ASTM C471M-14

Standard Test Methods for Chemical Analysis of Gypsum and Gypsum Products (Metric)

SIGNIFICANCE AND USE
17.1 This test method covers the determination of calcium sulfate in gypsum and gypsum products by extraction with ammonium acetate solution.
SCOPE
1.1 These test methods cover the chemical analysis of gypsum and gypsum panel products, including gypsum ready-mixed plaster, gypsum wood-fibered plaster, and gypsum concrete.  
1.2 The test methods appear in the following order:    
Sections  
Preparation of Sample  
4  
Complete Procedure  
5 – 16  
Alternative Procedure for Analysis for Calcium Sulfate by Ammonium Acetate Method  
17 – 22  
Alternative Procedure for Analysis for Sodium Chloride by the Coulometric Method  
23 – 29  
Determination of Sand in Set Plaster  
30 – 36  
Wood-Fiber Content in Wood-Fiber Gypsum Plaster  
37 – 39  
Optional Procedure for Analysis for Sodium by the Atomic Absorption Method  
40 – 46  
Optional Procedure for Analysis for Sodium by Flame Photometry  
47 – 54  
Determination of Orthorhombic Cyclooctasulfur (S8) in Ggypsum Panel Products—General Provisions  
55  
Determination of Orthorhombic Cyclooctasulfur (S8) in Gypsum Panel Products by Gas Chromatograph Equipped with a Mass Spectrometer (GS/MS)  
56  
Determination of Orthorhombic Cyclooctasulfur (S8) in Gypsum Panel Products by Gas Chromatograph Equipped with an Electron Capture Detector (GC/ECD)  
57  
Determination of Orthorhombic Cyclooctasulfur (S8) in Gypsum Panel Products by High-performance Liquid Chromatograph Equipped with and Ultraviolet Detector (HPLC/UV)  
58  
1.3 The text of this standard references notes and footnotes that provide explanatory material. These notes and footnotes (excluding those in tables and figures) shall not be considered as requirements of the standard.  
1.4 The values stated in SI units are to be regarded as the standard.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

• Status: Historical
• Publication Date: 31-Oct-2014
• ICS: 91.100.10 - Cement. Gypsum. Lime. Mortar
• Technical Committee: C11 - Gypsum and Related Building Materials and Systems
• Drafting Committee: C11.01 - Specifications and Test Methods for Gypsum Products

Relations

• Replaces: ASTM C471M-13 - Standard Test Methods for Chemical Analysis of Gypsum and Gypsum Products (Metric)
• Effective Date: 01-Nov-2014
• Replaced By: ASTM C471M-16 - Standard Test Methods for Chemical Analysis of Gypsum and Gypsum Products (Metric)
• Effective Date: 01-Jan-2016
• Referred By: ASTM C22/C22M-00(2021) - Standard Specification for Gypsum
• Effective Date: 01-Nov-2014
• Referred By: ASTM C59/C59M-00(2020) - Standard Specification for Gypsum Casting Plaster and Gypsum Molding Plaster
• Effective Date: 01-Nov-2014
• Referred By: ASTM C452-21 - Standard Test Method for Potential Expansion of Portland-Cement Mortars Exposed to Sulfate
• Effective Date: 01-Nov-2014
• Referred By: ASTM C28/C28M-10(2020) - Standard Specification for Gypsum Plasters
• Effective Date: 01-Nov-2014
• Referred By: ASTM D3987-12(2020) - Standard Practice for Shake Extraction of Solid Waste with Water
• Effective Date: 01-Nov-2014
• Referred By: ASTM C35-01(2019) - Standard Specification for Inorganic Aggregates for Use in Gypsum Plaster
• Effective Date: 01-Nov-2014
• Referred By: ASTM C563-20 - Standard Guide for Approximation of Optimum SO<inf>3</inf> in Hydraulic Cement
• Effective Date: 01-Nov-2014
• Referred By: ASTM E3355-23 - Standard Guide for Characterization of Coal Combustion Products (CCPs) in Storage Area(s) for Beneficial Use
• Effective Date: 01-Nov-2014
• Referred By: ASTM C1396/C1396M-17 - Standard Specification for Gypsum Board
• Effective Date: 01-Nov-2014
• Referred By: ASTM C61/C61M-00(2020) - Standard Specification for Gypsum Keene's Cement
• Effective Date: 01-Nov-2014
• Referred By: ASTM D8155-17 - Standard Practice for Shake Extraction of Solid Mining and Metallurgical Processing Waste with Water
• Effective Date: 01-Nov-2014

