ISO 7203-2:2011
(Main)Fire extinguishing media — Foam concentrates — Part 2: Specification for medium- and high-expansion foam concentrates for top application to water-immiscible liquids
Fire extinguishing media — Foam concentrates — Part 2: Specification for medium- and high-expansion foam concentrates for top application to water-immiscible liquids
ISO 7203-2:2011 specifies the essential properties and performance of liquid foam concentrates used to make medium- or high-expansion foams or both for the control, extinction and inhibition of reignition of fires of water-immiscible liquids. Minimum performance on certain test fires is specified. These foams are suitable for top application to fires of water-immiscible liquid. Those foams that comply with ISO 7203-1 are also suitable for top application to fires of water-immiscible liquids.
Agents extincteurs — Émulseurs — Partie 2: Spécifications pour les émulseurs moyen et haut foisonnements destinés à une application par le haut sur les liquides non miscibles à l'eau
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Standards Content (Sample)
INTERNATIONAL ISO
STANDARD 7203-2
Second edition
2011-06-01
Fire extinguishing media — Foam
concentrates —
Part 2:
Specification for medium- and high-
expansion foam concentrates for top
application to water-immiscible liquids
Agents extincteurs — Émulseurs —
Partie 2: Spécifications pour les émulseurs moyen et haut
foisonnements destinés à une application par le haut sur les liquides
non miscibles à l'eau
Reference number
ISO 7203-2:2011(E)
©
ISO 2011
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ISO 7203-2:2011(E)
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ii © ISO 2011 – All rights reserved
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ISO 7203-2:2011(E)
Contents Page
Foreword .v
Introduction.vi
1 Scope.1
2 Normative references.1
3 Terms and definitions .2
4 Classification and uses of foam concentrates.3
4.1 Classification .3
4.2 Use with sea water .3
5 Tolerance of the foam concentrate to freezing and thawing .3
6 Sediment in the foam concentrate.4
6.1 Sediment before ageing.4
6.2 Sediment after ageing.4
7 Determination of viscosity for pseudo-plastic foam concentrates.4
7.1 Newtonian foam concentrates .4
7.2 Pseudo-plastic foam concentrates.4
8 pH of the foam concentrate.4
8.1 pH limits.4
8.2 Sensitivity to temperature .4
9 Surface tension of the foam solution .4
9.1 Before temperature conditioning.4
9.2 Temperature sensitivity .4
10 Interfacial tension between the foam solution and cyclohexane.5
10.1 Before temperature conditioning.5
10.2 Temperature sensitivity .5
11 Spreading coefficient of the foam solution on cyclohexane .5
12 Expansion and drainage of foam.5
12.1 Medium-expansion foam concentrates — Limits .5
12.2 High-expansion foam concentrate — Limits .5
13 Test fire performance.5
14 Marking, packaging and specification sheet.6
14.1 Marking.6
14.2 Packaging.6
14.3 Specification sheet.6
Annex A (normative) Preliminary sampling and conditioning of the foam concentrate.7
Annex B (normative) Determination of tolerance to freezing and thawing .8
Annex C (normative) Determination of volume percentage of sediment.10
Annex D (normative) Determination of viscosity for pseudo-plastic foam concentrates.11
Annex E (normative) Determination of surface tension, interfacial tension and spreading
coefficient.13
Annex F (normative) Determination of expansion and drainage time for medium-expansion foam
concentrates .14
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ISO 7203-2:2011(E)
Annex G (normative) Determination of expansion and drainage time for high-expansion foam
concentrates.19
Annex H (normative) Determination of test fire performance for medium-expansion foam
concentrates.25
Annex I (normative) Determination of test fire performance for high-expansion foam concentrates .29
Annex J (normative) Determination of radiation measurement method.33
Annex K (informative) Compatibility .37
Bibliography .38
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ISO 7203-2:2011(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the
International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 7203-2 was prepared by Technical Committee ISO/TC 21, Equipment for fire protection and fire fighting,
Subcommittee SC 6, Foam and powder media and fixed firefighting systems using foam and powder.
This second edition cancels and replaces the first edition (ISO 7203-2:1995), which has been technically
revised.
