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SIST EN 1601:2014/AC:2014

(Corrigendum)

Liquid petroleum products - Unleaded petrol - Determination of organic oxygenate compounds and total organically bound oxygen content by gas chromatography (O-FID)

Liquid petroleum products - Unleaded petrol - Determination of organic oxygenate compounds and total organically bound oxygen content by gas chromatography (O-FID)

CCMC origin: line missing in Table 1 (corrigendum issued for the English and German versions, no French version available)

Flüssige Mineralölerzeugnisse - Unverbleite Ottokraftstoffe - Bestimmung sauerstoffhaltiger organischer Verbindungen und des Gesamtgehalts an organisch gebundenem Sauerstoff mittels Gaschromatographie (O-FID)

Produit pétroliers liquides - Essence sans plomb - Détermination des composés oxygénés organiques et de la teneur totale en oxygène organiquement lié par chromatographie en phase gazeuse (O-FID)

Tekoči naftni proizvodi - Neosvinčeni motorni bencin - Določevanje organskih kisikovih spojin in celotnega organsko vezanega kisika s plinsko kromatografijo (O-FID)

General Information

Status
Withdrawn
Publication Date
05-Nov-2014
Withdrawal Date
03-Sep-2017
ICS
71.040.50 - Physicochemical methods of analysis
75.160.20 - Liquid fuels
Technical Committee
NAD - Petroleum products, lubricants and related products
Current Stage
9900 - Withdrawal (Adopted Project)
Start Date
01-Sep-2017
Due Date
24-Sep-2017
Completion Date
04-Sep-2017
Directive
98/70/EC - Quality of petrol and diesel fuels (Dir. 93/12/EEC amendment)
Ref Project
EN 1601:2014/AC:2014 - Liquid petroleum products - Unleaded petrol - Determination of organic oxygenate compounds and total organically bound oxygen content by gas chromatography (O-FID)

Relations

Corrects
SIST EN 1601:2014 - Liquid petroleum products - Unleaded petrol - Determination of organic oxygenate compounds and total organically bound oxygen content by gas chromatography (O-FID)
Effective Date
01-Dec-2014
Replaced By
SIST EN 1601:2017 - Liquid petroleum products - Determination of organic oxygenate compounds and total organically bound oxygen content in unleaded petrol - Method by gas chromatography (O-FID)
Effective Date
01-Oct-2017
Corrects
SIST EN 1601:2014 - Liquid petroleum products - Unleaded petrol - Determination of organic oxygenate compounds and total organically bound oxygen content by gas chromatography (O-FID)
Effective Date
08-Jun-2022

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2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.NURPDWRJUDILMR2),'Flüssige Mineralölerzeugnisse - Unverbleite Ottokraftstoffe - Bestimmung sauerstoffhaltiger organischer Verbindungen und des Gesamtgehalts an organisch gebundenem Sauerstoff mittels Gaschromatographie (O-FID)Produit pétroliers liquides - Essence sans plomb - Détermination des composés oxygénés organiques et de la teneur totale en oxygène organiquement lié par chromatographie en phase gazeuse (O-FID)Liquid petroleum products - Unleaded petrol - Determination of organic oxygenate compounds and total organically bound oxygen content by gas chromatography (O-FID)75.160.20Liquid fuels71.040.50Fizikalnokemijske analitske metodePhysicochemical methods of analysisICS:Ta slovenski standard je istoveten z:EN 1601:2014/AC:2014SIST EN 1601:2014/AC:2014en,de01-december-2014SIST EN 1601:2014/AC:2014SLOVENSKI
STANDARD



SIST EN 1601:2014/AC:2014



EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 1601:2014/AC
October 2014
Octobre 2014
Oktober 2014 ICS 75.160.20 English version Version Française Deutsche Fassung
Liquid petroleum products - Unleaded petrol - Determination of organic oxygenate compounds and total organically bound oxygen content by gas chromatography (O-FID)
Produit pétroliers liquides - Essence sans plomb - Détermination des composés oxygénés organiques et de la teneur totale en oxygène organiquement lié par chromatographie en phase gazeuse (O-FID)
Flüssige Mineralölerzeugnisse - Unverbleite Ottokraftstoffe - Bestimmung sauerstoffhaltiger organischer Verbindungen und des Gesamtgehalts an organisch gebundenem Sauerstoff mittels Gaschromatographie (O-FID) This corrigendum becomes effective on 22 October 2014 for
...

