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ASTM D3595-14

(Specification)

Standard Specification for Polychlorotrifluoroethylene (PCTFE) Extruded Plastic Sheet and Film

Standard Specification for Polychlorotrifluoroethylene (PCTFE) Extruded Plastic Sheet and Film

ABSTRACT
This specification covers four types of polychlorotrifluoroethylene extruded plastic sheet and film: Type I - a transparent film with high and low moisture vapor transmission rate; Type II - a dimensionally stable transparent sheet and film with low moisture vapor transmission rate; Type III - a dimensionally stable transparent film with very low moisture vapor transmission rate; and Type IV - a low crystalline transparent film with high ductility and extremely low moisture vapor transmission rate. The specimens shall be manufactured from polychlorotrifluoroethylene plastics that consist of at least 90% chlorotrifluoethylene and 10% chemical modification such as co-monomers but not colorants, fillers, plasticizers, or mechanical blends of other resins. Tests shall be conducted to determine the specific property values of the specimen which shall conform to the tensile strength, elongation, dimensional stability or shrinkage, and moisture vapor transmission rate requirements.
SCOPE
1.1 This specification covers extruded sheet and film in thicknesses from 0.015 to 0.25 mm (0.0006 to 0.01 in.).  
1.2 The values stated in SI units shall be regarded as the standard.  
1.3 The following precautionary statement pertains only to the test methods portion, Section 9 of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Note 1—There is no known ISO equivalent to this standard.

General Information

Status
Historical
Publication Date
28-Feb-2014
ICS
83.140.10 - Films and sheets
Technical Committee
D20 - Plastics
Drafting Committee
D20.15 - Thermoplastic Materials
Current Stage
Ref Project

Relations

Replaces
ASTM D3595-02(2007) - Standard Specification for Polychlorotrifluoroethylene (PCTFE) Extruded Plastic Sheet and Film
Effective Date
01-Mar-2014
Replaced By
ASTM D3595-14(2019) - Standard Specification for Polychlorotrifluoroethylene (PCTFE) Extruded Plastic Sheet and Film
Effective Date
01-May-2019

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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D3595 −14
Standard Specification for
Polychlorotrifluoroethylene (PCTFE) Extruded Plastic Sheet
1
and Film
This standard is issued under the fixed designation D3595; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* IEEE/ASTM SI 10 Standard for Use of the International
3
System of Units (SI): The Modern Metric System
1.1 This specification covers extruded sheet and film in
thicknesses from 0.015 to 0.25 mm (0.0006 to 0.01 in.).
3. Terminology
1.2 The values stated in SI units shall be regarded as the
3.1 Definitions of terms used in this specification shall be in
standard.
accordance with Terminology D883.
1.3 The following precautionary statement pertains only to
3.2 lot, n—one production run or a uniform blend of two or
the test methods portion, Section 9 of this specification:This
more production runs.
standarddoesnotpurporttoaddressallofthesafetyconcerns,
3.3 Abbreviations are in accordance with Terminology
ifany,associatedwithitsuse.Itistheresponsibilityoftheuser
D1600. PCTFE is the abbreviation for polychlorotrifluoroeth-
of this standard to establish appropriate safety and health
ylene.
practices and determine the applicability of regulatory limita-
tions prior to use.
4. Classification
NOTE 1—There is no known ISO equivalent to this standard.
4.1 This specification covers four types of polychlorotrif-
4
luoroethylene sheet and film:
2. Referenced Documents
4.1.1 Type I—Transparent film, with high and low moisture
2
2.1 ASTM Standards:
vapor transmission rate.
D618 Practice for Conditioning Plastics for Testing
4.1.2 Type II—Dimensionally stable transparent sheet and
D882 Test Method for Tensile Properties of Thin Plastic
film with low moisture vapor transmission rate.
Sheeting
4.1.3 Type III—Dimensionally stable transparent film with
D883 Terminology Relating to Plastics
very low moisture vapor transmission rate.
D1204 Test Method for Linear Dimensional Changes of
4.1.4 Type IV—Low crystalline transparent film with high
Nonrigid Thermoplastic Sheeting or Film at Elevated
ductility and extremely low moisture vapor transmission.
Temperature
4.2 A one-line system may be used to specify materials
D1430 ClassificationSystemforPolychlorotrifluoroethylene
covered by this specification. The system uses predefined cells
(PCTFE) Plastics
to refer to specific aspects of this specification, as illustrated
D1600 Terminology forAbbreviatedTerms Relating to Plas-
below.
tics
D3892 Practice for Packaging/Packing of Plastics Specification
Standard Number : : : : Special
F1249 Test Method for Water Vapor Transmission Rate
Type Grade Class
Block : : : : Notes
Through Plastic Film and Sheeting Using a Modulated
:::::
Infrared Sensor
-------------- --- --- --- -----
Example: Specification D3595—02, I 6 C
For this example, the line callout would be Specification
D3595 – 02, I6C, and would specify a coagulated dispersion
1
This specification is under the jurisdiction of ASTM Committee D20 on
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic form of polytetrafluoro-ethylene that has all of the properties
Materials.
listed for that Type, Grade, and Class in the appropriate
Current edition approved March 1, 2014. Published March 2014. Originally
approved in 1977. Last previous edition approved in 2007 as D3595 - 02(2007).
DOI: 10.1520/D3595-14.
2 3
For referenced ASTM standards, visit the ASTM website, www.astm.org, or Available from ASTM International, 100 Barr Harbor Drive, West
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Conshohocken, PA 19428–2959.
4
Standards volume information, refer to the standard’s Document Summary page on The basic polymer used to make these types of polymer does not correspond to
the ASTM website. the types given in Specification D1430.
*A Summary of Changes section appears at the end of this standard
Copyright ©ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA19428-2959. United States
1

