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ASTM D5273-23

(Guide)

Standard Guide for Analysis of Propylene Concentrates

Standard Guide for Analysis of Propylene Concentrates

SIGNIFICANCE AND USE
4.1 This guide is intended to provide information on the likely composition of propylene concentrates and on probable ways to test them. Since there are currently no ASTM test methods for determining all components of interest, this guide provides information on other potentially available test methods.  
4.2 Although this guide is not to be used for specifications, it can provide a starting point for parties to develop mutually agreed upon specifications which meet their respective requirements. It can also be used as a starting point in finding suitable test methods for determining various components of propylene.
SCOPE
1.1 This guide covers a list of the major grades of propylene concentrates produced in North America. It includes possible components and test methods, both ASTM and other, either actually used, or believed to be in use, to test for these properties. This guide is not intended to be used or construed as a set of specifications for any grade of propylene concentrate.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
30-Nov-2023
ICS
71.080.10 - Aliphatic hydrocarbons
Technical Committee
D02 - Petroleum Products, Liquid Fuels, and Lubricants
Drafting Committee
D02.D0.03 - Propylene
Current Stage
Ref Project

Relations

Replaces
ASTM D5273-18 - Standard Guide for Analysis of Propylene Concentrates
Effective Date
01-Dec-2023
Refers
ASTM D3227-23 - Standard Test Method for (Thiol Mercaptan) Sulfur in Gasoline, Kerosine, Aviation Turbine, and Distillate Fuels (Potentiometric Method)
Effective Date
01-May-2023

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Standards Content (Sample)