ISO 7203 consists of the following parts, under the general title Fire extinguishing media — Foam
concentrates:
⎯ Part 1: Specification for low-expansion foam concentrates for top application to water-immiscible liquids
⎯ Part 2: Specification for medium- and high-expansion foam concentrates for top application to water-
immiscible liquids
⎯ Part 3: Specification for low-expansion foam concentrates for top application to water-miscible liquids
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ISO 7203-2:2011(E)
Introduction
Firefighting foams are widely used to control and extinguish fires of flammable liquids and for inhibiting re-
ignition. They can also be used to prevent ignition of flammable liquids and, in certain conditions, extinguish
fires of solid combustibles.
Foams can be used in combination with other extinguishing media, particularly halons, carbon dioxide and
powders, which are the subject of other International Standards including ISO 5923, ISO 6183, ISO 7201-1,
ISO 7201-2 and ISO 7202. A specification for foam systems (ISO 7076), which is cited in this part of ISO 7203,
is under preparation.
Attention is drawn to Annex K, which deals with the compatibility of foam concentrates, and the compatibility
of foams and powders.
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INTERNATIONAL STANDARD ISO 7203-2:2011(E)
Fire extinguishing media — Foam concentrates —
Part 2:
Specification for medium- and high-expansion foam
concentrates for top application to water-immiscible liquids
1 Scope
This part of ISO 7203 specifies the essential properties and performance of liquid foam concentrates used to
make medium- or high-expansion foams or both for the control, extinction and inhibition of reignition of fires of
water-immiscible liquids. Minimum performance on certain test fires is specified.
These foams are suitable for top application to fires of water-immiscible liquid. Those foams that comply with
ISO 7203-1 are also suitable for top application to fires of water-immiscible liquids.
2 Normative references
The following referenced documents are indispensable for the application of this document. For dated
references, only the edition cited applies. For undated references, the latest edition of the referenced
document (including any amendments) applies.
ISO 304, Surface active agents — Determination of surface tension by drawing up liquid films
ISO 3104, Petroleum products — Transparent and opaque liquids — Determination of kinematic viscosity and
calculation of dynamic viscosity
ISO 3219, Plastics —Polymers/resins in the liquid state or as emulsions or dispersions — Determination of
viscosity using a rotational viscometer with defined shear rate
ISO 3310-1, Test sieves — Technical requirements and testing — Part 1: Test sieves of metal wire cloth
ISO 3696:1987, Water for analytical laboratory use — Specification and test methods
ISO 3734, Petroleum products — Determination of water and sediment in residual fuel oils – Centrifuge
method
ISO 7203-1, Fire extinguishing media — Foam concentrates — Part 1: Specifications for low-expansion foam
concentrates for top application to water-immiscible liquids
BS 5117-1.3:1985, Testing corrosion inhibiting, engine coolant concentrate (“antifreeze”). Methods of test for
determination of physical and chemical properties. Determination of freezing point
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ISO 7203-2:2011(E)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1
characteristic value
value declared by the foam concentrate supplier for the chemical and physical properties and the
performances of the foam, foam solution, and foam concentrate
3.2
25 % drainage time
time for 25 % of the liquid content of a foam to drain out
3.3
50 % drainage time
time for 50 % of the liquid content of a foam to drain out
3.4
expansion
ratio of the volume of foam to the volume of the foam solution from which it was made
3.5
low-expansion
with expansion in the range 1 to 20, as applied to foam and to associated equipment, systems and
concentrates
3.6
medium-expansion
with expansion in the range 21 to 200, as applied to foam and to associated equipment, systems and
concentrates
3.7
high-expansion
with expansion greater than or equal to 200, as applied to foam and to associated equipment, systems and
concentrates
3.8
foam
〈firefighting〉 aggregate of air-filled bubbles formed from an aqueous solution of a suitable foam concentrate
3.9
foam concentrate
concentrate
liquid which, when mixed with water in the appropriate concentration, gives a foam solution
3.10
protein foam concentration
P
foam concentrate derived from hydrolised protein materials
3.11
fluoroprotein foam concentrate
FP
protein foam concentrate with added fluorinated surface-active agents
3.12
synthetic foam concentrate
S
foam concentrate based on a mixture of hydrocarbon surface-active agents and which can contain
fluorocarbons with additional stabilizers
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ISO 7203-2:2011(E)
3.13
alcohol-resistant foam concentrate
AR
foam concentrate resistant to breakdown when applied to the surface of alcohol or other water-miscible solvents
3.14
aqueous film-forming foam concentrate
AFFF
foam concentrate based on a mixture of hydrocarbon and fluorinated surface-active agents with the ability to
form an aqueous film on the surface of some hydrocarbons
3.15
film-forming fluoroprotein foam concentrate
FFFP
fluoroprotein foam concentrate that has the ability to form an aqueous film on the surface of some
hydrocarbons
3.16
foam solution
solution of foam concentrate and water
3.17
forceful application
application of foam such that it falls directly onto the surface of a liquid fuel
3.18
gentle application
application of foam indirectly to the surface of a liquid fuel via a backboard, tank wall or other surface
3.19
sediment
insoluble particles in the foam concentrate
3.20
spreading coefficient
value calculated from the measured surface and interfacial tensions to indicate the ability of one liquid to
spontaneously spread across the surface of another
4 Classification and uses of foam concentrates
4.1 Classification
The foam concentrate shall be classified as medium- or high-expansion or both and shall comply with the
appropriate requirements.