---------------------- Page: 1 ----------------------
D3595−14
TABLE 1 Thickness Tolerance TABLE 2 Tensile Strength and Elongation
Thickness Tensile Strength, min
Elongation,
Tolerance,% TypeAvailability Thickness, mm (in.) Type
min,%
mm in. psi MPa
0.015 0.0006 ±20 IV 0.019 to 0.0075 I, II, III 2800 19.32 50
0.019 0.00075 ±20 III (0.00075 to 0.0015)
0.020 0.0008 ±20 IV 0.051 to 0.002 I, II, III 3100 21.40 50
0.0216 0.00085 ±20 IV (0.020 to 0.01)
0.023 0.0009 ±20 IV 0.015 to 0.191 IV 4000 27.60 70
0.038 0.0015 ±20 I, (0.0006 to 0.0075)
0.051 0.002 ±15 I, II, III, IV
0.064 0.0025 ±20 IV
0.076 0.003 ±15 II
TABLE 3 Dimens
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D3595 − 02 (Reapproved 2007) D3595 − 14
Standard Specification for
Polychlorotrifluoroethylene (PCTFE) Extruded Plastic Sheet
1
and Film
This standard is issued under the fixed designation D3595; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope Scope*
1.1 This specification covers extruded sheet and film in thicknesses from 0.015 to 0.25 mm (0.0006 to 0.01 in.).
1.2 The values stated in SI units shall be regarded as the standard.
1.3 The following precautionary statement pertains only to the test methods portion, Section 9 of this specification:This standard
does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this
standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
NOTE 1—There is no known ISO equivalent specification to this specification.standard.
2. Referenced Documents
2
2.1 ASTM Standards:
4
D374 Test Methods for Thickness of Solid Electrical Insulation (Withdrawn 2013)
D618 Practice for Conditioning Plastics for Testing
D882 Test Method for Tensile Properties of Thin Plastic Sheeting
D883 Terminology Relating to Plastics
D1204 Test Method for Linear Dimensional Changes of Nonrigid Thermoplastic Sheeting or Film at Elevated Temperature
D1430 Classification System for Polychlorotrifluoroethylene (PCTFE) Plastics
D1600 Terminology for Abbreviated Terms Relating to Plastics
D3892 Practice for Packaging/Packing of Plastics
F1249 Test Method for Water Vapor Transmission Rate Through Plastic Film and Sheeting Using a Modulated Infrared Sensor
3
IEEE/ASTM SI 10 Standard for Use of the International System of Units (SI): The Modern Metric System
3. Terminology
3.1 Definitions of terms used in this specification shall be in accordance with Terminology D883.
3.2 lot, n—one production run or a uniform blend of two or more production runs.
3.3 Abbreviations are in accordance with Terminology D1600. PCTFE is the abbreviation for polychlorotrifluoroethylene.
4. Classification
4
4.1 This specification covers four types of polychlorotrifluoroethylene sheet and film:
4.1.1 Type I—Transparent film, with high and low moisture vapor transmission rate.
4.1.2 Type II—Dimensionally stable transparent sheet and film with low moisture vapor transmission rate.
4.1.3 Type III—Dimensionally stable transparent film with very low moisture vapor transmission rate.
4.1.4 Type IV—Low crystalline transparent film with high ductility and extremely low moisture vapor transmission.
1
This specification is under the jurisdiction of ASTM Committee D20 on Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic Materials.
Current edition approved Sept. 1, 2007March 1, 2014. Published November 2007March 2014. Originally approved in 1977. Last previous edition approved in 20022007
as D3595 - 02.D3595 - 02(2007). DOI: 10.1520/D3595-02R07.10.1520/D3595-14.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Available from ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA 19428–2959.
4
The basic polymer used to make these types of polymer does not correspond to the types given in Specification D1430.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D3595 − 14
TABLE 1 Thickness Tolerance
Thickness
Tolerance, % Type Availability
mm in.
0.015 0.0006 ±20 IV
0.019 0.00075 ±20 III
0.020 0.0008 ±20 IV
0.0216 0.00085 ±20 IV
0.023 0.0009 ±20 IV
0.038 0.0015 ±20 I,
0.051 0.0002 ±15 I, II, III, IV
0.051 0.002 ±15 I, II, III, IV
0.064 0.0025 ±20 IV
0.076 0.0003 ±15 II
0.076 0.003 ±15 II
0.102 0.004 ±15 II
0.127 0.0005 ±15 II
0.127 0.005 ±15 II
0.140 0.0055 ±15 IV
0.152 0.006 ±15 IV
0.19 0.0075 ±10 II
0.20 0.0078 ±10 III
0.25 0.010 ±10 II
4.2 A one-line system may be used to specify materials covered by this specific
...