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: C471M − 14
StandardTest Methods for
Chemical Analysis of Gypsum and Gypsum Products
1
(Metric)
This standard is issued under the fixed designation C471M; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* 1.4 The values stated in SI units are to be regarded as the
standard.
1.1 These test methods cover the chemical analysis of
1.5 This standard does not purport to address all of the
gypsum and gypsum panel products, including gypsum ready-
safety concerns, if any, associated with its use. It is the
mixed plaster, gypsum wood-fibered plaster, and gypsum
responsibility of the user of this standard to establish appro-
concrete.
priate safety and health practices and determine the applica-
1.2 The test methods appear in the following order:
bility of regulatory limitations prior to use.
Sections
Preparation of Sample 4
2. Referenced Documents
Complete Procedure 5–16
2
Alternative Procedure for Analysis for
2.1 ASTM Standards:
Calcium Sulfate by Ammonium Acetate 17–22
C11 Terminology Relating to Gypsum and Related Building
Method
Alternative Procedure for Analysis for Materials and Systems
Sodium Chloride by the Coulometric 23–29
C22/C22M Specification for Gypsum
Method
C28/C28M Specification for Gypsum Plasters
Determination of Sand in Set Plaster 30–36
Wood-Fiber Content in Wood-Fiber Gyp- 37–39
C59 Specification for Gypsum Casting Plaster and Gypsum
sum Plaster
Molding Plaster
Optional Procedure for Analysis for So-
C61 Specification for Gypsum Keene’s Cement
dium by the Atomic Absorption Method 40–46
Optional Procedure for Analysis for So- 47–54
C317/C317M Specification for Gypsum Concrete
dium by Flame Photometry
C778 Specification for Standard Sand
Determination of Orthorhombic Cyclooc- 55
C842 Specification forApplication of Interior Gypsum Plas-
tasulfur (S ) in Ggypsum Panel
8
Products—General Provisions
ter
Determination of Orthorhombic Cyclooc- 56
D1193 Specification for Reagent Water
tasulfur (S ) in Gypsum Panel Prod-
8
D1428 Test Method for Test for Sodium and Potassium In
ucts by Gas Chromatograph Equipped
with a Mass Spectrometer (GS/MS)
Water and Water-Formed Deposits by Flame Photometry
Determination of Orthorhombic Cyclooc- 57 3
(Withdrawn 1989)
tasulfur (S ) in Gypsum Panel Prod-
8
D2013 Practice for Preparing Coal Samples for Analysis
ucts by Gas Chromatograph Equipped
with an Electron Capture Detector
E11 Specification for Woven Wire Test Sieve Cloth and Test
(GC/ECD)
Sieves
Determination of Orthorhombic Cyclooc- 58
tasulfur (S ) in Gypsum Panel Prod-
8
ucts by High-performance Liquid Chro- 3. Terminology
matograph Equipped with and
3.1 Definitions—Definitions shall be in accordance with
Ultraviolet Detector (HPLC/UV)
Terminology C11.
1.3 The text of this standard references notes and footnotes
3.2 Definitions of Terms Specific to This Standard:
that provide explanatory material. These notes and footnotes
3.2.1 calibration standard, n—a chemical mixture contain-
(excluding those in tables and figures) shall not be considered
ing a known quantity of the analyte used to relate the measured
as requirements of the standard.
analytical signal to the concentration of the analyte.
1
These test methods are under the jurisdiction of ASTM Committee C11 on
2
Gypsum and Related Building Materials and Systems and are the direct responsi- For referenced ASTM standards, visit the ASTM website, www.astm.org, or
bility of Subcommittee C11.01 on Specifications and Test Methods for Gypsum contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM
Products. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved Nov. 1, 2014. Published November 2014. Originally the ASTM website.
3
approved in 1961. Last previous edition approved in 2013 as C471 – 13. DOI: The last approved version of this historical standard is referenced on
10.1520/C0471M-14. www.astm.org.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
C471M − 14
3.2.2 dried sample, n—a sample devoid of free water. 4.4 Gypsum Casting and Molding Plaster,(C59)—Reduce
the dried sample in accordance with 4.1.5. Thoroughly blend
3.2.3 internal standard, n—a chemical used in the quantifi-
and rehydrate the specimen in accordance with 4.1.4.
cationofS bymonitoringandadjustingforminorvariancesin
8
instrument performance.
4.5 Gypsum Keene’s Cement,(C61)—Reduce the dried
sample in accordance with 4.1.5
...

