SIST EN 16105:2023
(Main)Paints and varnishes - Laboratory method for determination of release of regulated dangerous substances from coatings in intermittent contact with water
Paints and varnishes - Laboratory method for determination of release of regulated dangerous substances from coatings in intermittent contact with water
This European Standard specifies a laboratory method to determine the leaching behaviour of substances from coatings into water over defined time intervals.
The release of substances from coatings under natural conditions cannot be determined with this method.
Beschichtungsstoffe - Laborverfahren zur Bestimmung der Freisetzung von Substanzen aus Beschichtungen in intermittierendem Kontakt mit Wasser
Dieses Dokument legt ein Laborverfahren fest, mit dem das Auswaschverhalten von Substanzen aus Beschichtungen ins Wasser innerhalb definierter Zeitintervalle bestimmt werden kann.
Das Verfahren ist für die Bestimmung des Auswaschens von Substanzen aus Beschichtungen unter natürlichen Bedingungen nicht anwendbar.
Dieses Verfahren kann für Putze angewendet werden, wenn die Bedingung (4) im Anwendungsbereich von CEN/TS 16637 1 erfüllt ist.
(4) Es wird angenommen, dass der zeitweilige Kontakt mit Wasser (zum Beispiel Beanspruchung durch Regenwasser) nach Vereinbarung als dauerhafter Kontakt geprüft wird. Bei einigen Beschichtungen (zum Beispiel einige Putze mit organischen Bindemitteln nach EN 15824), die zeitweilig mit Wasser in Berührung kommen, könnten physikalische und chemische Eigenschaften sich bei dauerhaftem Kontakt mit Wasser ändern. Diese Produkte werden nicht in dieser Technischen Spezifikation berücksichtigt, da das Prüfverfahren in CEN/TS 16637 2 für die Prüfung dieser Bauprodukte nicht geeignet ist.
Peintures et vernis - Méthode de laboratoire pour la détermination de la libération de substances dangereuses réglementées provenant de revêtements en contact avec l’eau par intermittence
Le présent document spécifie une méthode de laboratoire visant à déterminer le comportement à la lixiviation par l’eau des substances contenues dans les revêtements sur des intervalles de temps spécifiés.
La libération de substances depuis les revêtements dans des conditions naturelles ne peut pas être déterminée à l’aide de la présente méthode.
Cette méthode peut être appliquée aux enduits, lorsque la condition (4) du domaine d’application de la spécification technique CEN/TS 16637 1 est remplie.
(4) Il est supposé qu’un contact intermittent avec l’eau (par exemple, une exposition à l’eau de pluie) est examiné, par convention, comme un contact permanent. Pour certains revêtements (par exemple certains enduits contenant des liants organiques conformément à l’EN 15824) en contact intermittent avec l’eau, les propriétés physiques et chimiques peuvent êtres altérées par un contact permanent avec l’eau. Ces produits ne sont pas couverts par la spécification technique CEN/TS 16637-1 car la méthode d’essai décrite dans la CEN/TS 16637 2 n’est pas appropriée pour ces produits de construction.
Barve in laki - Laboratorijska metoda za ugotavljanje sproščanja reguliranih nevarnih snovi iz premazov ob občasnem stiku z vodo
Ta evropski standard določa laboratorijsko metodo za določanje izluževanja snovi s prevlek v vodi v določenih časovnih intervalih.
S to metodo ni mogoče določiti sproščanja snovi s prevlek pod naravnimi pogoji.
