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ASTM D5368-93(2006)

(Test Method)

Standard Test Methods for Gravimetric Determination of Total Solvent Extractable Content (TSEC) of Solid Waste Samples

Standard Test Methods for Gravimetric Determination of Total Solvent Extractable Content (TSEC) of Solid Waste Samples

SIGNIFICANCE AND USE
The TSEC provides a quantitative measure of the total solvent extractable organic content of the solid waste in question. Based upon the TSEC, the extract may be analyzed or further processed (that is, further cleanup or solvent concentration) in preparation for analysis. Thus, the TSEC provides a quantitative measure for optimizing the extractable organic concentration prior to chemical analysis.
The TSEC of soil or waste material may be used as a quantitative measure for the screening and selection of samples for chemical analysis.
The TSEC may be useful as a simple and relatively inexpensive quantitative indicator of changes occurring in the total extractable organic content of soil or waste materials.
The detection limit of the TSEC depends upon the specific procedures employed. Typical detection limits in solvent extracts (that is, without solvent pre-concentration) for Method A are more than 1000 μg/g. For Method B typical detection limits are 20 to 100 μg/g in the solvent extract. For Method C the typical detection limits are 3 to 20 μg/g for solutes in the solvent extract.
The sensitivity of the methods can be adjusted by varying the volume of solvent extract prior to gravimetric residue determination.
SCOPE
1.1 These test methods describe standard procedures for gravimetrically determining the total nonvolatile and semi-volatile organic content of solvent extracts from soils or solid wastes. The following methods are included: SectionMethod A-Micro-Determination of TSECMethod B-Evaporating Dish ProcedureMethod C-Boiling Flask Procedure
1.2 These methods are used after a solvent extract is obtained from a soil or solid waste. For these methods to be applicable, the extraction solvent must have a boiling point less than that of water at ambient pressure.
1.3 The total solvent extractable content (TSEC) of a soil, sediment, sludge, or solid waste depends upon the solvent and method used for the extraction procedure.

General Information

Status
Historical
Publication Date
31-Jan-2006
ICS
13.030.10 - Solid wastes
Technical Committee
D34 - Waste Management
Drafting Committee
D34.01.06 - Analytical Methods
Current Stage
Ref Project

Relations

Replaces
ASTM D5368-93(2001) - Standard Test Methods for Gravimetric Determination of Total Solvent Extractable Content (TSEC) of Solid Waste Samples
Effective Date
01-Feb-2006
Replaced By
ASTM D5368-13 - Standard Test Methods for Gravimetric Determination of Total Solvent Extractable Content (TSEC) of Solid Waste Samples (Withdrawn 2014)
Effective Date
01-Apr-2013
Referred By
ASTM D5681-22e1 - Standard Terminology for Waste and Waste Management
Effective Date
01-Feb-2006
Referred By
ASTM D5765-16 - Standard Practice for Solvent Extraction of Total Petroleum Hydrocarbons from Soils and Sediments Using Closed Vessel Microwave Heating
Effective Date
01-Feb-2006

