Standard Specification for Low Toluene Low Dioxane (LTLD) Benzene

ABSTRACT
This specification covers the requirements for a grade of benzene known as low toluene low dioxane (LTLD) benzene. Sampled materials shall meet specified values of the following physical and chemical properties: purity; toluene content; sulfur content; thiophene content; nonaromatic hydrocarbons content; nitrogen content; acid wash color; color in Pt-Co scale; 1,4 dioxane content; anhydrous basis solidification point; water content; and total chlorides.
SCOPE
1.1 This specification covers a grade of benzene known as Low Toluene Low Dioxane (LTLD) Benzene.
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA regulations, supplier's Material Safety Data Sheets, and local regulations for all materials used in this specification.

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Publication Date
30-Nov-2008
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D7185 – 08
Standard Specification for
1
Low Toluene Low Dioxane (LTLD) Benzene
This standard is issued under the fixed designation D7185; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* D3437 Practice for Sampling and Handling Liquid Cyclic
Products
1.1 This specification covers a grade of benzene known as
D4492 Test Method for Analysis of Benzene by Gas Chro-
Low Toluene Low Dioxane (LTLD) Benzene.
matography
1.2 The following applies to all specified limits in this
D4735 Test Method for Determination of Trace Thiophene
standard: for purposes of determining conformance with this
in Refined Benzene by Gas Chromatography
standard, an observed value or a calculated value shall be
D5194 Test Method for Trace Chloride in Liquid Aromatic
rounded off “to the nearest unit” in the last right-hand digit
Hydrocarbons
used in expressing the specification limit, in accordance with
D5386 Test Method for Color of Liquids Using Tristimulus
the rounding-off method of Practice E29.
Colorimetry
1.3 The values stated in SI units are to be regarded as the
D5808 Test Method for Determining Chloride in Aromatic
standard. The values given in parentheses are for information
Hydrocarbons and Related Chemicals by Microcoulom-
only.
etry
1.4 Consult current OSHA regulations, supplier’s Material
D6069 Test Method for Trace Nitrogen inAromatic Hydro-
Safety Data Sheets, and local regulations for all materials used
carbons by Oxidative Combustion and Reduced Pressure
in this specification.
Chemiluminescence Detection
2. Referenced Documents
D6304 Test Method for Determination of Water in Petro-
2
leum Products, Lubricating Oils, and Additives by Coulo-
2.1 ASTM Standards:
metric Karl Fischer Titration
D848 Test Method for Acid Wash Color of Industrial
D6875 Test Method for Solidification Point of Industrial
Aromatic Hydrocarbons
Organic Chemicals by Thermistor
D852 Test Method for Solidification Point of Benzene
D7011 Test Method for Determination of Trace Thiophene
D1209 Test Method for Color of Clear Liquids (Platinum-
in Refined Benzene by Gas Chromatography and Sulfur
Cobalt Scale)
Selective Detection
D1685 Test Method for Traces of Thiophene in Benzene by
D7183 Test Method for Determination of Total Sulfur in
Spectrophotometry
Aromatic Hydrocarbons and Related Chemicals by Ultra-
violet Fluorescence
1
D7184 Test Method for Ultra Low Nitrogen in Aromatic
This specification is under the jurisdiction of ASTM Committee D16 on
Aromatic Hydrocarbons and Related Chemicals and is the direct responsibility of Hydrocarbons by Oxidative Combustion and Reduced
Subcommittee D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their
Pressure Chemiluminescence Detection
Derivatives.
D7375 Test Method for Trace Quantities of Water in Aro-
Current edition approved Dec. 1, 2008. Published December 2008. Originally
matic Hydrocarbons and Their Mixtures by Coulometric
approved in 2006. Last previous edition approved in 2007 as D7185 - 07. DOI:
10.1520/D7185-08.
Karl Fischer Titration
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
E29 Practice for Using Significant Digits in Test Data to
contact ASTM Customer Service at service@astm.org. For An
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D7185–07 Designation: D 7185 – 08
Standard Specification for
1
Low Toluene Low Dioxane (LTLD) Benzene
This standard is issued under the fixed designation D 7185; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification covers a grade of benzene known as Low Toluene Low Dioxane (LTLD) Benzene.
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard,
an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing
the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA regulations, supplier’s Material Safety Data Sheets, and local regulations for all materials used in
this specification.
2. Referenced Documents
2
2.1 ASTM Standards:
D 848 Test Method for Acid Wash Color of Industrial Aromatic Hydrocarbons
D 852 Test Method for Solidification Point of Benzene
D 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D 1685 Test Method for Traces of Thiophene in Benzene by Spectrophotometry
D 3437 Practice for Sampling and Handling Liquid Cyclic Products
D 4492 Test Method for Analysis of Benzene by Gas Chromatography
D 4735 Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography
D 5194 Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
D 5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
D 5808 Test Method for Determining Organic Chloride inAromatic Hydrocarbons and Related Chemicals by Microcoulometry
D 6069 Test Method for Trace Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D 6304 Test Method for Determination of Water in Petroleum Products, Lubricating Oils, and Additives by Coulometric Karl
