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ASTM D5394-02

(Specification)

Standard Specification for Reclaimed 1,1,1-Trichloroethane

Standard Specification for Reclaimed 1,1,1-Trichloroethane

SCOPE
1.1 This specification defines Type I (high quality reclaimed 1,1,1-trichloroethane, approximating MIL Specification), Type II (good quality reclaimed solvent), Type III (minimal acceptable reclaimed solvent).
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For a specific hazards statement see Section 4.
1.3 1,1,1-trichloroethane also is known commercially as methyl chloroform.

General Information

Status
Historical
Publication Date
09-Dec-2002
ICS
71.080.20 - Halogenated hydrocarbons
Technical Committee
D26 - Halogenated Organic Solvents and Fire Extinguishing Agents
Drafting Committee
D26.02 - Vapor Degreasing
Current Stage
Ref Project

Relations

Replaces
ASTM D5394-97 - Standard Specification for Reclaimed 1,1,1-Trichloroethane
Effective Date
10-Dec-2002
Replaced By
ASTM D5394-02(2007) - Standard Specification for Reclaimed 1,1,1-Trichloroethane
Effective Date
01-Feb-2007

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ASTM D5394-02 - Standard Specification for Reclaimed 1,1,1-TrichloroethaneASTM D5394-02 - Standard Specification for Reclaimed 1,1,1-Trichloroethane
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ASTM D5394-02 - Standard Specification for Reclaimed 1,1,1-Trichloroethane
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Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D 5394 – 02
Standard Specification for
1
Reclaimed 1,1,1-Trichloroethane
This standard is issued under the fixed designation D 5394; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
TABLE 1 Properties, Type I
1. Scope
Property Specification Test Method
1.1 This specification definesType I (high quality reclaimed
Appearance Free of turbidity and D 3741
1,1,1-trichloroethane, approximating MIL Specification), Type
suspended matter
II (good quality reclaimed solvent), Type III (minimal accept-
1,1,1-trichloroethane, weight %, 92 D 6806
able reclaimed solvent).
min
Nonvolatile residue, weight 0.0040 D 2109
1.2 This standard does not purport to address all of the
%, max
safety concerns, if any, associated with its use. It is the
Color, Pt-Co, max 25 D 2108
responsibility of the user of this standard to establish appro-
Water, weight %, max 0.015 D 3401
Acid acceptance as NaOH, weight 0.20 D 2942
priate safety and health practices and determine the applica-
%, min
bility of regulatory limitations prior to use. For a specific
A
Aluminum scratch test Passes D 2943
hazards statement see Section 4. Acidity as HCl, weight %, max 0.001 D 2989
Alkalinity as NaOH, weight %, max 0.020 D 2106
1.3 1,1,1-trichloroethane also is known commercially as
Halide as Cl, weight %, max 0.0005 D 2988
methyl chloroform.
A
Distill 100 mL solvent, collect 50 mL distillate, and conduct scratch test on
distillate and portion remaining in distillation flask.
2. Referenced Documents
2.1 ASTM Standards:
D 2106 Test Method for the Determination of Amine Acid
2.2 Other Documents:
2
3
Acceptance (Alkalinity) of Halogenated Organic Solvents STP-310A Handbook of Vapor Degreasing
4
D 2108 Test Method for Color of Halogenated Organic
STP-403A Cold Cleaning with Halogenated Solvents
2
Solvents and Their Admixtures (Platinum-Cobalt Scale)
3. Properties
D 2109 Test Methods for Nonvolatile Matter in Haloge-
2
nated Organic Solvents and Their Admixtures 3.1 Reclaimed 1,1,1-trichloroethane, Type I, shall conform
D 2942 Test Method for Total Acid Acceptance of Haloge- to the requirements of Table 1.
2
nated Organic Solvents (Nonreflux Method)
3.2 Reclaimed 1,1,1-trichloroethane, Type II, shall conform
D 2943 Test Method for Aluminum Scratch of 1,1,1- to the requirements of Table 2. See STP-310A.
2
Trichloroethane
3.3 Reclaimed 1,1,1-trichloroethane, Type III, shall con-
D 2988 Test Method for Water-Soluble Halide Ion in Halo- form to the requirements of Table 3. See STP-403A.
2
genated Organic Solvents and Their Admixtures
3.4 This specification does not address the possibility of
D 2989 Test Method for Acidity-Alkalinity of Halogenated product flash points due to the presence of flammable constitu-
2
Organic Solvents and Their Admixtures
ents. However, flash point must be determined for proper
D 3401 Test Methods for Water in Halogenated Organic labeling and shipment. The Tag closed-cup procedure is
2
Solvents and Their Admixtures
recommended.
D 3741 Test Method for Appearance of Admixtures Con- 3.5 Specific gravity for these grades typically will be
2
taining Halogenated Organic Solvents between 1.25 and 1.37.
D 3844 Practice for Labeling Halogenated Hydrocarbon
2
4. Hazards
Solvent Containers
4.1 Due to the possible presence of low level foreign
D 6806 Practice for Analysis of Halogenated Organic Sol-
2
vents and Their Admixtures by Gas Chromatography contaminants in reclaimed 1,1,1-trichloroethane, the user is
cautioned to use due care in determining the effects of these
contaminants.
1
This specification is under the jurisdiction of ASTM Committee D26 on
Halogenated Organic Solvents and Fire Extinguishing Agents and is the direct
responsibility of Subcommittee D26.02 on Vapor Degreasing.
3
Current edition approved Dec. 10, 2002. Published February 2003. Originally Symposium on Vapor Degreasing, ASTM STP 310A, ASTM.
4
published in 1993. Last previous edition approved in 1997 as D 5394-97. Symposium on Cold Cleaning With Halogenated Solvents, ASTM STP 403A,
2
Annual Book of ASTM Standards, Vol 15.05. ASTM.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
1

---------------------- Page: 1 ----------------------
D5394–02
TABLE 2 Properties, Type II
Property Specification Test Method
Appearance Free of turbidity and D 3741
suspended matter
1,1,1-trichloroethane, weight %, 90 D 6806
min
Nonvolatile residue (NVR), weight 0.010 D 2109
%, max
Color, Pt-Co, max 30 D 2108
Water, weight %, max 0.015 D 3401
Acid acceptance as NaOH, weight 0.20 D 2942
%, min
A
Aluminum scratch test Passes
...

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