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ASTM D5368-93(2006) - Standard Test Methods for Gravimetric Determination of Total Solvent Extractable Content (TSEC) of Solid Waste SamplesASTM D5368-93(2006) - Standard Test Methods for Gravimetric Determination of Total Solvent Extractable Content (TSEC) of Solid Waste Samples
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ASTM D5368-93(2006) - Standard Test Methods for Gravimetric Determination of Total Solvent Extractable Content (TSEC) of Solid Waste Samples
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D5368 − 93(Reapproved 2006)
Standard Test Methods for
Gravimetric Determination of Total Solvent Extractable
1
Content (TSEC) of Solid Waste Samples
This standard is issued under the fixed designation D5368; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D5369 Practice for Extraction of Solid Waste Samples for
Chemical Analysis Using Soxhlet Extraction
1.1 These test methods describe standard procedures for
gravimetrically determining the total nonvolatile and semi-
3. Terminology
volatile organic content of solvent extracts from soils or solid
3.1 Definitions:
wastes. The following methods are included:
3.1.1 total solvent extractable content (TSEC)— the total
Section
concentration by weight (w/w) of organic materials that is
Method A—Micro-Determination of TSEC 11-13
Method B—Evaporating Dish Procedure 14-16
extractable from a soil or solid waste by the selected solvent.
Method C—Boiling Flask Procedure 17-19
1.2 These methods are used after a solvent extract is
4. Summary of Methods
obtained from a soil or solid waste. For these methods to be
4.1 The sample is extracted with an organic solvent using a
applicable,theextractionsolventmusthaveaboilingpointless
procedure such as described in Practices D5369 (Soxhlet
than that of water at ambient pressure.
Extraction) or Test Method D4281. The quantity of material
1.3 The total solvent extractable content (TSEC) of a soil,
extracted into the solvent is determined as the residue weight
sediment, sludge, or solid waste depends upon the solvent and
after solvent evaporation. Similar ASTM methods are Test
method used for the extraction procedure.
Methods D2109 and D3445, and Practice D2910.
4.1.1 MethodA,Micro-DeterminationMethod—Theresidue
2. Referenced Documents
weight after solvent evaporation is determined for 200 µL of
2
solvent extract evaporated on an aluminum weighing dish. A
2.1 ASTM Standards:
heat lamp is used to effect evaporation.
D2109 Test Methods for Nonvolatile Matter in Halogenated
4.1.2 Method B, Evaporating Dish Procedure—The residue
Organic Solvents and Their Admixtures
weight after solvent evaporation is determined for 1.0 to 75.0
D2910 Method for Removal of Organic Matter from Water
3
mL of solvent extract. Solvent is evaporated in an evaporating
by Activated Carbon Absorption (Withdrawn 1991)
dish by heating at 5°C below the solvent boiling point. A
D3086 Test Method for Organochlorine Pesticides in Water
3
stream of nitrogen over the surface of the solvent is used to
(Withdrawn 1996)
accelerate evaporation.
D3445 Method of Test for Nonvolatile Matter in Trichloro-
3
4.1.3 Method C, Boiling Flask Method—The residue weight
trifluoroethane (Withdrawn 1991)
after solvent evaporation is determined for 100 to 300 mL of
D3694 Practices for Preparation of Sample Containers and
solvent evaporated in a boiling flask. Solvent is evaporated in
for Preservation of Organic Constituents
a water bath at the solvent boiling point.
D4281 Test Method for Oil and Grease (Fluorocarbon Ex-
tractable Substances) by Gravimetric Determination
5. Significance and Use
5.1 The TSEC provides a quantitative measure of the total
1
These test methods are under the jurisdiction of ASTM Committee D34 on
solvent extractable organic content of the solid waste in
Waste Management and are the direct responsibility of Subcommittee D34.01.06 on
question.BasedupontheTSEC,theextractmaybeanalyzedor
Analytical Methods.
further processed (that is, further cleanup or solvent concen-
Current edition approved Feb. 1, 2006. Published March 2006. Originally
approved in 1993. Last previous edition approved in 2001 as D5368 - 93(2001)
tration) in preparation for analysis. Thus, the TSEC provides a
DOI: 10.1520/D5368-93R06.
quantitative measure for optimizing the extractable organic
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
concentration prior to chemical analysis.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
5.2 The TSEC of soil or waste material may be used as a
the ASTM website.
3
quantitativemeasureforthescreeningandselectionofsamples
The last approved version of this historical standard is referenced on
www.astm.org. for chemical analysis.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5368 − 93 (2006)
5.3 The TSEC may be useful as a simple and relatively interest) in the solvent will preclud
...

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5 – 6  
B – Evaluation of Reactivity and Leachate Quality
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7 – 8  
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1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
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