ASTM D5184-22
(Test Method)Standard Test Methods for Determination of Aluminum and Silicon in Fuel Oils by Ashing, Fusion, Inductively Coupled Plasma Atomic Emission Spectrometry, and Atomic Absorption Spectrometry
Standard Test Methods for Determination of Aluminum and Silicon in Fuel Oils by Ashing, Fusion, Inductively Coupled Plasma Atomic Emission Spectrometry, and Atomic Absorption Spectrometry
SIGNIFICANCE AND USE
5.1 Catalyst fines in fuel oils can cause abnormal engine wear. These test methods provide a means of determining silicon and aluminum, the major constituents of the catalysts.
SCOPE
1.1 These test methods cover the determination of aluminum and silicon in fuel oils at concentrations between 5 mg/kg and 150 mg/kg for aluminum and 10 mg/kg and 250 mg/kg for silicon.
1.2 Test Method A—Inductively coupled plasma atomic emission spectrometry is used in this test method to quantitatively determine aluminum and silicon.
1.3 Test Method B—Flame atomic absorption spectrometry is used in this test method to quantitatively determine aluminum and silicon.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. Specific warning statements are given in Sections 7.6, 10.1, and 11.5.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
Relations
Buy Standard
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D5184 − 22
Standard Test Methods for
Determination of Aluminum and Silicon in Fuel Oils by
Ashing, Fusion, Inductively Coupled Plasma Atomic
Emission Spectrometry, and Atomic Absorption
1
Spectrometry
This standard is issued under the fixed designation D5184; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* 2. Referenced Documents
2
2.1 ASTM Standards:
1.1 These test methods cover the determination of alumi-
num and silicon in fuel oils at concentrations between 5 mg⁄kg D1193 Specification for Reagent Water
D4057 Practice for Manual Sampling of Petroleum and
and150 mg⁄kgforaluminumand10 mg⁄kgand250 mg⁄kgfor
silicon. Petroleum Products
D4175 Terminology Relating to Petroleum Products, Liquid
1.2 Test Method A—Inductively coupled plasma atomic
Fuels, and Lubricants
emission spectrometry is used in this test method to quantita-
D4177 Practice for Automatic Sampling of Petroleum and
tively determine aluminum and silicon.
Petroleum Products
1.3 Test Method B—Flame atomic absorption spectrometry
D6299 Practice for Applying Statistical Quality Assurance
is used in this test method to quantitatively determine alumi-
and Control Charting Techniques to Evaluate Analytical
num and silicon.
Measurement System Performance
D6792 Practice for Quality Management Systems in Petro-
1.4 The values stated in SI units are to be regarded as
leum Products, Liquid Fuels, and Lubricants Testing
standard. No other units of measurement are included in this
Laboratories
standard.
D7260 Practice for Optimization, Calibration, and Valida-
1.5 This standard does not purport to address all of the
tion of Inductively Coupled Plasma-Atomic Emission
safety concerns, if any, associated with its use. It is the
Spectrometry (ICP-AES) for ElementalAnalysis of Petro-
responsibility of the user of this standard to establish appro-
leum Products and Lubricants
priate safety, health, and environmental practices and deter-
D7740 Practice for Optimization, Calibration, and Valida-
mine the applicability of regulatory limitations prior to use.
tion ofAtomicAbsorption Spectrometry for MetalAnaly-
Specific warning statements are given in Sections 7.6, 10.1,
sis of Petroleum Products and Lubricants
and 11.5.
1.6 This international standard was developed in accor-
3. Terminology
dance with internationally recognized principles on standard-
3.1 Definitions:
ization established in the Decision on Principles for the
3.1.1 For definitions of terms used in this test method, refer
Development of International Standards, Guides and Recom-
to Terminology D4175.
mendations issued by the World Trade Organization Technical
3.2 Definitions of Terms Specific to This Standard:
Barriers to Trade (TBT) Committee.
3.2.1 calibration, n—the process by which the relationship
between signal intensity and elemental concentration is deter-
mined for a specific element analysis.
