EN 1302:2024

Chemicals used for treatment of water intended for human consumption - Aluminium-based coagulants - Analytical methods

This document is applicable to aluminium-based coagulants used for treatment of water intended for human consumption. It specifies analytical methods to be used for products described in EN 878, EN 882, EN 885, EN 886, EN 887, EN 935 and EN 17034.

Produkte zur Aufbereitung von Wasser für den menschlichen Gebrauch - Flockungsmittel auf Aluminiumbasis - Analytische Methoden

Dieses Dokument ist anwendbar für Flockungsmittel auf Aluminiumbasis zur Aufbereitung von Wasser für den menschlichen Gebrauch. Es legt die zu verwendenden analytischen Methoden für die Produkte fest, die in EN 878, EN 882, EN 885, EN 886, EN 887, EN 935 und EN 17034 beschrieben sind.

Produits chimiques utilisés pour le traitement de l'eau destinée à la consommation humaine - Coagulants à base d'aluminium - Méthodes d'analyse

Le présent document est applicable aux coagulants à base d’aluminium utilisés pour le traitement de l’eau destinée à la consommation humaine. Il spécifie les méthodes d’analyse à utiliser pour les produits décrits dans les normes EN 878, EN 882, EN 885, EN 886, EN 887, EN 935 et EN 17034.

Kemikalije, ki se uporabljajo za pripravo pitne vode - Koagulanti na osnovi aluminija - Analitske metode

General Information

• Status: Published
• Publication Date: 03-Dec-2024
• ICS: 71.100.80 - Chemicals for purification of water
• Technical Committee: CEN/TC 164 - Water supply
• Drafting Committee: CEN/TC 164/WG 9 - Drinking water treatment
• Current Stage: 6060 - Definitive text made available (DAV) - Publishing
• Start Date: 04-Dec-2024
• Due Date: 13-Dec-2023
• Completion Date: 04-Dec-2024
• Ref Project: kSIST FprEN 1302:2024 - Chemicals used for treatment of water intended for human consumption - Aluminium-based coagulants - Analytical methods

Relations

• Replaces: EN 1302:1999/AC:2002 - Chemicals used for treatment of water intended for human consumption - Aluminium-based coagulants - Analytical methods
• Effective Date: 11-Dec-2024
• Replaces: EN 1302:1999 - Chemicals used for treatment of water intended for human consumption - Aluminium-based coagulants - Analytical methods
• Effective Date: 07-Jul-2021

Standards Content (Sample)

SLOVENSKI STANDARD
oSIST prEN 1302:2023
01-julij-2023
Kemikalije, ki se uporabljajo za pripravo pitne vode - Koagulanti na osnovi
aluminija - Analitske metode
Chemicals used for treatment of water intended for human consumption - Aluminium-
based coagulants - Analytical methods
Produkte zur Aufbereitung von Wasser für den menschlichen Gebrauch -
Flockungsmittel auf Aluminiumbasis - Analytische Methoden
Produits chimiques utilisés pour le traitement de l'eau destinée à la consommation
humaine - Coagulants à base d'aluminium - Méthodes d'analyse
Ta slovenski standard je istoveten z: prEN 1302
ICS:
13.060.20 Pitna voda Drinking water
71.100.80 Kemikalije za čiščenje vode Chemicals for purification of
water
oSIST prEN 1302:2023 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

oSIST prEN 1302:2023
oSIST prEN 1302:2023
DRAFT
EUROPEAN STANDARD
prEN 1302
NORME EUROPÉENNE
EUROPÄISCHE NORM
May 2023
ICS 71.100.80 Will supersede EN 1302:1999
English Version
Chemicals used for treatment of water intended for human
consumption - Aluminium-based coagulants - Analytical
methods
Produits chimiques utilisés pour le traitement de l'eau Produkte zur Aufbereitung von Wasser für den
destinée à la consommation humaine - Coagulants à menschlichen Gebrauch - Flockungsmittel auf
base d'aluminium - Méthodes d'analyse Aluminiumbasis - Analytische Methoden
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 164.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.

EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 1302:2023 E
worldwide for CEN national Members.

oSIST prEN 1302:2023
prEN 1302:2023 (E)
Contents Page
European foreword . 3
1 Scope . 4
2 Normative references . 4
3 Terms and definitions . 4
4 Methods of analysis . 5
5 Sampling . 7
6 Expression of results . 8
6.1 Aluminium content. 8
6.2 Iron . 8
6.3 Sodium, calcium, chloride, sulfate and silicate . 8
6.4 Free acid . 8
6.5 Basicity . 8
6.6 Insoluble matters . 8
6.7 Chemical parameters. 8
6.8 Repeatability . 8
Annex A (normative) Analysis of aluminium content . 9
Annex B (normative) Analysis of chemical parameters and impurities . 15
Annex C (informative) Routine methods . 37
Bibliography . 56

oSIST prEN 1302:2023
prEN 1302:2023 (E)
European foreword
This document (prEN 1302:2023) has been prepared by Technical Committee CEN/TC 164 “Water
supply”, the secretariat of which is held by AFNOR.
This document is currently submitted to the CEN Enquiry.
This document will supersede EN 1302:1999.
In comparison with the previous edition, the following technical modifications have been made:
— Replacement of the withdrawn aluminium product standards EN 881 and EN 883 by EN 17034.
— Replacement of the withdrawn mercury analysing standard ISO 5666-1:1983 by ISO 12846:2012.
— Removal of the withdrawn standard ISO 6382:1981. As there was no replacement, the analysing
method for silicon content based on this standard was removed.
— Removal of routine methods used for determinate arsenic. Method: Silver diethyldithiocarbamate
spectrophotometric method based on standard ISO 6595:1982 as this standard has been
withdrawn without replacement.
— Removal of routine methods used for determinate iron. Method: 1,10-Phenanthroline
spectrophotometric method based on standard ISO 6685:1982 as this standard has been
withdrawn without replacement.
2+
— Removal of a method for determination of iron (total and Fe ) (volumetric method) as EN 5790
has been removed as the standard has been withdrawn without replacement. Furthermore, the
method uses potassium dichromate and there are other options for iron determination.
— Update of the clause titles to correspond the CEN Standard form.
— Update of Table 1 and 2 to correspond the analytical methods available in the standard.
oSIST prEN 1302:2023
prEN 1302:2023 (E)
1 Scope
This document is applicable to aluminium-based coagulants used for treatment of water intended for
human consumption. It specifies analytical methods to be used for products described in EN 878,
EN 882, EN 885, EN 886, EN 887, EN 935 and EN 17034.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 878, Chemicals used for treatment of water intended for human consumption - Aluminium sulfate
EN 882, Chemicals used for treatment of water intended for human consumption - Sodium aluminate
EN 885, Chemicals used for treatment of water intended for human consumption - Polyaluminium chloride
hydroxide silicate
EN 886, Chemicals used for treatment of water intended for human consumption - Polyaluminium
hydroxide silicate sulfate
EN 887, Chemicals used for treatment of water intended for human consumption - Aluminium iron (III)
sulfate
EN 935, Chemicals used for treatment of water intended for human consumption - Aluminium iron(III)
chloride (monomeric) and aluminium iron(III) chloride hydroxide (monomeric)
EN 17034, Chemicals used for treatment of water intended for human consumption - Aluminium chloride
anhydrous, aluminium chloride basic, dialuminium chloride pentahydroxide and aluminium chloride
hydroxide sulfate
EN ISO 3696, Water for analytical laboratory use - Specification and test methods (ISO 3696)
ISO 5725-2, Accuracy (trueness and precision) of measurement methods and results — Part 2: Basic
method for the determination of repeatability and reproducibility of a standard measurement method
ISO 6227:1982, Chemical products for industrial use — General method for determination of chloride ions
— Potentiometric method
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminology databases for use in standardization at the following addresses:

— ISO Online browsing platform: available at https://www.iso.org/obp/
— IEC Electropedia: available at https://www.electropedia.org/
3.1
laboratory sample
sample as prepared for sending to the laboratory and intended for inspection or testing
[SOURCE: ISO 6206:1979]
oSIST prEN 1302:2023
prEN 1302:2023 (E)
3.2
test sample
sample prepared from the laboratory sample and from which test portions will be taken
[SOURCE: ISO 6206:1979]
3.3
test portion
quantity of material drawn from the test sample (or from the laboratory sample if both are the same)
and on which the test or observation is actually carried out
[SOURCE: ISO 6206:1979]
4 Methods of analysis
The methods of analysis are used to analyse the product quality. Table 1 lists the methods which shall
be used for analysis of aluminium-based coagulants composition as commercial product and the
principles of each method. The reference methods which shall be used are described in full in
Annexes A and B. Other methods can be used for quality control.
Table 2 lists the methods which shall be used for analysis of main by-products and chemical
parameters. These are applicable to all aluminium based coagulants (EN 878, EN 882, EN 885, EN 886,
EN 887, EN 935 and EN 17034). The relevant limit value for each coagulant is available in the product
standard.
oSIST prEN 1302:2023
prEN 1302:2023 (E)
Table 1 — Methods of analysis of the composition of commercial product
Reference Informative
Determination EN 878 EN 882 EN 885 EN 886 EN 887 EN 935 EN 17034 Principle Annex
method method
a
x  x  x x x x x EDTA complexometric titration A.1
Aluminium
b
Aluminium  x  x x x x x CDTA complexometric titration Annex A
x
Aluminium x   x      Gluconate A.2
Iron x  x x x x x x x ICP-OES B.8
Iron  x x x x x x x x FAAS A.1
c
Iron
x x x x x x x x ICP-MS
Sodium x  x  x x x x x ICP-OES B.8
Sodium  x   x x    AAS A.1
Sodium  x  x      Gluconate A.2
Calcium  x   x x   x AAS A.1
Calsium x    x x   x ICP-OES B.8
Chloride x    x   x x Potentiometric titration B.1
Sulfate x  x   x x  x Barium sulfate gravimetry B.2
Free acid   x    x x x Acidimetric titration B.4
Basicity x  x x   x x x Acidimetric titration, oxalate method B.5
Basicity     x x    Acidimetric titration, KF method B.6
Basicity  x        Calculation method C.7
Key
AAS: Atomic Absorption Spectrometry
AFS: Atomic Fluorescence Spectrometry
ICP-OES: Inductively Coupled Plasma Optical Emission Spectrometry
ICP-MS: Inductively Coupled Plasma Mass Spectrometry
a
Only applicable for determination of aluminium if iron content is lower than 1,6 g Fe per kilogram of aluminium.
b
The reference method when iron content is higher than 1,6 g Fe per kilogram of aluminium.
c
This document does not give a description for this method of analysis.
oSIST prEN 1302:2023
prEN 1302:2023 (E)
Table 2 — Applicability methods of analysis to main by-products and chemical parameters
Reference Routine
Determination Principle
method method
Insoluble matter B.7  Gravimetry
Arsenic B.8  ICP-OES
C.3 ICP-MS
x AAS
Cadmium B.8  ICP-OES
C.3 ICP-MS
x AAS
Chromium B.8  ICP-OES
x ICP-MS
x AAS
Mercury B.10  AAS (cold vapour)
B.9 AFS
Nickel B.8  ICP-OES
x ICP-MS
x AAS
Lead B.8  ICP-OES
C.3 ICP-MS
x AAS
Antimony B.8  ICP-OES
C.3 ICP-MS
x AAS
Selenium B.8  ICP-OES
C.3 ICP-MS
x AAS
Key
AAS: Atomic Absorption Spectrometry
AFS: Atomic Fluorescence Spectrometry
ICP-OES: Inductively Coupled Plasma Optical Emission Spectrometry
ICP-MS: Inductively Coupled Plasma Mass Spectrometry
5 Sampling
Sampling methods are mentioned in the product standards (EN 878, EN 882, EN 885, EN 886, EN 887,
EN 935 and EN 17034). Choose the relevant sampling method.
From the laboratory sample, prepare the test sample by grinding the solid samples until the particle
size is below 2,5 mm and homogenizing, and homogenize the liquid samples.
oSIST prEN 1302:2023
prEN 1302:2023 (E)
6 Expression of results
6.1 Aluminium content
The aluminium content shall be expressed as aluminium mass fraction in % or as Al in grams per kg of
product.
6.2 Iron
The iron co
...