iTeh StandardsiTeh Standards
EURUSD
Your shopping cart is empty.
ASTM

ASTM D4752-03

(Test Method)

Standard Test Method for Measuring MEK Resistance of Ethyl Silicate (Inorganic) Zinc-Rich Primers by Solvent Rub

Standard Test Method for Measuring MEK Resistance of Ethyl Silicate (Inorganic) Zinc-Rich Primers by Solvent Rub

SIGNIFICANCE AND USE
Ethyl silicate zinc-rich primers cure by the reaction of the vehicle with moisture, thereby providing a binder. As relative humidity and temperature vary during the day, so does the rate of cure. A certain minimum degree of cure is necessary prior to topcoating. It has been shown that the degree of cure of ethyl silicate zinc-rich primers can be measured by the chemical changes occurring using diffuse reflectance infrared spectroscopy.2 This solvent rub test has been shown to correlate well with the infrared spectroscopic results of some two-component ethyl silicate inorganic zinc systems.
The cure rating required for the application of specific topcoats must be agreed upon before the test method is used.
SCOPE
1.1 This test method describes a solvent rub technique for assessing the MEK resistance of ethyl silicate (inorganic) zinc-rich primers. The MEK resistance of some two-component ethyl silicate zinc-rich primers has been shown to correlate well with the cure of the primer as determined by diffuse reflectance infrared spectroscopy. The technique can be used in the laboratory, field, or in the fabricating shop. Practice D 5402 is the preferred method for organic coatings.
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazard statements are given in Section 6. Consult supplier's Material Safety Data Sheet(s) for specific hazard information relating to the solvent used.

General Information

Status
Historical
Publication Date
09-Jan-2003
ICS
87.040 - Paints and varnishes
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.46 - Industrial Protective Coatings
Current Stage
Ref Project

Relations

Replaces
ASTM D4752-98 - Standard Test Method for Measuring MEK Resistance of Ethyl Silicate (Inorganic) Zinc-Rich Primers by Solvent Rub
Effective Date
10-Jan-2003
Replaced By
ASTM D4752-10 - Standard Practice for Measuring MEK Resistance of Ethyl Silicate (Inorganic) Zinc-Rich Primers by Solvent Rub
Effective Date
01-Feb-2010
Referred By
ASTM D5498-12a(2018) - Standard Guide for Developing a Training Program for Personnel Performing Coating and Lining Work Inspection for Nuclear Facilities
Effective Date
10-Jan-2003
Referred By
ASTM F2831-19 - Standard Practice for Internal Non Structural Epoxy Barrier Coating Material Used In Rehabilitation of Metallic Pressurized Piping Systems
Effective Date
10-Jan-2003
Referred By
ASTM D6577-15(2019) - Standard Guide for Testing Industrial Protective Coatings
Effective Date
10-Jan-2003
Referred By
ASTM D3276-21 - Standard Guide for Painting Inspectors (Metal Substrates)
Effective Date
10-Jan-2003
Referred By
ASTM D5402-19 - Standard Practice for Assessing the Solvent Resistance of Organic Coatings Using Solvent Rubs
Effective Date
10-Jan-2003

Buy Standard

ASTM D4752-03 - Standard Test Method for Measuring MEK Resistance of Ethyl Silicate (Inorganic) Zinc-Rich Primers by Solvent RubASTM D4752-03 - Standard Test Method for Measuring MEK Resistance of Ethyl Silicate (Inorganic) Zinc-Rich Primers by Solvent Rub
PreviousNext
Standard
ASTM D4752-03 - Standard Test Method for Measuring MEK Resistance of Ethyl Silicate (Inorganic) Zinc-Rich Primers by Solvent Rub
English language
8 pages
sale 15% off
Preview
sale 15% off
Preview

