ASTM D3352-08a
(Test Method)Standard Test Method for Strontium Ion in Brackish Water, Seawater, and Brines
Standard Test Method for Strontium Ion in Brackish Water, Seawater, and Brines
SIGNIFICANCE AND USE
This test method can be used to determine strontium ions in brackish water, seawater, and brines.
SCOPE
1.1 This test method covers the determination of soluble strontium ion in brackish water, seawater, and brines by atomic absorption spectrophotometry.
1.2 Samples containing from 5 to 2100 mg/L of strontium may be analyzed by this test method.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
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Designation:D3352 −08a
StandardTest Method for
1
Strontium Ion in Brackish Water, Seawater, and Brines
This standard is issued under the fixed designation D3352; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope wavelength they emit when excited. When radiation from a
given excited element is passed through a flame containing
1.1 This test method covers the determination of soluble
ground state atoms of that element, the intensity of the
strontium ion in brackish water, seawater, and brines by atomic
transmitted radiation will decrease in proportion to the amount
absorption spectrophotometry.
of the ground state element in the flame. A hollow cathode
1.2 Samples containing from 5 to 2100 mg/L of strontium
lamp whose cathode is made of the element to be determined
may be analyzed by this test method. 3
provides the radiation. The metal atoms to be measured are
placed in the beam of radiation by aspirating the specimen into
1.3 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this an oxidant-fuel flame. A monochromator isolates the charac-
teristic radiation from the hollow cathode lamp and a photo-
standard.
sensitive device measures the attenuated transmitted radiation.
1.4 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the 4.2 Sincethevariableandsometimeshighconcentrationsof
responsibility of the user of this standard to establish appro-
matrix materials in the waters and brines affect absorption
priate safety and health practices and determine the applica- differently,itisdifficulttopreparestandardssufficientlysimilar
bility of regulatory limitations prior to use.
to the waters and brines. To overcome this difficulty, the
method of additions is used in which three identical samples
2. Referenced Documents
are prepared and varying amounts of a standard added to two
2
of them. The three samples are then aspirated, the concentra-
2.1 ASTM Standards:
D1129 Terminology Relating to Water tion readings recorded, and the original sample concentration
calculated.
D1193 Specification for Reagent Water
D2777 Practice for Determination of Precision and Bias of
5. Significance and Use
Applicable Test Methods of Committee D19 on Water
4
5.1 This test method can be used to determine strontium
D3370 Practices for Sampling Water from Closed Conduits
ions in brackish water, seawater, and brines.
D5810 Guide for Spiking into Aqueous Samples
D5847 Practice for Writing Quality Control Specifications
6. Interferences
for Standard Test Methods for Water Analysis
6.1 The chemical suppression caused by silicon, aluminum,
3. Terminology
and phosphate is controlled by adding lanthanum. The lantha-
num also controls ionization interference.
3.1 Definitions—For definitions of terms used in this test
method, refer to Terminology D1129.
7. Apparatus
4. Summary of Test Method 7.1 AtomicAbsorptionSpectrophotometer—Theinstrument
shall consist of atomizer and burner, suitable pressure-
4.1 This test method is dependent on the fact that metallic
regulating devices capable of maintaining constant oxidant and
elements, in the ground state, will absorb light of the same
3
For additional information on atomic absorption, see the following references:
1
This test method is under the jurisdiction of ASTM Committee D19 on Water Angino, E. E., and Billings, G. K., Atomic Absorption Spectrophotometry in
and is the direct responsibility of Subcommittee D19.05 on Inorganic Constituents Geology, Elsevier Publishing Co., NewYork, N.Y., 1967. Dean, J.A., and Rains, T.
in Water. C., Editors, Flame Emission and Atomic Absorption Spectrometry Vol 1−Theory,
Current edition approved Nov. 15, 2008. Published November 2008. Originally Marcel Dekker, New York, NY, 1969.
4
approved in 1974. Last previous edition approved in 2008 as D3352 – 08. DOI: Additional information is contained in the following references: Fletcher, G. F.,
10.1520/D3352-08A. and Collins, A. G., “Atomic Absorption Methods of Analysis of Oilfield Brines:
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or Barium,Calcium,Copper,Iron,Lead,Lithium,Magnesium,Manganese,Potassium,
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Sodium, Strontium, and Zinc,” U.S. Bureau of Mines, Report of Investigations
Standards volume information, refer to the standard’s Document Summary page on 7861, 1974, 14 pp. Collins, A. G., Geochemistry of Oilfield Waters, Elsevier
the ASTM website. Publishing Co., Amsterdam. The Netherlands, 1975.
Co
...
This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D 3352–08 Designation: D 3352 – 08a
Standard Test Method for
1
Strontium Ion in Brackish Water, Seawater, and Brines
This standard is issued under the fixed designation D 3352; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This test method covers the determination of soluble strontium ion in brackish water, seawater, and brines by atomic
absorption spectrophotometry.
1.2 Samples containing from 5 to 2100 mg/L of strontium may be analyzed by this test method.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
D 1129 Terminology Relating to Water
D1193Specification for Reagent Water
D 1193 Specification for Reagent Water
D 2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D 3370 Practices for Sampling Water from Closed Conduits
D 5810 Guide for Spiking into Aqueous Samples
D 5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
3. Terminology
3.1 Definitions—For definitions of terms used in this test method, refer to Terminology D 1129.
4. Summary of Test Method
4.1 Thistestmethodisdependentonthefactthatmetallicelements,inthegroundstate,willabsorblightofthesamewavelength
they emit when excited. When radiation from a given excited element is passed through a flame containing ground state atoms of
that element, the intensity of the transmitted radiation will decrease in proportion to the amount of the ground state element in the
3
flame. A hollow cathode lamp whose cathode is made of the element to be determined provides the radiation. The metal atoms
tobemeasuredareplacedinthebeamofradiationbyaspiratingthespecimenintoanoxidant-fuelflame.Amonochromatorisolates
the characteristic radiation from the hollow cathode lamp and a photosensitive device measures the attenuated transmitted
radiation.