1
These test methods are under the jurisdiction of ASTM Committee D02 on
Petroleum Products, Liquid Fuels, and Lubricants and are the direct responsibility
2
of Subcommittee D02.03 on Elemental Analysis. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved Oct. 1, 2022. Published October 2022. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1991. Last previous edition approved in 2017 as D5184 – 12 (2017). Standards volume information, refer to the standard’s Document Summary page on
DOI: 10.1520/D5184-22. the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
D5184 − 22
3.2.2 check standard, n—incalibration,anartifactmeasured 6.6 Electric Oven, maintained at a temperature of 50 °C to
periodically, the results of which typically are plotted on a 60 °C.
control chart to evaluate the measurement process.
6.7 Graduated Cylinders, 10 mL, 25 mL, 50 mL, and
100 mL.
4. Summary of Test Methods
6.8 Pipettes, 1 mL, 2 mL, 5 mL, 10 mL, 20 mL, and 25 mL.
4.1 Aweighed quantity of homogenized sample is heated in
6.9 Platinum Dish, 100 mL capacity, cleaned with fused
a clean platinum dish, the combustible material is removed by
potassium hydrogen sulfate.
burning and the carbon finally removed by heating in a muffle
furnace at a temperature of 550 °C
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D5184 − 12 (Reapproved 2017) D5184 − 22
Standard Test Methods for
Determination of Aluminum and Silicon in Fuel Oils by
Ashing, Fusion, Inductively Coupled Plasma Atomic
Emission Spectrometry, and Atomic Absorption
1
Spectrometry
This standard is issued under the fixed designation D5184; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope Scope*
1.1 These test methods cover the determination of aluminum and silicon in fuel oils at concentrations between 5 mg ⁄kg and
150 mg ⁄kg for aluminum and 10 mg ⁄kg and 250 mg ⁄kg for silicon.
1.2 Test Method A—Inductively coupled plasma atomic emission spectrometry is used in this test method to quantitatively
determine aluminum and silicon.
1.3 Test Method B—Flame atomic absorption spectrometry is used in this test method to quantitatively determine aluminum and
silicon.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety safety, health, and healthenvironmental practices and determine the
applicability of regulatory limitations prior to use. Specific warning statements are given in Sections 7.6, 10.1, and 11.5.
1.6 This international standard was developed in accordance with internationally recognized principles on standardization
established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued
by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
2. Referenced Documents
2
2.1 ASTM Standards:
D1193 Specification for Reagent Water
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4175 Terminology Relating to Petroleum Products, Liquid Fuels, and Lubricants
D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measure-
ment System Performance
1
These test methods are under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and are the direct responsibility of
Subcommittee D02.03 on Elemental Analysis.
Current edition approved May 1, 2017Oct. 1, 2022. Published June 2017October 2022. Originally approved in 1991. Last previous edition approved in 20122017 as
D5184 – 12.D5184 – 12 (2017). DOI: 10.1520/D5184-12R17.10.1520/D5184-22.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM Standards
volume information, refer to the standard’s Document Summary page on the ASTM website.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1
---------------------- Page: 1 ----------------------
D5184 − 22
D6792 Practice for Quality Management Systems in Petroleum Products, Liquid Fuels, and Lubricants Testing Laboratories
D7260 Practice for Optimization, Calibration, and Validation of Inductively Coupled Plasma-Atomic Emission Spectrometry
(ICP-AES) for Elemental Analysis of Petroleum Products and Lubricants
D7740 Practice for Optimization, Calibration, and Validation of Atomic Absorption Spectrometry for Metal Analysis of
Petroleum Products and Lubricants
E135 Terminology Relating to Analytical Chemistry for Metals, Ores, and Related Materials
3. Terminology
3.1 Definitions:
3.1.1 emission spectroscopy, n—Refer to Terminology E135.
3.1.1 For definitions of terms used in this test method, refer to Terminology D4175.
3.2 Definitions of Terms Specific to This Standard:
3.2.1 calibration, n—the process by which the relationship between signal intensity and elemental concentration is determined for
a specific element analysis.
3.2.2 check standard, n—in calibration, an artifact measured periodically, the results of which typically are plotted on a control
chart to evaluate the measurement process.
4. Summary of Test Methods
4.1 A weighed quantity of homogenized sample is heated in a clean platinum dish, the combustible material is rem
...
Questions, Comments and Discussion
Ask us and Technical Secretary will try to provide an answer. You can facilitate discussion about the standard in here.