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information.
Designation:D4752–03
Standard Test Method for
Measuring MEK Resistance of Ethyl Silicate (Inorganic)
1
Zinc-Rich Primers by Solvent Rub
This standard is issued under the fixed designation D4752; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
4
1. Scope a Nonferrous Metal Base
D4138 PracticesforMeasurementofDryFilmThicknessof
1.1 This test method describes a solvent rub technique for
Protective Coating Systems by Destructive, Cross-
assessing the MEK resistance of ethyl silicate (inorganic)
Sectioning Means
zinc-rich primers. The MEK resistance of some two-
D5402 Practice for Assessing the Solvent Resistance of
component ethyl silicate zinc-rich primers has been shown to
Organic Coatings Using Solvent Rubs
correlate well with the cure of the primer as determined by
2
diffuse reflectance infrared spectroscopy. The technique can
3. Terminology
be used in the laboratory, field, or in the fabricating shop.
3.1 Definitions of Terms Specific to This Standard:
Practice D5402 is the preferred method for organic coatings.
3.1.1 double rub—the act of rubbing a solvent saturated
1.2 The values stated in SI units are to be regarded as the
cloth in one complete forward and backward motion over a
standard. The values given in parentheses are for information
coated surface.
only.
1.3 This standard does not purport to address all of the
4. Significance and Use
safety concerns, if any, associated with its use. It is the
4.1 Ethyl silicate zinc-rich primers cure by the reaction of
responsibility of the user of this standard to establish appro-
the vehicle with moisture, thereby providing a binder. As
priate safety and health practices and determine the applica-
relative humidity and temperature vary during the day, so does
bility of regulatory limitations prior to use. Specific hazard
the rate of cure.Acertain minimum degree of cure is necessary
statements are given in Section 6. Consult supplier’s Material
prior to topcoating. It has been shown that the degree of cure
Safety Data Sheet(s) for specific hazard information relating to
of ethyl silicate zinc-rich primers can be measured by the
the solvent used.
chemical changes occurring using diffuse reflectance infrared
2
2. Referenced Documents spectroscopy. This solvent rub test has been shown to corre-
3 late well with the infrared spectroscopic results of some
2.1 ASTM Standards:
two-component ethyl silicate inorganic zinc systems.
D740 Specification for Methyl Ethyl Ketone
4.2 The cure rating required for the application of specific
D1186 Test Methods for Nondestructive Measurement of
topcoats must be agreed upon before the test method is used.
Dry Film Thickness of Nonmagnetic Coatings Applied to
4
a Ferrous Base
5. Reagents and Materials
D1400 Test Method for Nondestructive Measurement of
5.1 Methyl Ethyl Ketone (MEK), in accordance with Speci-
DryFilmThicknessofNonconductiveCoatingsAppliedto
fication D740.
5.2 Cheesecloth, 100 % cotton mesh size grade 28 by 24
1
This test method is under the jurisdiction of ASTM Committee D01 on Paint
approximately 300- by 300-mm (12- by 12-in.) and contrasting
and Related Coatings, Materials, andApplications and is the direct responsibility of
in color to the coating being evaluated, or other mutually
Subcommittee D01.46 on Industrial Protective Coatings.
agreed upon cloth.
Current edition approved Jan. 10, 2003. Published March 2003. Originally
approved in 1987. Last previous edition approved in 1998 as D4752 – 98. DOI: 5.3 Squeeze Bottle.
10.1520/D4752-03.
5.4 Proper Safety Equipment, as determined from the sol-
2
Starr, T. L., Henton, L. E., Lewis, W. S., and Rideout, F. A., “Improved Field
vent MSDS, for example, solvent resistant gloves, respirator.
Reliability of High Performance Coating Systems: Phase II—Develop Procedures
and Criteria in Critical Performance Areas,” available from SSPC: The Society for
6. Procedure
Protective Coatings, 40 24th St., Sixth Floor, Pittsburgh, PA 15213, www.sspc.org.
3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
6.1 Selectareasontheprimersurfaceatleast150mm(6in.)
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
long on which to run the tests. Clean the surface with tap water
Standards volume information, refer to the standard’s Document Summary page on
or dry cloth to remove loose material.
the ASTM website.
4
Withdrawn. The last approved version of this historical standard is referenced
on www.astm.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

--------------------
...

Questions, Comments and Discussion

Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.

