ASTM E28-14

Standard Test Methods for Softening Point of Resins Derived from Pine Chemicals and Hydrocarbons, by Ring-and-Ball Apparatus

SIGNIFICANCE AND USE
3.1 In general, with materials of these types, softening does not take place at a definite temperature. As the temperature rises, these materials gradually change from brittle or exceedingly thick and slow-flowing materials to softer and less viscous liquids. For this reason, the determination of the softening point must be made by a fixed, arbitrary, and closely defined method if the results obtained are to be comparable.  
3.2 In these test methods, the softening point is defined as the temperature at which a disk of the sample held within a horizontal ring is forced downward a distance of 25.4 mm (1 in.) under the weight of a steel ball as the sample is heated at 5°C/min in a water, glycerin, silicone oil, ethylene glycol/water or glycerin/water bath.  
3.3 The automatic method was chosen to be the reference method because a round robin demonstrated that it gave more precise results than the manual method.
SCOPE
1.1 These test methods are intended for determining the softening point of resins (including rosin and terpene resins) and similar materials by means of the ring-and-ball apparatus.  
Note 1: For testing asphalts, tars, and pitches, see Test Method D36.  
1.1.1 Test method using the automated ring and ball softening point apparatus is the reference method and  
1.1.2 Test method using the manual ring and ball softening point apparatus is an alternative method.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

• Status: Historical
• Publication Date: 30-Jun-2014
• ICS: 87.060.20 - Binders
• Technical Committee: D01 - Paint and Related Coatings, Materials, and Applications
• Drafting Committee: D01.34 - Pine Chemicals and Hydrocarbon Resins