This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D5273 − 23
Standard Guide for
1
Analysis of Propylene Concentrates
This standard is issued under the fixed designation D5273; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* D2504 Test Method for Noncondensable Gases in C and
2
Lighter Hydrocarbon Products by Gas Chromatography
1.1 This guide covers a list of the major grades of propylene
3
(Withdrawn 2024)
concentrates produced in North America. It includes possible
D2505 Test Method for Ethylene, Other Hydrocarbons, and
components and test methods, both ASTM and other, either
Carbon Dioxide in High-Purity Ethylene by Gas Chroma-
actually used, or believed to be in use, to test for these
tography
properties. This guide is not intended to be used or construed
D2712 Test Method for Determination of Hydrocarbon Im-
as a set of specifications for any grade of propylene concen-
purities in High Purity Propylene by Gas Chromatography
trate.
D3227 Test Method for (Thiol Mercaptan) Sulfur in
1.2 The values stated in SI units are to be regarded as
Gasoline, Kerosine, Aviation Turbine, and Distillate Fuels
standard. No other units of measurement are included in this
(Potentiometric Method)
standard.
D3246 Test Method for Sulfur in Petroleum Gas by Oxida-
3
1.3 This standard does not purport to address all of the
tive Microcoulometry (Withdrawn 2024)
safety concerns, if any, associated with its use. It is the D3700 Practice for Obtaining LPG Samples Using a Float-
responsibility of the user of this standard to establish appro-
ing Piston Cylinder
priate safety, health, and environmental practices and deter- D4178 Practice for Calibrating Moisture Analyzers
mine the applicability of regulatory limitations prior to use.
D4468 Test Method for Total Sulfur in Gaseous Fuels by
1.4 This international standard was developed in accor- Hydrogenolysis and Rateometric Colorimetry
dance with internationally recognized principles on standard-
D4629 Test Method for Trace Nitrogen in Liquid Hydrocar-
ization established in the Decision on Principles for the bons by Syringe/Inlet Oxidative Combustion and Chemi-
Development of International Standards, Guides and Recom- luminescence Detection
mendations issued by the World Trade Organization Technical
D4864 Test Method for Determination of Traces of Metha-
Barriers to Trade (TBT) Committee. nol in Propylene Concentrates by Gas Chromatography
3
(Withdrawn 2016)
2. Referenced Documents
D5454 Test Method for Water Vapor Content of Gaseous
2
Fuels Using Electronic Moisture Analyzers
2.1 ASTM Standards:
D5623 Test Method for Sulfur Compounds in Light Petro-
D2163 Test Method for Determination of Hydrocarbons in
leum Liquids by Gas Chromatography and Sulfur Selec-
Liquefied Petroleum (LP) Gases and Propane/Propene
tive Detection
Mixtures by Gas Chromatography
D6667 Test Method for Determination of Total Volatile
D2384 Test Methods for Traces of Volatile Chlorides in
Sulfur in Gaseous Hydrocarbons and Liquefied Petroleum
Butane-Butene Mixtures
Gases by Ultraviolet Fluorescence
D6729 Test Method for Determination of Individual Com-
1
ponents in Spark Ignition Engine Fuels by 100 Metre
This guide is under the jurisdiction of ASTM Committee D02 on Petroleum
Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcom-
Capillary High Resolution Gas Chromatography
mittee D02.D0.03 on Propylene.
D7423 Test Method for Determination of Oxygenates in C2,
Current edition approved Dec. 1, 2023. Published January 2024. Originally
C3, C4, and C5 Hydrocarbon Matrices by Gas Chroma-
approved in 1992. Last previous edition approved in 2018 as D5273 – 18. DOI:
10.1520/D5273-23. tography and Flame Ionization Detection
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on The last approved version of this historical standard is referenced on
the ASTM website. www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5273 − 23
D7994 Test Method for Total Fluorine, Chlorine, and Sulfur ments. It can also be used as a starting point in finding suitable
in Liquid Petroleum Gas (LPG) by Oxidativ
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D5273 − 18 D5273 − 23
Standard Guide for
1
Analysis of Propylene Concentrates
This standard is issued under the fixed designation D5273; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope*
1.1 This guide covers a list of the major grades of propylene concentrates produced in North America. It includes possible
components and test methods, both ASTM and other, either actually used, or believed to be in use, to test for these properties. This
guide is not intended to be used or construed as a set of specifications for any grade of propylene concentrate.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of
regulatory limitations prior to use.
1.4 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D2163 Test Method for Determination of Hydrocarbons in Liquefied Petroleum (LP) Gases and Propane/Propene Mixtures by
Gas Chromatography
D2384 Test Methods for Traces of Volatile Chlorides in Butane-Butene Mixtures
D2504 Test Method for Noncondensable Gases in C and Lighter Hydrocarbon Products by Gas Chromatography (Withdrawn
2
3
2024)
D2505 Test Method for Ethylene, Other Hydrocarbons, and Carbon Dioxide in High-Purity Ethylene by Gas Chromatography
D2712 Test Method for Determination of Hydrocarbon Impurities in High Purity Propylene by Gas Chromatography
D3227 Test Method for (Thiol Mercaptan) Sulfur in Gasoline, Kerosine, Aviation Turbine, and Distillate Fuels (Potentiometric
Method)
3
D3246 Test Method for Sulfur in Petroleum Gas by Oxidative Microcoulometry (Withdrawn 2024)
D3700 Practice for Obtaining LPG Samples Using a Floating Piston Cylinder
D4178 Practice for Calibrating Moisture Analyzers
D4468 Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and Rateometric Colorimetry
D4629 Test Method for Trace Nitrogen in Liquid Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence
Detection
1
This guide is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.D0.03 on Propylene.
Current edition approved July 1, 2018Dec. 1, 2023. Published August 2018January 2024. Originally approved in 1992. Last previous edition approved in 20122018 as
D5273 – 92 (2012).D5273 – 18. DOI: 10.1520/D5273-18.10.1520/D5273-23.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
The last approved version of this historical standard is referenced on www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D5273 − 23
D4864 Test Method for Determination of Traces of Methanol in Propylene Concentrates by Gas Chromatography (Withdrawn
3
2016)
D5454 Test Method for Water Vapor Content of Gaseous Fuels Using Electronic Moisture Analyzers
D5623 Test Method for Sulfur Compounds in Light Petroleum Liquids by Gas Chromatography and Sulfur Selective Detection
D6667 Test Method for Determination of Total Volatile Sulfur in Gaseous Hydrocarbons and Liquefied Petroleum Gases by
Ultraviolet Fluorescence
D6729 Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 100 Metre Capillary High
Resolution Gas Chromatography
D7423 Test Method for Determination of Oxygenates in C2, C3, C4, and C5 Hydrocarbon Matrices by Gas Chromatography
and Flame Ionization Detection
D7994 T
...

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ASTM D7061-23(Test Method)
Standard Test Method for Measuring n-Heptane Induced Phase Separation of Asphaltene-Containing Heavy Fuel Oils as Separability Number by an Optical Scanning Device