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1.1 This test method covers the measurement of the wetting tension of a polyethylene or polypropylene film surface in contact with drops of specific test solutions in the presence of air.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard.
Note 1: This test method and the specified reagents were specifically developed for polyethylene and polypropylene films. It is possible to utilize this test method and the specified reagents for films composed of other polymers, but this can affect the surface energies of the gas-liquid and solid-liquid interfaces, which will affect the contact angle and wetting tension. The applicability and significance for use of non-polyolefin materials must be established by the user.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 9.
Note 2: This test method is equivalent to ISO 8296.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D2291/D2291M-22(Practice)
Standard Practice for Fabrication of Ring Test Specimens for Glass-Resin Composites

SIGNIFICANCE AND USE
4.1 This practice provides a uniform procedure for fabricating glass fiber/thermoset resin ring samples for use as test specimens. Specimens so prepared can be used in Test Methods D2290 and D2344/D2344M.
SCOPE
1.1 This practice is intended for use in the fabrication of ring-type test specimens to be used in the evaluation of the mechanical properties of reinforcement and resins in a composite structure. The practice outlines the steps in the preparation of the test specimens, including the final specimen machining where applicable. Three final ring configurations are included.  
1.2 The values stated in either SI units or inch-pound units are to be regarded separately as standard. The values stated in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Combining values from the two systems may result in nonconformance with the standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: There is no known ISO equivalent to this practice.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D1494-22(Test Method)
Standard Test Method for Diffuse Light Transmission Factor of Reinforced Plastics Panels

SIGNIFICANCE AND USE
4.1 The purpose of this test method is to obtain the diffuse light transmittance factor of both flat and corrugated translucent building panels by the use of simple apparatus and by employing as a light source a combination of fluorescent tubes whose energy distribution closely approximates CIE Source C.
SCOPE
1.1 This test method covers the determination of the diffuse light transmission factor of translucent reinforced plastics building panels.  
1.2 The values stated in SI units are to be regarded as the standard. The values given in the parentheses are for information only.  
1.3 The text of this standard references notes and footnotes which provide explanatory material. These notes and footnotes (excluding those in Tables and Figures) shall not be considered as requirements of this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: There is no known ISO equivalent to this standard.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D1593-22(Specification)
Standard Specification for Nonrigid Vinyl Chloride Plastic Film and Sheeting

ABSTRACT
This specification covers nonrigid, unsupported vinyl chloride plastic film and sheeting in which the resin portion of the composition contains at least 90 % vinyl chloride. The remaining 10 % may include one or more monomers copolymerized with vinyl chloride, or consist of other resins mechanically blended together with poly(vinyl chloride) or copolymers thereof. The film and sheeting covered herein shall be 0.075 to 0.25 mm (3 to 10 mils) in thickness for film and greater than 0.25 mm in thickness for sheet, and shall include the stabilizers and plasticizers necessary to meet the requirements of this specification. The material may be transparent, translucent, or opaque, and may be plain, printed, embossed, or otherwise surface treated. This specification designates three general-purpose types of vinyl chloride film and sheeting - calendered, extruded, and cast. The materials shall be tested for its tensile strength and elongation at rapture, tear resistance, volatile loss, water extraction, low temperature impact, burning rate, shrinkage, and color fastness to rubbing.
SCOPE
1.1 This specification covers nonrigid, unsupported vinyl chloride plastic film and sheeting in which the resin portion of the composition contains at least 90 % vinyl chloride. The remaining 10 % can include one or more monomers copolymerized with vinyl chloride, or consist of other resins mechanically blended together with poly(vinyl chloride) or copolymers thereof.  
1.2 The vinyl chloride plastic film and sheeting covered herein shall be 0.075 to 0.25 mm (3 to 10 mils) in thickness for film and greater than 0.25 mm in thickness for sheeting. The film and sheeting shall include the stabilizers and plasticizers necessary to meet the requirements of this specification. This specification covers transparent, translucent, or opaque film and sheeting that is plain, printed, embossed, or otherwise surface treated.  
1.3 The values stated in SI units are to be regarded as the standard.  
1.4 The following safety hazards caveat pertains only to the test methods portion, Section 10, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
Note 1: There is no known ISO equivalent to this standard.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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