Standard Practice for Dynamic Mechanical Analysis and Thermogravimetry of Roofing and Waterproofing Membrane Material

SIGNIFICANCE AND USE
Dynamic mechanical analysis provides a measure of the rheological properties of roofing and waterproofing membrane materials.
Thermogravimetry is used to characterize the thermal stability of roofing and waterproofing membrane materials under the specific temperature program and gaseous atmosphere conditions selected for the analysis.
Both dynamic mechanical analysis and thermogravimetry are used to evaluate the effect of either laboratory-simulated or in-service exposure on roofing and waterproofing membrane materials.
Both dynamic mechanical analysis and thermogravimetry can be applied to asphalt shingles. However, their application to asphalt shingles is beyond the scope of this practice, which is limited to low-slope membrane materials at this time.
This practice can be useful in the development of performance criteria for roofing and waterproofing membrane materials.
SCOPE
1.1 This practice covers test procedures and conditions that are applicable when Test Methods D 5023, D 5024, D 5026, D 5279, and D 5418 are used for conducting dynamic mechanical analysis of roofing and waterproofing membrane material in three-point bending, compression, tension, torsion, and dual cantilever modes, respectively. The specific method is selected by the analyst and depends on the membrane material and the operating principles of the individual instrument used for the analysis.
1.2 This practice covers test procedures and conditions that are applicable when Test Method E 1131 is used for conducting thermogravimetry of roofing and waterproofing membrane material.
1.3 Membrane materials include bituminous built-up roofing, polymer-modified bitumen sheets, vulcanized rubbers, non-vulcanized polymeric sheets, and thermoplastics. The membrane materials can be either nonreinforced or reinforced.
1.4 This practice is applicable to new membrane materials received from the supplier, those exposed artificially in the laboratory or outdoors on an exposure rack, and those sampled from field installations.
1.5 This practice contains notes which are explanatory and are not part of the mandatory requirements of this practice.
1.6 The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only.
This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Publication Date
30-Apr-2005
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ASTM D6382-99(2005) - Standard Practice for Dynamic Mechanical Analysis and Thermogravimetry of Roofing and Waterproofing Membrane Material
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Please contact ASTM International (www.astm.org) for the latest information.
Designation: D6382 – 99 (Reapproved 2005)
Standard Practice for
Dynamic Mechanical Analysis and Thermogravimetry of
Roofing and Waterproofing Membrane Material
This standard is issued under the fixed designation D6382; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope 2. Referenced Documents
1.1 This practice covers test procedures and conditions that 2.1 ASTM Standards:
are applicable when Test Methods D5023, D5024, D5026, D1079 TerminologyRelatingtoRoofingandWaterproofing
D5279, and D5418 are used for conducting dynamic mechani- D4092 Terminology for Plastics: Dynamic Mechanical
calanalysisofroofingandwaterproofingmembranematerialin Properties
three-point bending, compression, tension, torsion, and dual D5023 Test Method for Plastics: Dynamic Mechanical
cantilever modes, respectively.The specific method is selected Properties: In Flexure (Three-Point Bending)
by the analyst and depends on the membrane material and the D5024 Test Method for Plastics: Dynamic Mechanical
operating principles of the individual instrument used for the Properties: In Compression
analysis. D5026 Test Method for Plastics: Dynamic Mechanical
1.2 This practice covers test procedures and conditions that Properties: In Tension
areapplicablewhenTestMethodE1131isusedforconducting D5279 Test Method for Plastics: Dynamic Mechanical
thermogravimetry of roofing and waterproofing membrane Properties: In Torsion
material. D5418 Test Method for Plastics: Dynamic Mechanical
1.3 Membrane materials include bituminous built-up roof- Properties: In Flexure (Dual Cantilever Beam)
ing, polymer-modified bitumen sheets, vulcanized rubbers, E473 Terminology Relating to Thermal Analysis and Rhe-
non-vulcanized polymeric sheets, and thermoplastics. The ology
membrane materials can be either nonreinforced or reinforced. E1131 TestMethodforCompositionalAnalysisbyThermo-
1.4 This practice is applicable to new membrane materials gravimetry
received from the supplier, those exposed artificially in the E1142 Terminology Relating to Thermophysical Properties
laboratory or outdoors on an exposure rack, and those sampled
3. Terminology
from field installations.