4.2 Since the variable and sometimes high concentrations of matrix materials in the waters and brines affect absorption
differently, it is difficult to prepare standards sufficiently similar to the waters and brines. To overcome this difficulty, the method
of additions is used in which three identical samples are prepared and varying amounts of a standard added to two of them. The
three samples are then aspirated, the concentration readings recorded, and the original sample concentration calculated.
1
ThistestmethodisunderthejurisdictionofASTMCommitteeD19onWaterandisthedirectresponsibilityofSubcommitteeD19.05onInorganicConstituentsinWater.
Current edition approved Aug.Nov. 15, 2008. Published SeptemberNovember 2008. Originally approved in 1974. Last previous edition approved in 20032008 as
´1
D3352–03 . D 3352 – 08.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. ForAnnualBookofASTMStandards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
For additional information on atomic absorption, see the following references: Angino, E. E., and Billings, G. K., Atomic Absorption Spectrophotometry in Geology,
Elsevier Publishing Co., NewYork, N.Y., 1967. Dean, J.A., and Rains, T. C., Editors, Flame Emission andAtomicAbsorption Spectrometry Vol 1−Theory, Marcel Dekker,
New York, NY, 1969.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1
---------------------- Page: 1 ----------------------
D 3352 – 08a
5. Significance and Use
4
5.1 This test method can be used to determine strontium ions in brackish water, seawater, and brines.
6. Interferences
6.1 The chemical suppression caused by silicon, aluminum, and phosphate is controlled by adding lanthanum. The lanthanum
also controls ionization interference.
7. Apparatus
7.1 Atomic Absorption Spectrophotometer —The instrument shall consist of atomizer and burner, suitable pressure-regulating
devicescapableo
...
This document is not anASTM standard and is intended only to provide the user of anASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation:D 3352–08 Designation: D 3352 – 08a
Standard Test Method for
1
Strontium Ion in Brackish Water, Seawater, and Brines
This standard is issued under the fixed designation D 3352; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This test method covers the determination of soluble strontium ion in brackish water, seawater, and brines by atomic
absorption spectrophotometry.
1.2 Samples containing from 5 to 2100 mg/L of strontium may be analyzed by this test method.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
2. Referenced Documents
2
2.1 ASTM Standards:
D 1129 Terminology Relating to Water
D1193
D 1193 Specification for Reagent Water
D 2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D 3370 Practices for Sampling Water from Closed Conduits
D5810
D 5810 Guide for Spiking into Aqueous Samples
D5847
D 5847 Practice for Writing Quality Control Specifications for Standard Test Methods for Water Analysis
3. Terminology
3.1 Definitions—For definitions of terms used in this test method, refer to Terminology D 1129.
4. Summary of Test Method
4.1 Thistestmethodisdependentonthefactthatmetallicelements,inthegroundstate,willabsorblightofthesamewavelength
they emit when excited. When radiation from a given excited element is passed through a flame containing ground state atoms of
that element, the intensity of the transmitted radiation will decrease in proportion to the amount of the ground state element in the
3
flame. A hollow cathode lamp whose cathode is made of the element to be determined provides the radiation. The metal atoms
tobemeasuredareplacedinthebeamofradiationbyaspiratingthespecimenintoanoxidant-fuelflame.Amonochromatorisolates
the characteristic radiation from the hollow cathode lamp and a photosensitive device measures the attenuated transmitted
radiation.
4.2 Since the variable and sometimes high concentrations of matrix materials in the waters and brines affect absorption
differently, it is difficult to prepare standards sufficiently similar to the waters and brines. To overcome this difficulty, the method
of additions is used in which three identical samples are prepared and varying amounts of a standard added to two of them. The
three samples are then aspirated, the concentration readings recorded, and the original sample concentration calculated.
1
ThistestmethodisunderthejurisdictionofASTMCommitteeD19onWaterandisthedirectresponsibilityofSubcommitteeD19.05onInorganicConstituentsinWater.
Current edition approved Aug.Nov. 15, 2008. Published SeptemberNovember 2008. Originally approved in 1974. Last previous edition approved in 20032008 as
´1
D3352–03 . D 3352 – 08.
2
For referencedASTM standards, visit theASTM website, www.astm.org, or contactASTM Customer Service at service@astm.org. ForAnnualBookofASTMStandards
volume information, refer to the standard’s Document Summary page on the ASTM website.
3
For additional information on atomic absorption, see the following references: Angino, E. E., and Billings, G. K., Atomic Absorption Spectrophotometry in Geology,
Elsevier Publishing Co., NewYork, N.Y., 1967. Dean, J.A., and Rains, T. C., Editors, Flame Emission andAtomicAbsorption Spectrometry Vol 1−Theory, Marcel Dekker,
New York, NY, 1969.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1
---------------------- Page: 1 ----------------------
D 3352 – 08a
5. Significance and Use
4
5.1 This test method can be used to determine strontium ions in brackish water, seawater, and brines.
6. Interferences
6.1 The chemical suppression caused by silicon, aluminum, and phosphate is controlled by adding lanthanum. The lanthanum
also controls ionization interference.
7. Apparatus
7.1 Atomic Absorption Spectrophotometer —The instrument shall consist of atomizer and burner, suitable pressure-regulating
devicescapableofmaintainingconsta
...
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