4.2 Use with sea water
If a foam concentrate is marked as suitable for use with sea water, the recommended concentrations for use
with fresh water and sea water shall be identical.
5 Tolerance of the foam concentrate to freezing and thawing
Before and after temperature conditioning in accordance with A.2, the foam concentrate, if claimed by the
supplier not to be adversely affected by freezing and thawing, shall show no visual sign of stratification and
non-homogeneity, when tested in accordance with Annex B.
Foam concentrates complying with this clause shall be tested for compliance with the appropriate requirements
given in other clauses of this part of ISO 7203 after freezing and thawing in accordance with A.2.1.
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ISO 7203-2:2011(E)
6 Sediment in the foam concentrate
6.1 Sediment before ageing
Any sediment in the concentrate prepared in accordance with A.1 shall be dispersible through a 180 µm sieve,
and the volume percentage of sediment shall be not more than 0,25 % when tested in accordance with Annex C.
6.2 Sediment after ageing
Any sediment in the concentrate aged in accordance with C.1 shall be dispersible through a 180 µm sieve, and
the volume percentage of sediment shall be not more than 1,0 % when tested in accordance with Annex C.
7 Determination of viscosity for pseudo-plastic foam concentrates
7.1 Newtonian foam concentrates
The viscosity of the foam concentrate at the lowest temperature for use claimed by the manufacturer shall be
determined in accordance with ISO 3104. If the viscosity is greater than 200 mm/s, the container shall be
marked “This concentrate can require special proportioning equipment”.
7.2 Pseudo-plastic foam concentrates
The viscosity of the foam concentrate shall be determined in accordance with Annex D. If the viscosity at the
lowest temperature for use is greater than or equal to 120 mPa/s at 375/s, the container shall be marked
“Pseudo-plastic foam concentrate. This concentrate can require special proportioning equipment”.
8 pH of the foam concentrate
8.1 pH limits
The pH of the foam concentrate, before and after temperature conditioning in accordance with A.2, shall be
not less than 6,0 and not more than 8,5 at (20 ± 2) °C.
8.2 Sensitivity to temperature
The difference in pH between before and after temperature conditioning shall not be greater than 1,0 pH units.
9 Surface tension of the foam solution
9.1 Before temperature conditioning
The surface tension of the foam solution prepared from the concentrate, before temperature conditioning in
accordance with A.2, at the supplier's recommended concentration, shall be within ±10 % of the characteristic
value when determined in accordance with E.2.
9.2 Temperature sensitivity
The surface tension of the foam solution prepared from the concentrate, after temperature conditioning in
accordance with A.2, at the supplier's recommended concentration, shall be determined in accordance with E.2.
The value obtained after temperature conditioning shall not be less than 0,95 times, or more than 1,05 times,
the value obtained before temperature conditioning.
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ISO 7203-2:2011(E)
10 Interfacial tension between the foam solution and cyclohexane
10.1 Before temperature conditioning
Before temperature conditioning in accordance with A.2, the difference between the interfacial tension
between the foam solution prepared from the foam concentrate and cyclohexane (when determined in
accordance with E.3) and the characteristic value for interfacial tension shall not exceed 1,0 mN/m or 10 % of
the characteristic value, whichever is the greater.