1.5 This practice contains notes which are explanatory and 3.1 Definitions—For definitions of terms used in this prac-
tice, refer to Terminologies E473, D1079, D4092, and E1142.
are not part of the mandatory requirements of this practice.
1.6 The values stated in SI units are to be regarded as the
4. Summary of Practice
standard. The values in parentheses are for information only.
4.1 In conducting a dynamic mechanical analysis, the roof-
1.7 This standard does not purport to address all of the
ing or waterproofing membrane specimen is placed in a test
safety concerns, if any, associated with its use. It is the
chamber and subjected to a controlled, increasing temperature
responsibility of the user of this standard to establish appro-
program. The temperature range can be from well-below (for
priate safety and health practices and determine the applica-
example, −80°C) to somewhat (for example, 50°C) above
bility of regulatory limitations prior to use.
room temperature. The glass transition temperature, storage
modulus, loss modulus, and damping factor of the specimen
are measured.
ThispracticeisunderthejurisdictionofASTMCommitteeD08onRoofingand
Waterproofing and is the direct responsibility of Subcommittee D08.20 on Roofing
Membrane Systems. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved May 1, 2005. Published May 2005. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1999. Last previous edition approved in 1999 as D6382–99. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D6382-99R05. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Please contact ASTM International (www.astm.org) for the latest information.
D6382 – 99 (2005)
4.2 In conducting a thermogravimetry analysis, the roofing 7. Test Conditions
or waterproofing membrane specimen is placed in a test
7.1 Conduct the dynamic mechanical analysis using the
chamber and subjected to a controlled, increasing temperature
following conditions and parameters:
program. The temperature range can be from about room
7.1.1 Preconditioning—Precondition the specimen in an
temperature (for example, 20 to 40°C) to well-above room
oven for1hat80 6 2°C (176 6 4°F) to provide a consistent
temperature (for example, 900°C), and the atmosphere of the
thermal history prior to analysis. Then allow the precondi-
chamber is controlled through the use of inert gas such as
tioned specimen to cool to 23 6 2°C (74 6 4 °F) in a
nitrogen or reactive gas such as air. The percent mass loss of
desiccator. Store the preconditioned specimen in the desiccator
the specimen is determined as a function of temperature.
at 23 6 2°C (74 6 4°F) until conducting the analysis.
7.1.2 Temperature Range—The temperature range shall be
5. Significance and Use
−80 to 50°C (−112 to 122°F), with an allowed variation of
5.1 Dynamicmechanicalanalysisprovidesameasureofthe
62°C (64°F).
rheological properties of roofing and waterproofing membrane
7.1.3 Low Temperature Stabilization—The specimen shall
materials.
remain at −80°C (−112°F) for 5 min before beginning an
5.2 Thermogravimetry is used to characterize the thermal
analysis.
stability of roofing and waterproofing membrane materials
7.1.4 Heating Rate—The heating rate shall be 2°C/min
under the specific temperature program and gaseous atmo-
(4°F/min).
sphere conditions selected for the analysis.
7.1.5 Frequency—The frequency shall be 1 Hz.
5.3 Both dynamic mechanical analysis and thermogravim-
7.1.6 Clamping Pressure—The clamping pressure shall be
etry are used to evaluate the effect of either laboratory-
in accordance with the equipment manufacturer’s instructions.
simulated or in-service exposure on roofing and waterproofing
membrane materials.
8. Test Report
5.4 Both dynamic m
...

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