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
SIST EN 16105:2023
01-maj-2023
Nadomešča:
SIST EN 16105:2011
Barve in laki - Laboratorijska metoda za ugotavljanje sproščanja reguliranih
nevarnih snovi iz premazov ob občasnem stiku z vodo
Paints and varnishes - Laboratory method for determination of release of regulated
dangerous substances from coatings in intermittent contact with water
Beschichtungsstoffe - Laborverfahren zur Bestimmung der Freisetzung von Substanzen
aus Beschichtungen in intermittierendem Kontakt mit Wasser
Peintures et vernis - Méthode de laboratoire pour la détermination de la libération de
substances dangereuses réglementées provenant de revêtements en contact avec l’eau
par intermittence
Ta slovenski standard je istoveten z: EN 16105:2023
ICS:
87.040 Barve in laki Paints and varnishes
SIST EN 16105:2023 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
SIST EN 16105:2023
---------------------- Page: 2 ----------------------
SIST EN 16105:2023
EN 16105
EUROPEAN STANDARD
NORME EUROPÉENNE
January 2023
EUROPÄISCHE NORM
ICS 87.040 Supersedes EN 16105:2011
English Version
Paints and varnishes - Laboratory method for
determination of release of regulated dangerous
substances from coatings in intermittent contact with
water
Peintures et vernis - Méthode de laboratoire pour la Beschichtungsstoffe - Laborverfahren zur Bestimmung
détermination de la libération de substances der Freisetzung von Substanzen aus Beschichtungen in
dangereuses réglementées provenant de revêtements intermittierendem Kontakt mit Wasser
en contact avec l'eau par intermittence
This European Standard was approved by CEN on 25 December 2022.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2023 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 16105:2023 E
worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
SIST EN 16105:2023
EN 16105:2023 (E)
Contents Page
European Foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Reagents . 7
5 Apparatus . 7
5.1 General . 7
5.2 Equipment . 7
6 Test procedure . 8
6.1 General considerations . 8
6.2 Sample preparation . 9
6.2.1 Substrate . 9
6.2.2 Sampling . 9
6.2.3 Number and size of test specimens . 9
6.2.4 Preparation of the test specimens . 9
6.2.5 Conditioning . 9
6.3 Immersion method . 9
6.3.1 Test procedure . 9
6.3.2 Analysis .10
7 Results .10
7.1 Results in concentrations .10
7.2 Results in terms of specific emissions .10
8 Test report .11
Annex A (informative) Forms for recording .13
Annex B (informative) Examples of data — Leaching of biocides .15
B.1 General .15
B.2 Sample preparation .15
B.3 Test procedure .15
B.4 Analytical methods .15
B.5 Test results .15
B.6 Assessment of the uncertainty .16
Bibliography .17
2
---------------------- Page: 4 ----------------------
SIST EN 16105:2023
EN 16105:2023 (E)
European Foreword
This document (EN 16105:2023) has been prepared by Technical Committee CEN/TC 139 “Paints and
Vanishes” the secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by July 2023, and conflicting national standards shall be
withdrawn at the latest by July 2023.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 16105:2011.
The main changes compared to the previous edition are as follows:
— the Scope has been amended;
— in 6.3.1 tolerances have been added;
— normative references have been updated.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the United
Kingdom.
3
---------------------- Page: 5 ----------------------
SIST EN 16105:2023
EN 16105:2023 (E)
Introduction
Leaching of substances from coatings into water needs to be quantified to enable an environmental risk
assessment for the use of substances in coating materials. Substances can be leached from coatings,
particularly by driving rain, and transferred into the environment.
4
---------------------- Page: 6 ----------------------
SIST EN 16105:2023
EN 16105:2023 (E)
1 Scope
This document specifies a laboratory method to determine the leaching behaviour of substances from
coatings into water over defined time intervals.
The release of substances from coatings under natural conditions cannot be determined with this
method.
This method can be applied to renders, when condition (4) of the Scope of CEN/TS 16637-1 is fulfilled.
(4) It is assumed that intermittent contact with water (e.g. exposure to rainwater) is tested — by
convention — as permanent contact. For some coatings, (e.g. some renders with organic binders
according to EN 15824) in intermittent contact to water, physical and chemical properties might be
altered in permanent contact with water. These products are not covered by the Technical Specification
CEN/TS 16637-1 since the test method in CEN/TS 16637-2 is not appropriate for these construction
products.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 23270, Paints and varnishes and their raw materials - Temperatures and humidities for conditioning
and testing (ISO 3270)
EN ISO 15528, Paints, varnishes and raw materials for paints and varnishes - Sampling (ISO 15528)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminology databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https://www.iso.org/obp
— IEC Electropedia: available at https://www.electropedia.org/
3.1
substance
single chemical element or compound, or a complex structure of compounds, that is contained in the
coating and can potentially be extracted from the coating via water contact
3.2
target substance
substance of interest which has to be defined
Note 1 to entry: One or more target substances may be defined, which shall be quantified in the merged eluates
and for which results shall be given according to Clause 6. For example, biocides can be the target substances (see
Annex B).
5
---------------------- Page: 7 ----------------------
SIST EN 16105:2023
EN 16105:2023 (E)
3.3
biocide
additive added to a coating material to prevent organisms responsible for microbiological degradation
from attacking a substrate, a coating material or a film thereof
Note 1 to entry: A list of biocides is given in Annex I and IA of the Biocidal Products Directive 98/8/EC (Directive
98/8/EC of the European Parliament and of the Council of 16 February 1998 concerning the placing of biocidal
products on the market – BPD).
[SOURCE: EN ISO 4618:2014, 2.27 modified: Note 1 to entry has been added]
3.4
coating
layer formed from a single or multiple application of a coating material to a substrate
Note 1 to entry: The use of the term “coating” for “coating material” is deprecated.