10.2 Temperature sensitivity
After temperature conditioning in accordance with A.2, the interfacial tension between the foam solution
prepared from the foam concentrate and cyclohexane shall be determined in accordance with E.3.
The two values obtained before and after temperature conditioning shall not differ by more than 0,5 mN/m.
11 Spreading coefficient of the foam solution on cyclohexane
Before and after temperature conditioning in accordance with A.2, the spreading coefficient of the foam
solution prepared from a concentrate claimed by the supplier to be “film-forming” shall be positive when
calculated in accordance with E.4.
NOTE Foam concentrates complying with this clause are more likely to be of type AFFF or FFFP than of type FP, P or S.
12 Expansion and drainage of foam
12.1 Medium-expansion foam concentrates — Limits
The foam produced from the foam concentrate, before and after temperature conditioning in accordance with
A.2, with potable water and, if appropriate, with the synthetic sea water of H.2.4, shall have an expansion of
not less than 50 when tested in accordance with Annex F.
12.2 High-expansion foam concentrate — Limits
The foam produced from the foam concentrate, before and after temperature conditioning in accordance with
A.2, with potable water and, if appropriate, with the synthetic sea water of I.2.4, shall have an expansion of not
less than 201 when tested in accordance with Annex G.
13 Test fire performance
The foam produced from the foam concentrate with potable water, and if appropriate, with the synthetic sea
water of H.2.4 and/or I.2.4, shall have an extinguishing performance class and burn-back resistance level as
specified in Table 1 when tested in accordance with Annex H or Annex I, or both, as appropriate.
Table 1 — Test fire performance
Types of expansion foam Medium-expansion foam High-expansion foam
Extinction time, seconds Not more than 120 Not more than 150
1 % burn-back time, seconds Not less than 30 Not applicable
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ISO 7203-2:2011(E)
14 Marking, packaging and specification sheet
14.1 Marking
14.1.1 The following information shall be marked on the shipping container:
a) designation (identifying name) of the concentrate and, as appropriate, the words “medium” or “high”, or
“medium and high” and “expansion foam concentrate”;
b) if the concentrate complies with Clause 11, the words “aqueous film-forming”;
c) recommended concentration for use (most commonly 1 %, 3 % or 6 %);
d) any tendency of the foam concentrate to cause harmful physical effects, the methods required to avoid
them and the first aid treatment if they should occur;
e) recommended storage temperature and temperature of use;
f) if the concentrate complies with Clause 5, the words “Not affected by freezing and thawing” or, if the foam
concentrate does not comply with Clause 5, the words “Do not freeze”;
g) nominal quantity in the container;
h) supplier's name and address;
i) batch number;
j) words “Not suitable for use with sea water” or “Suitable for use with sea water”, as appropriate.
WARNING — It is extremely important that the foam concentrate, after dilution with water to the
recommended concentration, shall not, in normal usage, present a significant toxic hazard to life in
relation to the environment.
14.1.2 Markings on shipping containers shall be permanent and legible.
14.1.3 It is recommended that non-Newtonian concentrates be appropriately identified.
14.1.4 Foam concentrates complying with ISO 7203-1 shall also be marked “low-expansion”.
14.2 Packaging
The packaging of the foam concentrate shall ensure that the essential characteristics of the concentrate are
preserved when stored and handled in accordance with the supplier's recommendations.
14.3 Specification sheet
14.3.1 If the foam concentrate is Newtonian and the viscosity at the lowest temperature for use is more than
2
200 mm /s when measured in accordance with ISO 3104, the words “This concentrate can require special
proportioning equipment” shall be included on the specification sheet.
14.3.2 If the foam concentrate is pseudo-plastic and the viscosity at the lowest temperature for use is greater
than or equal to 120 mPa/s at 375/s, the words “Pseudo-plastic foam concentrate. This concentrate can
require special proportioning equipment” shall be included on the specification sheet.
14.3.3 It is recommended that non-Newtonian concentrates be appropriately identified.
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ISO 7203-2:2011(E)
Annex A
(normative)
Preliminary sampling and conditioning of the foam concentrate
A.1 Preliminary sampling
The sampling method shall ensure representative samples, whether taken from a bulk container or a number
of individual packages.
Store samples in fully closed containers.
NOTE Containers with a capacity of 20 l are suitable.
