Standard Practice for Dynamic Mechanical Analysis and Thermogravimetry of Roofing and Waterproofing Membrane Material

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1.1 This practice covers test procedures and conditions that are applicable when Test Methods D5023, D5024, D5026, D5279, and D5418 are used for conducting dynamic mechanical analysis of roofing and waterproofing membrane material in three-point bending, compression, tension, torsion, and dual cantilever modes, respectively. The specific method is selected by the analyst and depends on the membrane material and the operating principles of the individual instrument used for the analysis.
1.2 This practice covers test procedures and conditions that are applicable when Test Method E1131 is used for conducting thermogravimetry of roofing and waterproofing membrane material.
1.3 Membrane materials include bituminous built-up roofing, polymer-modified bitumen sheets, vulcanized rubbers, non-vulcanized polymeric sheets, and thermoplastics. The membrane materials can be either nonreinforced or reinforced.
1.4 This practice is applicable to new membrane materials received from the supplier, those exposed artificially in the laboratory or outdoors on an exposure rack, and those sampled from field installations.
1.5 This practice contains notes which are explanatory and are not part of the mandatory requirements of this practice.
1.6 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.
1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Publication Date
09-Jan-1999
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ASTM D6382-99 - Standard Practice for Dynamic Mechanical Analysis and Thermogravimetry of Roofing and Waterproofing Membrane Material
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D 6382 – 99
Standard Practice for
Dynamic Mechanical Analysis and Thermogravimetry of
Roofing and Waterproofing Membrane Material
This standard is issued under the fixed designation D 6382; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope D 4092 Terminology Relating to Dynamic Mechanical
Measurements on Plastics
1.1 This practice covers test procedures and conditions that
D 5023 Test Method for Measuring the Dynamic Mechani-
are applicable when Test Methods D 5023, D 5024, D 5026,
cal Properties of Plastics Using Three Point Bending
D 5279, and D 5418 are used for conducting dynamic me-
D 5024 Test Method for Measuring the Dynamic Mechani-
chanical analysis of roofing and waterproofing membrane
cal Properties of Plastics in Compression
material in three-point bending, compression, tension, torsion,
D 5026 Test Method for Measuring the Dynamic Mechani-
and dual cantilever modes, respectively.The specific method is
cal Properties of Plastics in Tension
selected by the analyst and depends on the membrane material
D 5279 Test Method for Measuring the Dynamic Mechani-
and the operating principles of the individual instrument used
cal Properties of Plastics in Torsion
for the analysis.
D 5418 Test Method for Measuring the Dynamic Mechani-
1.2 This practice covers test procedures and conditions that
cal Properties of Plastics Using a Dual Cantilever Beam
areapplicablewhenTestMethodE 1131isusedforconducting
E 473 Terminology Relating to Thermal Analysis
thermogravimetry of roofing and waterproofing membrane
E 1131 Test Method for Compositional Analysis by Ther-
material.
mogravimetry
1.3 Membrane materials include bituminous built-up roof-
E 1142 Terminology Relating to Thermophysical Proper-
ing, polymer-modified bitumen sheets, vulcanized rubbers,
ties
non-vulcanized polymeric sheets, and thermoplastics. The
membrane materials can be either nonreinforced or reinforced.
3. Terminology
1.4 This practice is applicable to new membrane materials
3.1 Definitions—For definitions of terms used in this prac-
received from the supplier, those exposed artificially in the
tice, refer to Terminologies E 473, D 1079, D 4092, and
laboratory or outdoors on an exposure rack, and those sampled
E 1142.
from field installations.
1.5 This practice contains notes which are explanatory and
4. Summary of Practice
are not part of the mandatory requirements of this practice.
4.1 In conducting a dynamic mechanical analysis, the roof-
1.6 The values stated in SI units are to be regarded as the
ing or waterproofing membrane specimen is placed in a test
standard. The values in parentheses are for information only.
chamber and subjected to a controlled, increasing temperature
1.7 This standard does not purport to address all of the
program. The temperature range can be from well-below (for
safety concerns, if any, associated with its use. It is the
example, -80°C) to somewhat (for example, 50°C) above room
responsibility of the user of this standard to establish appro-
temperature. The glass transition temperature, storage modu-
priate safety and health practices and determine the applica-
lus, loss modulus, and damping factor of the specimen are
bility of regulatory limitations prior to use.
measured.
4.2 In conducting a thremogravimetry analysis, the roofing
2. Referenced Documents
or waterproofing membrane specimen is placed in a test
2.1 ASTM Standards:
chamber and subjected to a controlled, increasing temperature
D 1079 Terminology Relating to Roofing, Waterproofing,
program. The temperature range can be from about room
and Bituminous Materials
temperature (for example, 20 to 40°C) to well-above room
temperature (for example, 900°C), and the atmosphere of the
This practice is under the jurisdiction of ASTM Committee D-8 on Roofing,
Waterproofing, and Bituminous Materials and is the direct responsibility of
Subcommittee D08.20 on Roofing Membrane Systems. Annual Book of ASTM Standards, Vol 08.02.
Current edition approved Jan. 10, 1999. Published March 1999. Annual Book of ASTM Standards, Vol 08.03.
2 5
Annual Book of ASTM Standards, Vol 04.04. Annual Book of ASTM Standards, Vol 14.02.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D 6382
chamber is controlled through the use of inert gas such as thermal history prior to analysis. Then allow the precondi-
nitrogen or reactive gas such as air. The percent mass loss of tionedspecimentocoolto23 62°C(7464°F)inadessicator.
the specimen is determined as a function of temperature. Store the preconditioned specimen in the dessicator at 23 6
2°C (74 6 4°F) until conducting the analysis.
5. Significance and Use 7.1.2 Temperature Range—The temperature range shall be
-80 to 50°C (-112 to 122°F), with an allowed variation of
5.1 Dynamic mechanical analysis provides a measure of the
62°C (6 4°F).
rheological properties of roofing and waterproofing membrane
7.1.3 Low Temperature Stabilization—The specimen shall
materials.
remain at -80°C (-112°F) for 5 min before beginning an
5.2 Thermogravimetry is used to characterize the thermal
analysis.
stability of roofing and waterproofing membrane materials
7.1.4 Heating Rate—The heating rate shall be 2°C/min
under the specific temperature program and gaseous atmo-
(4°F/min).
sphere conditions selected for the analysis.
7.1.5 Frequency—The frequency shall be 1 Hz.
5.3 Both dynamic mechanical analysis and thermogravim-
7.1.6 Clamping Pressure—The clamping pressure shall be
etry are used to evaluate the effect of either laboratory-
in accordance with the equipment manufacturer’s instructions.
simulated or in-service exposure on roofing and waterproofing
membrane materials.
8. Test Report
5.4 Both dynamic mechanical analysis and thermogravim-
8.1 Report the generic type of
...

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