SIGNIFICANCE AND USE
5.1 This procedure describes a rapid and sensitive method for estimating the stability reserve of an oil. The stability reserve is estimated in terms of a separability number, where a low value of the separability number indicates that there is a stability reserve within the oil. When the separability number is between 0 to 5, the oil can be considered to have a high stability reserve and asphaltenes are not likely to flocculate. If the separability number is between 5 to 10, the stability reserve in the oil will be much lower. However, asphaltenes are, in this case, not likely to flocculate as long as the oil is not exposed to any worse conditions, such as storing, aging, and heating. If the separability number is above 10, the stability reserve of the oil is very low and asphaltenes will easily flocculate, or have already started to flocculate.  
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FIG. 1 Schematic Representation of a Typical Measurement Using an Optical Scanning Device  
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SCOPE
1.1 This test method covers the quantitative measurement, either in the laboratory or in the field, of how easily asphaltene-containing heavy fuel oils diluted in toluene phase separate upon addition of heptane. This is measured as a separability number (%) by the use of an optical scanning device.  
1.2 The test method is limited to asphaltene-containing heavy fuel oils. ASTM specification fuels that generally fall within the scope of this test method are Specification D396, Grade Nos. 4, 5, and 6, Specification D975, Grade No. 4-D, and Specification D2880, Grade Nos. 3-GT and 4-GT. Refinery fractions from which such blended fuels are made also fall within the scope of this test method.  
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SCOPE
1.1 This test method covers the determination of butadiene dimer (4-vinylcyclohexene-1) and styrene in butadiene concentrates, both recycle and specification grade.  
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SIGNIFICANCE AND USE
5.1 High-purity propylene is required as a feedstock for various manufacturing processes, and the presence of trace amounts of certain hydrocarbon impurities may have adverse effects on yield or catalyst life. This test method is suitable for use as a benchmark in setting commercial specifications, for use as an internal quality control tool, and for use in development or research work.
SCOPE
1.1 This test method is used for the determination of hydrocarbon impurities in propylene (propene) material of 97 % by mass or greater purity (concentrates). These impurities are determined in the concentration range of 0.35 mg/kg to 8575 mg/kg and includes the following components: methane, ethane, ethylene, propane, acetylene, isobutane, propadiene, normal butane, trans-2-butene, butene-1, isobutylene, cis-2-butene, isopentane, methylacetylene, normal pentane, and 1,3-butadiene.
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1.1 This test method covers the determination of peroxides in butadiene.  
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1.1 This test method covers the determination of butadiene-1,3 purity and impurities such as propane, propylene, isobutane, n-butane, butene-1, isobutylene, propadiene, trans-butene-2, cis-butene-2, butadiene-1,2, pentadiene-1,4, and, methyl, dimethyl, ethyl, and vinyl acetylene in polymerization grade butadiene by gas chromatography. Impurities including butadiene dimer, carbonyls, inhibitor, and residue are measured by appropriate ASTM procedures and the results used to normalize the component distribution obtained by chromatography.  
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SCOPE
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1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 9.  
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ASTM D7827-19(Test Method)
Standard Test Method for Measuring n-Heptane Induced Phase Separation of Asphaltene from Heavy Fuel Oils as Separability Number by an Optical Device

SIGNIFICANCE AND USE
5.1 This procedure describes a rapid and sensitive method for estimating the stability reserve of an oil. The stability reserve is estimated in terms of a separability number, where a low value of the separability number indicates that there is a stability reserve within the oil. When the separability number is between 0 to 5, the oil can be considered to have a high stability reserve and asphaltenes are not likely to flocculate. If the separability number is between 5 to 10, the stability reserve in the oil will be much lower. However, asphaltenes are, in this case, not likely to flocculate as long as the oil is not exposed to any worse conditions, such as storing, aging, and heating. If the separability number is above 10, the stability reserve of the oil is very low and asphaltenes will easily flocculate, or have already started to flocculate.  
5.2 This test method can be used by refiners and users of heavy oils, for which this test method is applicable, to estimate the stability reserves of their oils. Hence, this test method can be used by refineries to control and optimize their refinery processes. Consumers of oils can use this test method to estimate the stability reserve of their oils before, during, and after storage.  
5.3 This test method is not intended for predicting whether oils are compatible before mixing, but can be used for determining the separability number of already blended oils. However, experience shows that oils exhibiting a low separability number are more likely to be compatible with other oils than are oils with high separability numbers.
SCOPE
1.1 This test method covers the quantitative measurement, either in the laboratory or in the field, of how easily asphaltene-containing heavy fuel oils diluted in toluene phase separate upon addition of heptane. The result is a separability number (%). See also Test Method D7061.  
1.2 The test method is limited to asphaltene-containing heavy fuel oils. ASTM specification fuels that generally fall within the scope of this test method are Specification D396, Grade Nos. 4, 5, and 6, Specification D975, Grade No. 4-D, and Specification D2880, Grade Nos. 3-GT and 4-GT. Refinery fractions from which such blended fuels are made also fall within the scope of this test method.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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ASTM
ASTM D5274-00(2019)(Guide)
Standard Guide for Analysis of 1,3–Butadiene Product

SIGNIFICANCE AND USE
4.1 This guide is intended to provide information on the possible composition of 1,3-butadiene products and possible ways to test them. Since there are currently not enough ASTM standards for determining all components of interest, this guide provides information on other potentially available test methods.  
4.2 Although this guide is not to be used for specifications, it can provide a starting point for parties to develop mutually agreed-upon specifications that meet their respective requirements. It can also be used as a starting point in finding suitable test methods for 1,3-butadiene components.
SCOPE
1.1 This guide covers the analysis of 1,3–butadiene products produced in North America. It includes possible components and test methods, both ASTM and other, either actually used or believed to be in use, to test for these components. This guide is not intended to be used or construed as a set of specifications for butadiene products.  
1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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