Standard Test Method for Sediment in Crude Oil by Membrane Filtration

SIGNIFICANCE AND USE
4.1 A knowledge of the sediment content of crude oil is important both in refinery operations and in crude oil commerce.
SCOPE
1.1 This test method covers the determination of sediment in crude oils by membrane filtration. This test method has been validated for crude oils with sediments up to approximately 0.15 mass %.  
1.2 The accepted unit of measure for this test method is mass %, but an equation to convert to volume % is provided (see Note 6).  
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.  
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific warning statements, see 6.1 and Annex A1.

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Publication Date
31-Mar-2015
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D4807 − 05 (Reapproved 2015)
Manual of Petroleum Measurement Standards (MPMS), Chapter 10.8
Standard Test Method for
1
Sediment in Crude Oil by Membrane Filtration
This standard is issued under the fixed designation D4807; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope of Petroleum and Petroleum Products
3
2.2 API Standards:
1.1 This test method covers the determination of sediment
MPMS Chapter 8.1Manual Sampling of Petroleum and
incrudeoilsbymembranefiltration.Thistestmethodhasbeen
Petroleum Products (ASTM Practice D4057)
validated for crude oils with sediments up to approximately
MPMS Chapter 8.2Automatic Sampling of Petroleum and
0.15 mass%.
Petroleum Products (ASTM Practice D4177)
1.2 The accepted unit of measure for this test method is
MPMSChapter8.3MixingandHandlingofLiquidSamples
mass%, but an equation to convert to volume% is provided
of Petroleum and Petroleum Products (ASTM Practice
(see Note 6).
D5854)
MPMS Chapter 10.1Test Method for Sediment in Crude
1.3 The values stated in SI units are to be regarded as the
standard. The values given in parentheses are for information Oils and Fuel Oils by the Extraction Method (ASTMTest
Method D473)
only.
4
2.3 ISO Standard:
1.4 This standard does not purport to address all of the
ISO 5272:1979Toluene for Industrial Use—Specifications
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
3. Summary of Test Method
priate safety and health practices and determine the applica-
3.1 A portion of a representative crude oil sample is
bility of regulatory limitations prior to use. For specific
dissolved in hot toluene and filtered under vacuum through a
warning statements, see 6.1 and Annex A1.
0.45µm porosity membrane filter. The filter with residue is
washed, dried, and weighed to give the final result.
2. Referenced Documents
2
2.1 ASTM Standards:
4. Significance and Use
D473TestMethodforSedimentinCrudeOilsandFuelOils
4.1 A knowledge of the sediment content of crude oil is
by the Extraction Method
important both in refinery operations and in crude oil com-
D4057Practice for Manual Sampling of Petroleum and
merce.
Petroleum Products
D4177Practice for Automatic Sampling of Petroleum and
5. Apparatus
Petroleum Products
5.1 Funnel and Filter Support Assembly—Use an assembly
D4865Guide for Generation and Dissipation of Static Elec-
designed to hold 47mm diameter filters as was used in the
tricity in Petroleum Fuel Systems
5
development of this test method (see Fig. 1).
D5854Practice for Mixing and Handling of Liquid Samples
5.1.1 Filter Funnel—Use a filter funnel with a 250mL
minimum capacity. The lower part of the funnel has a 40mm
1
This test method is under the jurisdiction of ASTM Committee D02 on inside diameter and is designed to secure the 47mm diameter
Petroleum Products, Liquid Fuels, and Lubricants and the API Committee on
Petroleum Measurement, and is the direct responsibility of Subcommittee D02.02
3
/COMQ on Hydrocarbon Measurement for Custody Transfer (Joint ASTM-API). Published as Manual of Petroleum Measurement Standards. Available from
Current edition approved April 1, 2015. Published May 2015. Originally AmericanPetroleumInstitute(API),1220L.St.,NW,Washington,DC20005-4070,
approved in 1988. Last previous edition approved in 2010 as D4807 – 05 (2010). http://www.api.org.
4
DOI: 10.1520/D4807-05R15. Available fromAmerican National Standards Institute (ANSI), 25 W. 43rd St.,
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or 4th Floor, New York, NY 10036, http://www.ansi.org.
5
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM The following filtration assembly was used in generating the precision:
Standards volume information, refer to the standard’s Document Summary page on Millipore Corp., Ashly Rd., Bedford, MA 01730. Other filtration assemblies also
the ASTM website. may be acceptable.
© Jointly copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, USA and the American Petroleum Institute (API), 1220 L Street NW, Washington DC 20005, USA
1