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This document specifies the gas chromatographic (GC) method for the determination of saturated,
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Additionally, the benzene and toluene content, oxygenated compounds and the total oxygen content can
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This document defines two procedures, A and B.
Procedure A is applicable to automotive motor gasoline with total aromatics of 19,32 % (V/V) up to
46,29 % (V/V); total olefins from 0,40 % (V/V) up to 26,85 % (V/V); oxygenates from 0,61 % (V/V) up to
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The method has also been tested for individual oxygenates. A precision has been determined for
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volume of ETBE from 0,99 % (V/V) up to 15,49 % (V/V), a total volume of TAME from 0,99 % (V/V) up to
5,92 % (V/V), and a total volume of TAEE from 0,98 % (V/V) up to 15,59 % (V/V).
Although this test method can be used to determine higher-olefin contents of up to 50 % (V/V), the
precision for olefins was tested only in the range from 0,40 % (V/V) to 26,85 % (V/V).
Although specifically developed for the analysis of automotive motor gasoline that contains oxygenates,
this test method can also be applied to other hydrocarbon streams having similar boiling ranges, such
as naphthas and reformates.
NOTE 2 For Procedure A, applicability of this document has also been verified for the determination of
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compounds.
Procedure B describes the analysis of oxygenated groups (ethanol, methanol, ethers, C3 – C5 alcohols)
in ethanol (E85) automotive fuel containing ethanol between 50 % (V/V) and 85 % (V/V). The gasoline
is diluted with an oxygenate-free component to lower the ethanol content to a value below 20 % (V/V)
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The sample can be fully analysed including hydrocarbons. Precision data for the diluted sample are
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NOTE 3 For Procedure B, the precision can be used for an ethanol fraction from about 50 % up to 85 % (V/V).
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This European Standard specifies a gas chromatographic method for the quantitative determination, in unleaded petrol having a final boiling point not greater than 220 °C, of individual organic oxygenate compounds in the range 0,17 % (m/m) to 15 % (m/m) in a direct analysis (without dilution), and total organically bound oxygen up to 3,9 % (m/m).
For samples for which one of the oxygenate compounds content is higher than 15 % (m/m), a procedure with a dilution of the sample before the analysis is given.
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This Technical report is published as background information to judge the approval of the use of the method described in EN ISO 22854 for the determination of all oxygenates as mentioned in the European Fuels Directive. Next, this report supports the use of multidimensional chromatography as the method for disputes on oxygenates in EN 228.
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This document specifies the gas chromatographic (GC) method for the determination of saturated,
olefinic and aromatic hydrocarbons in automotive motor gasoline and ethanol (E85) automotive fuel.
Additionally, the benzene and toluene content, oxygenated compounds and the total oxygen content can
be determined.
NOTE 1 For the purposes of this document, the terms % (m/m) and % (V/V) are used to represent respectively
the mass fraction, w, and the volume fraction, φ.
This document defines two procedures, A and B.
Procedure A is applicable to automotive motor gasoline with total aromatics of 19,32 % (V/V) up to
46,29 % (V/V); total olefins from 0,40 % (V/V) up to 26,85 % (V/V); oxygenates from 0,61 % (V/V) up to
9,85 % (V/V); oxygen content from 1,50 % (m/m) to 12,32 % (m/m); benzene content from 0,38 % (V/V)
up to 1,98 % (V/V) and toluene content from 5,85 % (V/V) up to 31,65 % (V/V).
The method has also been tested for individual oxygenates. A precision has been determined for
a total volume of methanol from 1,05 % (V/V) up to 16,96 % (V/V); a total volume of ethanol from
0,50 % (V/V) up to 17,86 % (V/V); a total volume of MTBE from 0,99 % (V/V) up to 15,70 % (V/V), a total
volume of ETBE from 0,99 % (V/V) up to 15,49 % (V/V), a total volume of TAME from 0,99 % (V/V) up to
5,92 % (V/V), and a total volume of TAEE from 0,98 % (V/V) up to 15,59 % (V/V).
Although this test method can be used to determine higher-olefin contents of up to 50 % (V/V), the
precision for olefins was tested only in the range from 0,40 % (V/V) to 26,85 % (V/V).
Although specifically developed for the analysis of automotive motor gasoline that contains oxygenates,
this test method can also be applied to other hydrocarbon streams having similar boiling ranges, such
as naphthas and reformates.
NOTE 2 For Procedure A, applicability of this document has also been verified for the determination of
n-propanol, acetone, and di-isopropyl ether (DIPE). However, no precision data have been determined for these
compounds.
Procedure B describes the analysis of oxygenated groups (ethanol, methanol, ethers, C3 – C5 alcohols)
in ethanol (E85) automotive fuel containing ethanol between 50 % (V/V) and 85 % (V/V). The gasoline
is diluted with an oxygenate-free component to lower the ethanol content to a value below 20 % (V/V)
before the analysis by GC.
The sample can be fully analysed including hydrocarbons. Precision data for the diluted sample are
only available for the oxygenated groups.
NOTE 3 For Procedure B, the precision can be used for an ethanol fraction from about 50 % up to 85 % (V/V).
For the ether fraction, the precision as specified in Table 6 can be used for samples containing at least 11 % (V/V)
of ethers. For the higher alcohol fraction, too few data were obtained to derive a full precision statement and the
data presented in Table 6 are therefore only indicative.
NOTE 4 An overlap between C9 and C10 aromatics can occur. However, the total is accurate. Isopropyl benzene
is resolved from the C8 aromatics and is included with the other C9 aromatics.

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SIST EN 16997:2017(Main)
Liquid petroleum products - Determination of the sulfur content in Ethanol (E85) automotive fuel - Wavelength dispersive X-ray fluorescence spectrometric method
EN 16997:2017

This European Standard specifies a wavelength-dispersive X-ray fluorescence (WDXRF) test method for
the determination of the sulfur content in ethanol (E85) automotive fuel [3], containing ethanol
between 50 % (V/V) and 85 % (V/V), from 5 mg/kg to 20 mg/kg, using instruments with either
monochromatic or polychromatic excitation.
NOTE 1 Sulfur contents higher than 20 mg/kg can be determined after sample dilution with an appropriate
solvent. However, the precision was not established for diluted samples.
NOTE 2 For the purposes of this European Standard, the terms “% (m/m)” and “% (V/V)” are used to represent
the mass fraction (μ) and the volume fraction (φ) of a material respectively.
WARNING — The use of this Standard can involve hazardous materials, operations and equipment.
This Standard does not purport to address all of the safety problems associated with its use. It is the
responsibility of users of this standard to take appropriate measures to ensure the safety and health of
personnel prior to application of the standard, and fulfil statutory and regulatory requirements for this
purpose.

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