[SOURCE: EN ISO 4618:2014, 2.50.1]
3.5
coating material
product, in liquid, paste or powder form, that, when applied to a substrate, forms a layer possessing
protective, decorative and/or other specific properties
[SOURCE: EN ISO 4618:2014, 2.51]
3.6
test specimen
body to be tested consisting of substrate with coating
3.7
emission
release of substances from a coating, which pass through the external surface of the coating under specific
conditions into the environment
Note 1 to entry: The emission is expressed in units of released mass per surface area, i.e. milligrams per square
metre.
3.8
leaching
release of substances from a coating, which pass through the external surface of the coating under specific
conditions into water
Note 1 to entry: The leaching is expressed in units of released mass per surface area, i.e. milligrams per square
metre.
3.9
immersion
exposure of test specimen to the leachant
6
---------------------- Page: 8 ----------------------
SIST EN 16105:2023
EN 16105:2023 (E)
3.10
immersion cycle
i
sequence consisting of 1 h immersion, 4 h drying and 1 h immersion
Note 1 to entry: i is the running number of immersion cycles.
3.11
eluate
solution obtained by one immersion
3.12
merged eluate
solution obtained at a specific immersion cycle, consisting of the eluates of the two immersions
3.13
specific emission
E
released mass of a target substance from a coating through the surface during a specific immersion cycle
Note 1 to entry: The unit is mass per surface area, i.e. milligrams per square metre.
3.14
leachant
liquid that is brought into contact with the test specimen in the leaching procedure
Note 1 to entry: Standard leachant as specified in 4.1.
4 Reagents
4.1 Standard leachant
Deionised water with a pH-value of (6 ± 1) and a water temperature of (23 ± 2) °C shall be used.
5 Apparatus
5.1 General
Check the materials and equipment specified in 5.2.1 to 5.2.6 before use for proper operation and absence
of interfering e
...
SLOVENSKI STANDARD
oSIST prEN 16105:2021
01-april-2021
Barve in laki - Laboratorijska metoda za ugotavljanje sproščanja snovi iz
premazov ob občasnem stiku z vodo
Paints and varnishes - Laboratory method for determination of release of substances
from coatings in intermittent contact with water
Beschichtungsstoffe - Laborverfahren zur Bestimmung der Freisetzung von Substanzen
aus Beschichtungen in intermittierendem Kontakt mit Wasser
Peintures et vernis - Méthode de laboratoire pour la détermination de la libération de
substances provenant de revêtements en contact avec l'eau par intermittence
Ta slovenski standard je istoveten z: prEN 16105
ICS:
87.040 Barve in laki Paints and varnishes
oSIST prEN 16105:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
oSIST prEN 16105:2021
---------------------- Page: 2 ----------------------
oSIST prEN 16105:2021
DRAFT
EUROPEAN STANDARD
prEN 16105
NORME EUROPÉENNE
EUROPÄISCHE NORM
April 2021
ICS 87.040 Will supersede EN 16105:2011
English Version
Paints and varnishes - Laboratory method for
determination of release of regulated dangerous
substances from coatings in intermittent contact with
water
Peintures et vernis - Méthode de laboratoire pour la Beschichtungsstoffe - Laborverfahren zur Bestimmung
détermination de la libération de substances der Freisetzung von Substanzen aus Beschichtungen in
provenant de revêtements en contact avec l'eau par intermittierendem Kontakt mit Wasser
intermittence
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 139.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.
This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.
Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 16105:2021 E
worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
oSIST prEN 16105:2021
prEN 16105:2021 (E)
Contents Page
Foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Reagents . 7
5 Apparatus . 7
5.1 General . 7
5.2 Equipment . 7
6 Test procedure . 8
6.1 General considerations . 8
6.2 Sample preparation . 9
6.2.1 Substrate . 9
6.2.2 Sampling . 9
6.2.3 Number and size of test specimens . 9
6.2.4 Preparation of the test specimens . 9
6.2.5 Conditioning . 9
6.3 Immersion method . 9
6.3.1 Test procedure . 9
6.3.2 Analysis . 10
7 Results . 10
7.1 Results in concentrations . 10
7.2 Results in terms of specific emissions . 10
8 Test report . 11
Annex A (informative) Forms for recording . 13
Annex B (informative) Examples of data: Leaching of biocides . 15
B.1 General . 15
B.2 Sample preparation . 15
B.3 Test procedure . 15
B.4 Analytical methods . 15
B.5 Test results . 15
B.6 Assessment of the uncertainty . 16
Bibliography . 17
2
---------------------- Page: 4 ----------------------
oSIST prEN 16105:2021
prEN 16105:2021 (E)
Foreword
This document (prEN 16105:2021) has been prepared by Technical Committee CEN/TC 139 “Paints
and Vanishes” the secretariat of which is held by DIN.
This document is currently submitted to the CEN Enquiry.
This document will supersede EN 16105:2011.