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: E28 − 14
Standard Test Methods for
Softening Point of Resins Derived from Pine Chemicals and
1
Hydrocarbons, by Ring-and-Ball Apparatus
ThisstandardisissuedunderthefixeddesignationE28;thenumberimmediatelyfollowingthedesignationindicatestheyearoforiginal
adoptionor,inthecaseofrevision,theyearoflastrevision.Anumberinparenthesesindicatestheyearoflastreapproval.Asuperscript
epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope rises, these materials gradually change from brittle or exceed-
ingly thick and slow-flowing materials to softer and less
1.1 These test methods are intended for determining the
viscous liquids. For this reason, the determination of the
softening point of resins (including rosin and terpene resins)
softening point must be made by a fixed, arbitrary, and closely
and similar materials by means of the ring-and-ball apparatus.
defined method if the results obtained are to be comparable.
NOTE 1—For testing asphalts, tars, and pitches, see Test Method D36.
3.2 In these test methods, the softening point is defined as
1.1.1 Test method using the automated ring and ball soften-
the temperature at which a disk of the sample held within a
ing point apparatus is the reference method and
horizontal ring is forced downward a distance of 25.4 mm
1.1.2 Test method using the manual ring and ball softening
(1in.) under the weight of a steel ball as the sample is heated
point apparatus is an alternative method.
at 5°C/min in a water, glycerin, silicone oil, ethylene glycol/
1.2 The values stated in SI units are to be regarded as the
water or glycerin/water bath.
standard. The values given in parentheses are for information
3.3 The automatic method was chosen to be the reference
only.
method because a round robin demonstrated that it gave more
1.3 This standard does not purport to address all of the
precise results than the manual method.
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
4. Sample Preparation
priate safety and health practices and determine the applica-
4.1 Preparation of Sample by the Pour Method:
bility of regulatory limitations prior to use.
4.1.1 This procedure is suitable for materials that can be
2. Referenced Documents
heated and poured without adverse effects on the softening
2
2.1 ASTM Standards:
point.
D36TestMethodforSofteningPointofBitumen(Ring-and-
4.1.2 Select a sample representative of the material to be
Ball Apparatus)
tested.Thesampleshouldconsistofflakes,pastilles,orfreshly
E1Specification for ASTM Liquid-in-Glass Thermometers
broken lumps free of oxidized surfaces. Avoid inclusion of
E177Practice for Use of the Terms Precision and Bias in
finely divided material or dust.
ASTM Test Methods
4.1.3 Selectaquantityatleasttwicethatnecessarytofillthe
E691Practice for Conducting an Interlaboratory Study to
desired number of rings, and melt it immediately in a clean
Determine the Precision of a Test Method
container, using an oven, hot plate, sand bath or oil bath to
prevent local overheating. Take care to avoid incorporating air
3. Significance and Use
bubbles in the sample. Melt the sample completely, but do not
3.1 In general, with materials of these types, softening does
heat it above a temperature necessary to pour the material
not take place at a definite temperature. As the temperature
readily. The time from the beginning of heating to the pouring
of the sample should not exceed 15 min.
1
These test methods are under the jurisdiction of ASTM Committee D01 on
Paint and Related Coatings, Materials, and Applications and are the direct
NOTE 2—For materials that may be heat sensitive, continuously inert
responsibility of Subcommittee D01.34 on Pine Chemicals and Hydrocarbon
the flask containing the test specimen with nitrogen (N ) during the
2
Resins.
remelting procedure.
Current edition approved July 1, 2014. Published August 2014. Originally
4.1.4 Formaterialsthattendtocrackorshrinkintheringon
approvedin1936.Lastpreviouseditionapprovedin2009asE28–99(2009).DOI:
10.1520/E0028-14.
cooling, immediately before filling the ring, preheat the ring to
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
approximately the temperature at which the material is to be
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
poured. The ring, while being filled, should rest bottom down
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. on a suitable metal surface. Pour the sample into the ring so as
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: E28 − 99 (Reapproved 2009) E28 − 14
Standard Test Methods for
Softening Point of Resins Derived from Naval Stores Pine
1
Chemicals and Hydrocarbons, by Ring-and-Ball Apparatus
This standard is issued under the fixed designation E28; the number immediately following the designation indicates the year of original
adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript
epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope
1.1 These test methods are intended for determining the softening point of resins (including rosin and terpene resins) and similar
materials by means of the ring-and-ball apparatus.
NOTE 1—For testing asphalts, tars, and pitches, see Test Method D36.
1.1.1 Test method using the manualautomated ring and ball softening point apparatus, apparatus is the reference method and
1.1.2 Test method using an automatedthe manual ring and ball softening point apparatus.apparatus is an alternative method.
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
D36 Test Method for Softening Point of Bitumen (Ring-and-Ball Apparatus)
E1 Specification for ASTM Liquid-in-Glass Thermometers
E177 Practice for Use of the Terms Precision and Bias in ASTM Test Methods
E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
3. Significance and Use
3.1 In general, with materials of these types, softening does not take place at a definite temperature. As the temperature rises,
these materials gradually change from brittle or exceedingly thick and slow-flowing materials to softer and less viscous liquids.
For this reason, the determination of the softening point must be made by a fixed, arbitrary, and closely defined method if the results
obtained are to be comparable.
3.2 In these test methods, the softening point is defined as the temperature at which a disk of the sample held within a horizontal
ring is forced downward a distance of 25.4 mm (1 in.)mm (1 in.) under the weight of a steel ball as the sample is heated at 5°C/min
in a water, glycerin, silicone oil, ethylene glycol/water or glycerin/water bath.
3.3 The automatic method was chosen to be the reference method because a round robin demonstrated that it gave more precise
results than the manual method.
4. Sample Preparation
4.1 Preparation of Sample by the Pour Method:
4.1.1 This procedure is suitable for materials that can be heated and poured without adverse effects on the softening point.
1
These test methods are under the jurisdiction of ASTM Committee D01 on Paint and Related Coatings, Materials, and Applications and are the direct responsibility of
Subcommittee D01.34 on Pine Chemicals and Hydrocarbon Resins.
Current edition approved June 1, 2009July 1, 2014. Published June 2009August 2014. Originally approved in 1936. Last previous edition approved in 20042009 as
E28 – 99 (2004).(2009). DOI: 10.1520/E0028-99R09.10.1520/E0028-14.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM Standards
volume information, refer to the standard’sstandard’s Document Summary page on the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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E28 − 14
4.1.2 Select a sample representative of the material to be tested. The sample should consist of flakes, pastilles, or freshly broken
lumps free of oxidized surfaces. Avoid inclusion of finely divided material or dust.
4.1.3 Select a quantity at least twice that necessary to fill the desired number of rings, and melt it immediately in a clean
container, using an oven, hot plate, sand bath or oil bath to prevent local overheating. Take care to avoid incorporating air bubbles
in the sample. Melt the sample completely, but do not heat it above a temperature necessary to pour the material readily. The time
from the beginnin
...