ASTM D2076-92(1998)

Standard Test Methods for Acid Value and Amine Value of Fatty Quaternary Ammonium Chlorides (Withdrawn 2007)

SCOPE
1.1 These test methods cover the determination of acid value and amine value in fatty quaternary ammonium chlorides.  
1.2 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
WITHDRAWN RATIONALE
These test methods cover the determination of acid value and amine value in fatty quaternary ammonium chlorides.
Formerly under the jurisdiction of Committee D01 on Paint and Related Coatings, Materials, and Applications, this test method was withdrawn in March 2007 in accordance with section 10.5.3.1 of the Regulations Governing ASTM Technical Committees, which requires that standards shall be updated by the end of the eighth year since the last approval date.

General Information

• Status: Withdrawn
• Publication Date: 31-Dec-1991
• Withdrawal Date: 19-Mar-2007
• ICS: 71.100.40 - Surface active agents
• Technical Committee: D01 - Paint and Related Coatings, Materials, and Applications

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D2076–92(Reapproved1998)
Standard Test Methods for
Acid Value and Amine Value of Fatty Quaternary Ammonium
Chlorides
This standard is issued under the fixed designation D 2076; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
These test methods were prepared jointly by ASTM and the American Oil Chemists’ Society.
1. Scope tee onAnalytical Reagents of theAmerican Chemical Society,
where such specifications are available. Other grades may be
1.1 These test methods cover the determination of acid
used, provided it is first ascertained that the reagent is of
value and amine value in fatty quaternary ammonium chlo-
sufficiently high purity to permit its use without lessening the
rides.
accuracy of the determination.
1.2 This standard does not purport to address all of the
5.2 Purity of Water—Unless otherwise indicated, references
safety concerns, if any, associated with its use. It is the
to water shall be understood to mean reagent water conforming
responsibility of the user of this standard to establish appro-
to Type II of Specification D 1193.
priate safety and health practices and determine the applica-
5.3 Bromphenol Blue Indicator Solution—Dissolve 0.2 g of
bility of regulatory limitations prior to use.
bromphenol blue in 100 mL of methanol, ethanol, or isopro-
2. Referenced Documents
panol.
5.4 Hydrochloric Acid, Standard Solution (0.1 N)—Add 17
2.1 ASTM Standards:
mLofconcentratedhydrochloricacid(HCl,spgr1.19)to1000
D 1193 Specification for Reagent Water
mL of isopropyl alcohol in a 2-L volumetric flask. Make up to
3. Terminology
volume after cooling to room temperature. Standardize with
sodium carbonate using 0.1 % bromcresol green as the indica-
3.1 Definitions:
tor.
3.1.1 acid value—the number of milligrams of potassium
5.5 Hydrochloric Acid, Standard Solution (0.2 N)—Add 34
hydroxide needed to neutralize1gof sample, and is usually
mL of concentrated HCl (sp gr 1.19) to 1000 mL of isopropyl
due to amine hydrochloride.
alcohol in a 2-L volumetric flask. Make up to volume after
3.1.2 amine value—the number of milligrams of potassium
cooling to room temperature. Standardize with sodium carbon-
hydroxide equivalent to the fatty amine basicity in1gof
ate using 0.1 % bromcresol green as the indicator.
sample.
5.6 Isopropyl Alcohol (99 %)—Neutralize to the phenol-
4. Apparatus
phthalein end point with 0.1 N methanolic sodium hydroxide
(NaOH) just before running the acid value test.
4.1 Erlenmeyer Flasks, wide-mouth, alkali-resistant, boro-
5.7 Phenolphthalein Indicator Solution (10 g/L)—Dissolve
silicate glass, 250-mL capacity.
1 g of phenolphthalein in 100 mL of methanol, ethanol, or
4.2 Micro Buret, 10-mL capacity graduated to 0.02 mL.
isopropanol.
5. Reagents
5.8 Sodium Hydroxide, Standard Solution (0.1 N)—
Dissolve 4.0 g of sodium hydroxide (NaOH) in 1000 mL of
5.1 Purity of Reagents—Reagent grade chemicals shall be
cold methyl alcohol. Allow to stand overnight in a cold room.
used in all tests. Unless otherwise indicated, it is intended that
Siphon the supernatant liquid into a clean bottle.After coming
all reagents shall conform to the specifications of the Commit-
1 3
ThesetestmethodsareunderthejurisdictionofASTMCommitteeD-1onPaint Reagent Chemicals, American Chemical Society Specifications, American
and Related Coatings, Materials, and Applications and are the direct responsibility Chemical Society, Washington, DC. For suggestions on the testing of reagents not
of Subcommittee D01.32 on Drying Oils. listed by the American Chemical Society, see Analar Standards for Laboratory
Current edition approved March 15, 1992. Published May 1992. Originally Chemicals, BDH Ltd., Poole, Dorset, U.K., and the United States Pharmacopeia
e1
published as D 2076 – 62 T. Last previous edition D 2076 – 64 (1987) . and National Formulary, U.S. Pharmacopeial Convention, Inc. (USPC), Rockville,
Annual Book of ASTM Standards, Vol 11.01. MD.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D2076–92 (1998)
to room temperature, standardize the material with acid potas- 9.2 If free caustic material is present, calculate the percent
sium phthalate using 1 % phenolphthalein as the indicator. of free sodium hydroxide and the amine value as follows:
Free sodium hydroxide, % 5 ~A 3 N 3 4!/S (2)
6. Procedu
...