corroding it, penetrating it permanently or anyway altering the visible aspect.
The deteriorating action of the chemical aggressive can generate two different effects:
− a real chemical action, according to which the alteration of the surface is due to the chemical reaction between
the aggressive agent and some constituents of the surface itself;
− a physical absorbing action, in accordance to which the aggressive agent is able to penetrate the surface, so
that the removal is extremely difficult or not possible.
Both these actions can involve a modification of the visible appearance of the surface of the chemical attacked
material, but only in the first case the damage can introduce also a modification in the physical and mechanical
properties of the material itself.
4 Determination of the chemical resistance
4.1 Chemical reagents
4.1.1 Water solution containing hydrochloric acid solution, 50 % (V/V), prepared from N hydrochloric acid
solution;
4.1.2 Sodium hydroxide in a 50 % (V/V) water solution, prepared from a normal water sodium hydroxide not
carbonated solution
4.2 Apparatus
Glossmeter able to measure with accuracy and precision of 10% the brightness degree of the surface.
The glossmeter shall measure the reflection of a light ray incident on a surface; the reflection degree is given by the
amount of light specularly reflected in a point of the surface with relationship to the amount of light reflected by the
standard glass plate. A light source representing the average daylight shall be used, such as the source CIE D 65,
with the lighting intensity allowed by the glossmeter calibration.
The glossmeter shall, at least, be equipped with two optical systems placed at 60° and 20° angles.It allows an
efficient measurement of the different reflection directions as the 60° angle covers a range of reflection degrees
from low to high, while the 20° angle allows to measure with greater accuracy the higher reflection directions (see
Annex A).
4.3 Preparation of the specimens
For each type of material to be tested four samples shall be prepared, with polished surface (at least 70
...

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