This May Also Interest You

ASTM
ASTM D7190-10(2023)(Practice)
Standard Practice to Evaluate Leaching of Water-Soluble Materials from Latex Paint Films

SIGNIFICANCE AND USE
4.1 Surfactant staining is a common problem with exterior house paints, particularly when subjected to humid environments (such as morning dew) shortly after application.  
4.2 Interior paints used in humid areas such as kitchens and bathrooms may also experience surfactant staining.  
4.3 Leaching of water-soluble materials may be dependent on colorant dispersions that are mixed into tint base paints. Other paint components may also affect the leaching of water-soluble materials.
SCOPE
1.1 This practice covers the ability of a latex paint film to resist staining caused by the leaching of water-soluble materials when contacted with water shortly after application.  
1.2 Water staining is attributed to the leaching of surfactants or other water-soluble materials from a paint film.  
1.3 The values stated in SI units are to be regarded as standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D4287-00(2023)(Test Method)
Standard Test Method for High-Shear Viscosity Using a Cone/Plate Viscometer

SIGNIFICANCE AND USE
4.1 The viscosity value obtained by this test method gives information about the flow properties of the material under high-shear conditions similar to those encountered during application: brushing (see Test Method D4958), spraying, electrostatic disk, or roll coating.  
4.2 This test method is suitable for all paints and varnishes whether they are Newtonian in behavior or not. However, due to the narrow gap between the stationary and rotary parts of high-shear viscometers, this test method is more reproducible for paints having finer pigment dispersions as determined by Test Method D1210.
SCOPE
1.1 This test method covers the determination of the viscosity of paints, varnishes, and related products at a rate of shear of 12 000 s−1.  
1.2 Paints and varnishes that dry very rapidly may not give reproducible results with this test method. Measurements made at elevated temperatures may also give poor precision due to loss of volatiles and to drying.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    4 pages
    English language
    sale 15% off
ASTM
ASTM D4214-23(Test Method)
Standard Test Methods for Evaluating the Degree of Chalking of Exterior Paint Films

SIGNIFICANCE AND USE
4.1 The procedures provide a broad range of techniques and photographic references to evaluate chalking of exterior paints.
SCOPE
1.1 These test methods cover the evaluation of the degree of chalking on white or tinted exterior paint films. These test methods describe the procedures recommended for transferring the chalk to a fabric or fingertip, which is then compared to photographic reference standards, or in the case of adhesive tapes, compared to a reflectance table or photographic reference standards, to determine the degree of chalking.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    7 pages
    English language
    sale 15% off
  • Standard
    7 pages
    English language
    sale 15% off
ASTM
ASTM D4147-18(2023)(Practice)
Standard Practice for Applying Coil Coatings Using Wire-Wound Drawdown Bars

SIGNIFICANCE AND USE
3.1 This practice is useful in the laboratory to simulate roll-coated films.
SCOPE
1.1 This practice covers a procedure for applying a coil coating film of uniform thickness on a flat metal panel using wire-wound drawdown bars.  
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.3 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D16-23(Terminology)
Standard Terminology for Paint, Related Coatings, Materials, and Applications

SCOPE
1.1 This standard consists of technical terms used in standards under the jurisdiction of ASTM Committee D01 (on Paint and Related Coatings, Materials, and Applications), and of definitions suitable for use in these standards.
Note 1: When any definition in this standards is quoted or published out of the context of this standard, editorially insert the following delimiting statement “for paints and related coatings, materials, and applications” after the dash following the term (in the absence of an existing delimiting statement). This will limit the filed of application of the term and definition to that approved by this committee.  
1.2 In this terminology standard, definitions used in other ASTM standards are indicated by following the definition with the designation of that standard. In some cases, a relevant D01 subcommittee is also listed. Definitions influenced by those used by other organizations are indicated by the acronym of the organization. Primary terms are given in bold, while narrower and unapproved terms are given in italics.  
1.3 There are several specialized terminology standards under the jurisdiction of Committee D01, as follows: D804, D1695, D6440, D6488, and D7188. Few definitions from those standards are included in Terminology D16. Therefore, in searches for definitions of paints and coatings terms, these standards should be included where appropriate.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    10 pages
    English language
    sale 15% off
  • Standard
    10 pages
    English language
    sale 15% off
ASTM
ASTM D3732-23(Practice)
Standard Practice for Reporting Cure Times of Ultraviolet-Cured Coatings