A.2 Conditioning of foam concentrate
A.2.1 If the supplier claims that the concentrate is not adversely affected by freezing and thawing, condition
the concentrate sample through four cycles of freezing and thawing, generally as described in B.2, before
conditioning in accordance with A.2.2. If the foam concentrate is adversely affected by freezing and thawing, it
shall be conditioned according to A.2.2 without prior freezing and thawing.
A.2.2 Condition the concentrate in the sealed container for 7 d at (60 ± 2) °C, followed by 1 d at (20 ± 5) °C.
A.3 Subsequent testing
Test samples prepared in accordance with A.1, or A.1 and A.2 as appropriate. Agitate the sample container
before sampling for further tests.
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ISO 7203-2:2011(E)
Annex B
(normative)
Determination of tolerance to freezing and thawing
B.1 Apparatus
The usual laboratory apparatus and, in particular, the following.
B.1.1 Freezing chamber, capable of achieving the temperatures required in B.2.
B.1.2 Polyethylene tube, approximately 10 mm in diameter, approximately 400 mm long and sealed and
weighted at one end, with suitable spacers attached.
Figure B.1 shows a typical form.
B.1.3 Measuring cylinder, glass, of 500 ml capacity, approximately 400 mm high and approximately
65 mm in diameter, with a stopper.
B.2 Procedure
Set the temperature of the freezing chamber (B.1.1) to at least 10 °C below the freezing point of the sample,
measured in accordance with BS 5117-1.3, excluding 5.2.
To prevent the glass measuring cylinder (B.1.3) from breaking due to expansion of the foam concentrate on
freezing, insert the tube (B.1.2) into the measuring cylinder with the sealed end downward, weighted if
necessary to avoid flotation, the spacers ensuring it remains approximately on the central axis of the cylinder.
Fill the cylinder and fit the stopper.
Place the cylinder in the freezing chamber, cool it and maintain at the required temperature for 24 h. At the
end of this period, thaw the sample for not less than 24 h and not more than 96 h in an ambient temperature
of (20 ± 5) °C.
Repeat three times to give four cycles of freezing and thawing before testing.
Examine the sample for stratification and non-homogeneity.
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ISO 7203-2:2011(E)
Nominal dimensions in millimetres
ø10
1
1
1
1
1
1
2
Key
1 spacers (e.g. plastic cable strap)
2 weight at sealed end
Figure B.1 — Typical form of polyethylene tube
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ISO 7203-2:2011(E)
Annex C
(normative)
Determination of volume percentage of sediment
C.1 Sampling
Use a sample prepared in accordance with A.1. Ensure that any sediment is dispersed by agitating the
sample container. Take two samples, testing one immediately and the other after ageing for (24 ± 2) h at
(60 ± 2) °C in a filled container without access to air.
C.2 Apparatus
The usual laboratory apparatus and, in particular, the following.
C.2.1 Centrifuge tubes, graduated.
Centrifuge tubes complying with ISO 3734 are suitable.
2
C.2.2 Centrifuge, operating at (6 000 ± 600) m/s .
A centrifuge complying with ISO 3734 is suitable.
C.2.3 Sieve, of nominal aperture size 180 µm, complying with ISO 3310-1.
C.2.4 Wash bottle, plastic.
C.3 Procedure
Centrifuge each sample of the concentrate for (10 ± 1) min. Determine the volume of the sediment and record
it as a percentage of volume of the centrifuged sample volume.
Wash the contents of the centrifuge tube (C.2.1) onto the sieve (C.2.3) and check whether the sediment can
or cannot be dispersed through the sieve by the jet from the plastic wash bottle (C.2.4).
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ISO 7203-2:2011(E)
Annex D
(normative)
Determination of viscosity for pseudo-plastic foam concentrates
D.1 General
This annex gives the procedure for determining the viscosity for pseudo-plastic foam concentrates. The
procedure is described in ISO 3219.
NOTE Pseudo-plastic foam concentrates are a particular class of non-Newtonian foam concentrate and have a
viscosity which decreases with increasing shear rate at constant temperature.
D.2 Viscosity determination
D.2.1 Apparatus
The usual laboratory apparatus and a rotational viscometer in accordance with ISO 3219 with the following
parameters:
⎯ maximum shear stress of ≥75 Pa;
⎯ maximum shear rate of ≥600/s.
The viscometer shall be
...
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