The main changes compared to the previous edition are as follows:
— the scope has been amended;
— in 6.3.1 tolerances have been added;
— normative references have been updated.
3
---------------------- Page: 5 ----------------------
oSIST prEN 16105:2021
prEN 16105:2021 (E)
Introduction
Leaching of substances from coatings into water needs to be quantified to enable an environmental risk
assessment for the use of substances in coating materials. Substances can be leached from coatings,
particularly by driving rain, and transferred into the environment.
4
---------------------- Page: 6 ----------------------
oSIST prEN 16105:2021
prEN 16105:2021 (E)
1 Scope
This document specifies a laboratory method to determine the leaching behaviour of substances from
coatings into water over defined time intervals.
The release of substances from coatings under natural conditions cannot be determined with this
method.
This methods can be applied to renders, when condition (4) of the scope of CEN/TS 16637-1 is fulfilled.
(4) It is assumed that the temporary contact with water (e.g. exposure to rainwater) is examined as a
permanent contact by agreement. For some coatings (e.g. some plasters with organic binders according
to EN 15824) that come into temporary contact with water, physical and chemical properties may
change with prolonged contact with water. These products are not covered in this Technical
Specification because the test method in CEN/TS 16637-2 is not suitable for testing these construction
products.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
EN 23270, Paints and varnishes and their raw materials - Temperatures and humidities for conditioning
and testing (ISO 3270)
EN ISO 15528, Paints, varnishes and raw materials for paints and varnishes - Sampling (ISO 15528)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https://www.iso.org/obp
— IEC Electropedia: available at http://www.electropedia.org/
3.1
substance
single chemical element or compound, or a complex structure of compounds, that is contained in the
coating and can potentially be extracted from the coating via water contact
3.2
target substance
substance of interest which has to be defined
Note 1 to entry: One or more target substances may be defined, which shall be quantified in the merged eluates
and for which results shall be given according to Clause 6. For example, biocides can be the target substances (see
Annex B).
5
---------------------- Page: 7 ----------------------
oSIST prEN 16105:2021
prEN 16105:2021 (E)
3.3
biocide
additive added to a coating material to prevent organisms responsible for microbiological degradation
from attacking a substrate, a coating material or a film thereof
Note 1 to entry: A list of biocides is given in Annex I and IA of the Biocidal Products Directive 98/8/EC
(Directive 98/8/EC of the European Parliament and of the Council of 16 February 1998 concerning the placing of
biocidal products on the market – BPD).
[SOURCE: EN ISO 4618:2014, 2.27 modified: note 1 to entry has been added]
3.4
coating
layer formed from a single or multiple application of a coating material to a substrate
Note 1 to entry: The use of the term “coating” for “coating material” is deprecated.
[SOURCE: EN ISO 4618:2014, 2.50.1]
3.5
coating material
product, in liquid, paste or powder form, that, when applied to a substrate, forms a layer possessing
protective, decorative and/or other specific properties
[SOURCE: EN ISO 4618:2014, 2.51]
3.6
test specimen
body to be tested consisting of substrate with coating
3.7
emission
release of substances from a coating, which pass through the external surface of the coating under
specific conditions into the environment
Note 1 to entry: The emission is expressed in units of released mass per surface area, i.e. milligrams per square
metre.
3.8
leaching
release of substances from a coating, which pass through the external surface of the coating under
specific conditions into water
Note 1 to entry: The leaching is expressed in units of released mass per surface area, i.e. milligrams per square
metre.
3.9
immersion
exposure of test specimen to the leachant
6
---------------------- Page: 8 ----------------------
oSIST prEN 16105:2021
prEN 16105:2021 (E)
3.10
immersion cycle
i
sequence consisting of 1 h immersion, 4 h drying and 1 h immersion
Note 1 to entry: i is the running number of immersion cycles.
3.11
eluate
solution obtained by one immersion
3.12
merged eluate
solution obtained at a specific immersion cycle, consisting of the eluates of the two immersions
3.13
specific emission
E
released mass of a target substance from a coating through the surface during a specific immersion
cycle
Note 1 to entry: The unit is mass per surface area, i.e. milligrams per square metre.
3.14
leachant
liquid that is brought into contact with the test specimen in the leaching procedure
Note 1 to entry: Standard leachant as specified in 4.1.
4 Reagents
4.1 Standard leachant
Deionised water with a pH-value of (6 ± 1) and a water temperature of (23 ± 2) °C shall be used.
5 Apparatus
5.1 General
Check the materials and equipment specified in 5.2.1 to 5.2.6 before use for proper operation and
absence of interfering elements that might affect the results of the test.
The equipment specified in 5.2.2 to 5.2.5 shall also be calibrated.
5.2 Equipment
5.2.1 Immersion container
The container for immersion shall be m
...
Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.