This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: C471M − 13 C471M − 14
Standard Test Methods for
Chemical Analysis of Gypsum and Gypsum Products
1
(Metric)
This standard is issued under the fixed designation C471M; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope Scope*
1.1 These test methods cover the chemical analysis of gypsum and gypsum panel products, including gypsum ready-mixed
plaster, gypsum wood-fibered plaster, and gypsum concrete.
1.2 The test methods appear in the following order:
Sections
Preparation of Sample 4
Complete Procedure 5 – 16
Alternative Procedure for Analysis for
Calcium Sulfate by Ammonium Acetate 17 – 22
Method
Alternative Procedure for Analysis for
Sodium Chloride by the Coulometric 23 – 29
Method
Determination of Sand in Set Plaster 30 – 36
Wood-Fiber Content in Wood-Fiber Gyp- 37 – 39
sum Plaster
Optional Procedure for Analysis for So-
dium by the Atomic Absorption Method 40 – 46
Optional Procedure for Analysis for So- 47 – 54
dium by Flame Photometry
Determination of Sulfur (S ) in Gypsum 55–65
8
Panel Products by Liquid Extraction for
Analysis by Liquid or Gas Chromatog-
raphy
Determination of Orthorhombic Cyclooc- 55
tasulfur (S ) in Ggypsum Panel
8
Products—General Provisions
Determination of Orthorhombic Cyclooc- 56
tasulfur (S ) in Gypsum Panel Prod-
8
ucts by Gas Chromatograph Equipped
with a Mass Spectrometer (GS/MS)
Determination of Orthorhombic Cyclooc- 57
tasulfur (S ) in Gypsum Panel Prod-
8
ucts by Gas Chromatograph Equipped
with an Electron Capture Detector
(GC/ECD)
Determination of Orthorhombic Cyclooc- 58
tasulfur (S ) in Gypsum Panel Prod-
8
ucts by High-performance Liquid Chro-
matograph Equipped with and
Ultraviolet Detector (HPLC/UV)
1.3 The text of this standard references notes and footnotes that provide explanatory material. These notes and footnotes
(excluding those in tables and figures) shall not be considered as requirements of the standard.
1.4 The values stated in SI units are to be regarded as the standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility
of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory
limitations prior to use.
1
These test methods are under the jurisdiction of ASTM Committee C11 on Gypsum and Related Building Materials and Systems and are the direct responsibility of
Subcommittee C11.01 on Specifications and Test Methods for Gypsum Products.
Current edition approved Dec. 1, 2013Nov. 1, 2014. Published January 2014November 2014. Originally approved in 1961. Last previous edition approved in 20122013
as C471C471 – 13. – 01 (Reapproved 2012). DOI: 10.1520/C0471M-13.DOI: 10.1520/C0471M-14.
*A Summary of Changes section appears at the end of this standard
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

---------------------- Page: 1 ----------------------
C471M − 14
2. Referenced Documents
2
2.1 ASTM Standards:
C11 Terminology Relating to Gypsum and Related Building Materials and Systems
C22/C22M Specification for Gypsum
C28/C28M Specification for Gypsum Plasters
C59 Specification for Gypsum Casting Plaster and Gypsum Molding Plaster
C61 Specification for Gypsum Keene’s Cement
C317/C317M Specification for Gypsum Concrete
C778 Specification for Sand
C842 Specification for Application of Interior Gypsum Plaster
D1193 Specification for Reagent Water
D1428 Test Method for Test for Sodium and Potassium In Water and Water-Formed Deposits by Flame Photometry (Withdrawn
3
1989)
D2013 Practice for Preparing Coal Samples for Analysis
E11 Specification for Woven Wire Test Sieve Cloth and Test Sieves
3. Terminology
3.1 Definitions—Definitions shall be in accordance with Terminology C11.
3.2 Definitions of Terms Specific to This Standard:
3.2.1 calibration standard, n—a chemical mixture containing a known quantity of the analyte used to relate the measured
analytical signal to the concentration of the analyte.
3.2.2 dried sample, n—a sample devoid of free water.
3.2.3 internal standard, n—a chemical used in the quantification of S by monitoring and adjusting for minor variances in
8
instrument performance.
3.2.4 riffle, n—a hand feed sample divider device that divides the sam
...