---------------------- Page: 1 ----------------------
D4807 − 05 (2015)
5.7 Mixer—Use a nonaerating, high-speed mixer meeting
the verification efficiency requirements specified in Practice
D5854 (API MPMS Chapter 8.3). Either insertion mixers or
circulating mixers are acceptable provided they meet the
criteria in Practice D5854 (API MPMS Chapter
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D4807 − 05 (Reapproved 2010) D4807 − 05 (Reapproved 2015)
Manual of Petroleum Measurement Standards (MPMS), Chapter 10.8
Standard Test Method for
1
Sediment in Crude Oil by Membrane Filtration
This standard is issued under the fixed designation D4807; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope
1.1 This test method covers the determination of sediment in crude oils by membrane filtration. This test method has been
validated for crude oils with sediments up to approximately 0.15 mass %.
1.2 The accepted unit of measure for this test method is mass %, but an equation to convert to volume % is provided (see Note
6).
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use. For specific warning statements, see 6.1 and Annex A1.
2. Referenced Documents
2
2.1 ASTM Standards:
D473 Test Method for Sediment in Crude Oils and Fuel Oils by the Extraction Method
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D4865 Guide for Generation and Dissipation of Static Electricity in Petroleum Fuel Systems
D5854 Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products
3
2.2 API Standards:
MPMS Chapter 8.1 Manual Sampling of Petroleum and Petroleum Products (ASTM Practice D4057)
MPMS Chapter 8.2 Automatic Sampling of Petroleum and Petroleum Products (ASTM Practice D4177)
MPMS Chapter 8.3 Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products (ASTM Practice D5854)
MPMS Chapter 10.1 Test Method for Sediment in Crude Oils and Fuel Oils by the Extraction Method (ASTM Test Method
D473)
4
2.3 ISO Standard:
ISO 5272:1979 Toluene for Industrial Use—Specifications
3. Summary of Test Method
3.1 A portion of a representative crude oil sample is dissolved in hot toluene and filtered under vacuum through a
0.45-μm0.45 μm porosity membrane filter. The filter with residue is washed, dried, and weighed to give the final result.
4. Significance and Use
4.1 A knowledge of the sediment content of crude oil is important both in refinery operations and in crude oil commerce.
1
This test method is under the jurisdiction of ASTM Committee D02 on Petroleum Products Products, Liquid Fuels, and Lubricants and the API Committee on Petroleum
Measurement, and is the direct responsibility of Subcommittee D02.02 /COMQ on Hydrocarbon Measurement for Custody Transfer (Joint ASTM-API).
Current edition approved May 1, 2010April 1, 2015. Published May 2010May 2015. Originally approved in 1988. Last previous edition approved in 20052010 as D4807
ε1
– 05 . (2010). DOI: 10.1520/D4807-05R10.10.1520/D4807-05R15.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
Published as Manual of Petroleum Measurement Standards. Available from American Petroleum Institute (API), 1220 L. St., NW, Washington, DC 20005-4070,
http://www.api.org.
4
Available from American National Standards Institute (ANSI), 25 W. 43rd St., 4th Floor, New York, NY 10036, http://www.ansi.org.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
D4807 − 05 (2015)
FIG. 1 Membrane Filtration Assembly
5. Apparatus
5.1 Funnel and Filter Support Assembly—Use an assembly designed to hold 47-mm47 mm diameter filters as was used in the
5
development of this test method (see Fig. 1).
5.1.1 Filter Funnel—Use a filter funnel with a 250 mL 250 mL minimum capacity. The lower part of the funnel has a
40-mm40 mm inside diameter and is designed to secure the 47-mm47 mm diameter filter against the filter support. The funnel can
be ja
...

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