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ASTM D4077-07

(Specification)

Standard Specification for Cumene (Isopropylbenzene)

Standard Specification for Cumene (Isopropylbenzene)

ABSTRACT
This specification covers cumene (isopropylbenzene). Tests shall be performed to determine the requirements of cumene in accordance to the following test methods: purity; alpha-methylstrene, benzene, butylbenzenes, diisopropylbenzenes, ethylbenzene, phenols, n-propylbenzene, sulfur, bromine index, and appearance.
SCOPE
1.1 This specification covers cumene (isopropylbenzene).
1.2 The following applies to all specified limits in this specification: for purposes of determining conformance with this specification, an observed value or a calculated value shall be rounded off "to the nearest unit" in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E 29.
1.3 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.
1.4 Consult current OSHA Regulations and Supplier's Material Safety Data Sheets, and local regulations for all materials used in this specification.

General Information

Status
Historical
Publication Date
31-May-2007
ICS
71.080.15 - Aromatic hydrocarbons
Technical Committee
D16 - Aromatic, Industrial, Specialty and Related Chemicals
Drafting Committee
D16.07 - Styrene, Ethylbenzene and C9 and C10 Aromatic Hydrocarbons
Current Stage
Ref Project

Relations

Replaces
ASTM D4077-04 - Standard Specification for Cumene (Isopropylbenzene)
Effective Date
01-Jun-2007
Replaced By
ASTM D4077-11 - Standard Specification for Cumene (Isopropylbenzene)
Effective Date
01-Jun-2011

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ASTM D4077-07 - Standard Specification for Cumene (Isopropylbenzene)ASTM D4077-07 - Standard Specification for Cumene (Isopropylbenzene)
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ASTM D4077-07 - Standard Specification for Cumene (Isopropylbenzene)
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: D4077 – 07
Standard Specification for
1
Cumene (Isopropylbenzene)
This standard is issued under the fixed designation D4077; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope* D7057 Test Method for Analysis of Isopropylbenzene
(Cumene) by Gas Chromatography (External Standard)
1.1 This specification covers cumene (isopropylbenzene).
D7183 Test Method for Determination of Total Sulfur in
1.2 The following applies to all specified limits in this
Aromatic Hydrocarbons and Related Chemicals by Ultra-
specification: for purposes of determining conformance with
violet Fluorescence
this specification, an observed value or a calculated value shall
E29 Practice for Using Significant Digits in Test Data to
be rounded off “to the nearest unit” in the last right-hand digit
Determine Conformance with Specifications
used in expressing the specification limit, in accordance with
E298 Test Methods for Assay of Organic Peroxides
the rounding-off method of Practice E29.
E299 Test Method for Trace Amounts of Peroxides In
1.3 The values stated in SI units are to be regarded as the
Organic Solvents
standard. The values given in parentheses are for information
2.2 Other Documents:
only.
OSHA Regulations, 29 CFR paragraphs 1910.1000 and
1.4 Consult current OSHA Regulations and Supplier’s Ma-
3
1910.1200
terialSafetyDataSheets,andlocalregulationsforallmaterials
used in this specification.
3. Properties
2. Referenced Documents 3.1 Cumene (isopropylbenzene) shall conform to the fol-
2
lowing requirements:
2.1 ASTM Standards:
ASTM Test
D1209 Test Method for Color of Clear Liquids (Platinum-
Specifications
A
Property Method
Cobalt Scale)
D1492 Test Method for Bromine Index ofAromatic Hydro- Purity, weight %, min 99.92 D3760 or D7057
Alpha-Methylstrene, weight %, max 0.01 D3760 or D7057
carbons by Coulometric Titration
Benzene, weight %, max 0.001 D3760 or D7057
D2710 Test Method for Bromine Index of Petroleum Hy-
Butylbenzenes, weight %, max 0.02 D3760 or D7057
drocarbons by Electrometric Titration Diisopropylbenzenes, weight %, max 0.002 D3760 or D7057
Ethylbenzene, weight %, max 0.01 D3760 or D7057
D3160 TestMethodforPhenolContentofCumene(Isopro-
Phenols, mg/kg, max 5 D3160, D3760 or
pylbenzene) or AMS (a−Methylstyrene)
D7057
D3437 Practice for Sampling and Handling Liquid Cyclic
n-Propylbenzene, weight %, max 0.03 D3760 or D7057
Sulfur, mg/kg, max 1 D7183
Products
Bromine index, max 100 D1492 or D2710
D3760 Test Method for Analysis of Isopropylbenzene
B
Appearance visual
(Cumene) by Gas Chromatography Color, Pt/Co, max 15 D1209 or D5386
Cumene hydroperoxide, at loading, 100 E298 or E299
D5386 Test Method for Color of Liquids Using Tristimulus
MD/kg, max
Colorimetry
A
If more than one method is listed for a property, the producer and the user
should agre
...

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This specification covers cumene (isopropylbenzene). Tests shall be performed to determine the requirements of cumene in accordance to the following test methods: purity; alpha-methylstrene, benzene, butylbenzenes, diisopropylbenzenes, ethylbenzene, phenols, n-propylbenzene, sulfur, bromine index, and appearance.
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