SIGNIFICANCE AND USE
4.1 This practice provides a guide whereby all pertinent variables relating to the ultraviolet cure of a coating are described.
SCOPE
1.1 This practice applies to all coatings cured by ultraviolet energy.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D1644-01(2023)(Test Method)
Standard Test Methods for Nonvolatile Content of Varnishes

SIGNIFICANCE AND USE
2.1 These test methods are applicable to varnish and are useful to producers and users in determining nonvolatile content and are sometimes an appropriate measure of the film-forming matter in varnish.
SCOPE
1.1 These test methods determine the fraction of a varnish that is nonvolatile at the temperature of the test while volatile solvents are driven off. It is sometimes an approximate measure of the film-forming matter in a varnish.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For a specific statement, see Section 3.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    2 pages
    English language
    sale 15% off
ASTM
ASTM D6486-23(Practice)
Standard Practice for Short Term Vehicle Service Exposure of Automotive Coatings

SIGNIFICANCE AND USE
4.1 Since the exposure of automotive coatings to the various mechanical and chemical stresses encountered in actual operations, is very opportunistic, obtaining statistically significant data from which valid conclusions can be drawn, requires rigorous attention to the experimental designs and conditions of exposure.
SCOPE
1.1 This practice covers the protocol for vehicle service exposure testing of automotive coatings. Such exposure testing is valuable for the verification of the performance of automotive coatings and correlation with laboratory test data. Vehicle service exposure is intended to provide short term (2 to 20 weeks) exposure to the stress factors associated with vehicle operation. Factors included are scratch, mar, impact, stone chipping, insect impact, bird dropping, tree sap and staining, environmental fallout, etc.
Note 1: Vehicle service exposure is not intended to provide the conditions that are needed for characterizing the long term effects of weathering or corrosion exposure.  
1.2 The exposure conditions are produced by the placement of multiple test panels of automotive finishes on automotive test fleets that traverse a defined road course. Exposure to the operating environment can be 20 h/day, 7 days/week allowing for accumulation of over 100 000 miles in 10 weeks of exposure.  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    3 pages
    English language
    sale 15% off
  • Standard
    3 pages
    English language
    sale 15% off
ASTM
ASTM D2805-11(2023)(Test Method)
Standard Test Method for Hiding Power of Paints by Reflectometry

SIGNIFICANCE AND USE
5.1 This is a precise instrumental method giving results having an absolute physical significance without reference to a comparison paint. It should be used when maximum precision and minimum subjectivity are required, as in testing specification coatings or evaluating the hiding efficiency of pigments.  
5.2 Hiding power Test Method D344 is visual instead of instrumental, and gives results that are relative to a material standard instead of absolute. It is less precise than Test Method D2805 but more closely aligned with practical painting procedures.
SCOPE
1.1 This test method covers the determination, without reference to a material paint standard, of the hiding power of air dry coatings with Y tristimulus values greater than 15 %. With appropriate modification, it can also be used to test baking finishes.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    6 pages
    English language
    sale 15% off
ASTM
ASTM D6762-18(2023)(Test Method)
Standard Test Method for Determining the Hiding Power of Paint by Visual Evaluation of Spray Applied Coatings

SIGNIFICANCE AND USE
5.1 This test method determines hiding power of a test paint by visual evaluation of a spray applied coating.
Note 1: Test Method D2805 describes an instrumental method for determining hiding power. The paint film is applied at a uniform thickness (for example with a doctor blade), the film thickness is measured rigorously, and the opacity is determined photometrically. Hiding power is thereby determined with a high degree of precision.  
5.2 Test Method D6762 is less precise than Test Method D2805, but is commonly used since it is more closely related to the application characteristics of the paint and is simpler in concept and evaluation.
SCOPE
1.1 This test method provides for the quantitative visual determination of the film thickness required to achieve full hiding. This film thickness is considered to be the hiding power of a test paint.  
1.2 This method applies only to spray applied coatings but its concepts are valid for other methods of application as well.  
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

  • Standard
    4 pages
    English language
    sale 15% off