Fischer Titration
D 6875 Test Method for Solidification Point of Industrial Organic Chemicals by Thermistor
D 7011 Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography and Sulfur Selective
Detection
D 7183 Test Method for Determination of Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet
Fluorescence
D 7184 Test Method for Ultra Low Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D 7375 Test Method for Trace Quantities of Water inAromatic Hydrocarbons and Their Mixtures by Coulometric Karl Fischer
Titration
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
2.2 Other Document:
3
OSHA Regulations, 29 CFR paragraphs 1910.1000 and 1910.1200
1
This specification is under the jurisdiction ofASTM Committee D16 onAromatic Hydrocarbons and Related Chemicals and is the direct responsibility of Subcommittee
D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives.
Current edition approved JuneDec. 1, 2007.2008. Published July 2007.December 2008. Originally approved in 2006. Last previous edition approved in 20062007 as
D 7185 - 067.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. ForAnnualBookofASTMStandards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Available from U.S. Government Printing Office Superintendent of Documents, 732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401, http://
www.access.gpo.gov.
*ASummary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D7185–08
3. Properties
3.1 Low Toluene Low Dioxane (LTLD) Benzene shall conform to the following requirements:
Property Specification ASTM Test
A
Method
Purity, min, weight % 99.80 D 4492
Toluene, max, weight % 0.05 D 4492
Sulfur, max, mg/kg (if needed) D 7183
Thiophene, max, mg/kg 1.0 D 1685 or D 4735 or
D 7011
Nonaromatic hydrocarbons, max, 0.15 D 4492
weight %
Nitrogen, max., mg/kg (if needed) D 6069 or D 7184
Acid wash color
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D7185–07 Designation: D 7185 – 08
Standard Specification for
1
Low Toluene Low Dioxane (LTLD) Benzene
This standard is issued under the fixed designation D 7185; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This specification covers a grade of benzene known as Low Toluene Low Dioxane (LTLD) Benzene.
1.2 The following applies to all specified limits in this standard: for purposes of determining conformance with this standard,
an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing
the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA regulations, supplier’s Material Safety Data Sheets, and local regulations for all materials used in
this specification.
2. Referenced Documents
2
2.1 ASTM Standards:
D 848 Test Method for Acid Wash Color of Industrial Aromatic Hydrocarbons
D 852 Test Method for Solidification Point of Benzene
D 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)
D 1685 Test Method for Traces of Thiophene in Benzene by Spectrophotometry
D 3437 Practice for Sampling and Handling Liquid Cyclic Products
D 4492 Test Method for Analysis of Benzene by Gas Chromatography
D 4735 Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography
D 5194 Test Method for Trace Chloride in Liquid Aromatic Hydrocarbons
D 5386 Test Method for Color of Liquids Using Tristimulus Colorimetry
D 5808 Test Method for Determining Organic Chloride inAromatic Hydrocarbons and Related Chemicals by Microcoulometry
D 6069 Test Method for Trace Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D 6304 Test Method for Determination of Water in Petroleum Products, Lubricating Oils, and Additives by Coulometric Karl
Fischer Titration
D 6875 Test Method for Solidification Point of Industrial Organic Chemicals by Thermistor
D 7011 Test Method for Determination of Trace Thiophene in Refined Benzene by Gas Chromatography and Sulfur Selective
Detection
D 7183 Test Method for Determination of Total Sulfur in Aromatic Hydrocarbons and Related Chemicals by Ultraviolet
Fluorescence
D 7184 Test Method for Ultra Low Nitrogen in Aromatic Hydrocarbons by Oxidative Combustion and Reduced Pressure
Chemiluminescence Detection
D 7375 Test Method for Trace Quantities of Water inAromatic Hydrocarbons and Their Mixtures by Coulometric Karl Fischer
Titration
E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
2.2 Other Document:
3
OSHA Regulations, 29 CFR paragraphs 1910.1000 and 1910.1200
1
This specification is under the jurisdiction ofASTM Committee D16 onAromatic Hydrocarbons and Related Chemicals and is the direct responsibility of Subcommittee
D16.01 on Benzene, Toluene, Xylenes, Cyclohexane and Their Derivatives.
Current edition approved JuneDec. 1, 2007.2008. Published July 2007.December 2008. Originally approved in 2006. Last previous edition approved in 20062007 as
D 7185 - 067.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. ForAnnualBookofASTMStandards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Available from U.S. Government Printing Office Superintendent of Documents, 732 N. Capitol St., NW, Mail Stop: SDE, Washington, DC 20401, http://
www.access.gpo.gov.
*ASummary of Changes section appears at the end of this standard.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D7185–08
3. Properties
3.1 Low Toluene Low Dioxane (LTLD) Benzene shall conform to the following requirements:
Property Specification ASTM Test
A
Method
Purity, min, weight % 99.80 D 4492
Toluene, max, weight % 0.05 D 4492
Sulfur, max, mg/kg (if needed) D 7183
Thiophene, max, mg/kg 1.0 D 1685 or D 4735 or
D 7011
Nonaromatic hydrocarbons, max, 0.15 D 4492
weight %
Nitrogen, max., mg/kg (if needed) D 6069 or D 7184
Acid wash color
...

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