Standard Specification for Electrodeposited Coatings for Zinc Nickel Alloy Deposits

ABSTRACT
This specification covers the requirements for electrodeposited zinc nickel alloy coatings on metals. The zinc nickel coating shall be defined as Class 1. The five chromate conversion coating types shall be defined as follows: Type A shall be with colorless conversion coatings, Type B shall be with yellow iridescent conversion coatings, Type C shall be with bronze conversion coatings, Type D shall be with black chromate conversion coatings, and Type E shall be with any colors mentioned plus organic topcoat. The metal to be plated shall be free of flaws and defects that will be detrimental to the zinc alloy coating. It shall be subjected to such cleaning, pickling, and electroplating procedures as necessary to yield deposits. The coating shall be produced from an aqueous electroplating system that may be either an alkaline or acid formulation. The coating on all ready visible surfaces shall have an acceptable and characteristic appearance. The coating shall be adherent, free from blisters, pits, or discontinuities, and shall be free of cracks in the as plated state. The coating shall withstand normal handling and storage conditions without chipping, flaking, or other coating damage. The corrosion resistance of the coating shall be evaluated.
SCOPE
1.1 This specification covers the requirements for electrodeposited zinc nickel alloy coatings on metals.
1.2 The values stated in SI units are to be regarded as the standard.
1.3 The following precautionary statement pertains to the test method portion only, Section 8, of this specification: This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

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Publication Date
31-Dec-2009
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ASTM B841-99(2010) - Standard Specification for Electrodeposited Coatings for Zinc Nickel Alloy Deposits
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:B841 −99(Reapproved 2010)
Standard Specification for
1
Electrodeposited Coatings of Zinc Nickel Alloy Deposits
This standard is issued under the fixed designation B841; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope B568Test Method for Measurement of Coating Thickness
by X-Ray Spectrometry
1.1 Thisspecificationcoverstherequirementsforelectrode-
B571Practice for Qualitative Adhesion Testing of Metallic
posited zinc nickel alloy coatings on metals.
Coatings
1.2 The values stated in SI units are to be regarded as the
B602Test Method for Attribute Sampling of Metallic and
standard.
Inorganic Coatings
1.3 The following precautionary statement pertains to the
B697Guide for Selection of Sampling Plans for Inspection
test method portion only, Section 8, of this specification: This of Electrodeposited Metallic and Inorganic Coatings
standard does not purport to address all of the safety concerns,
B762Test Method of Variables Sampling of Metallic and
if any, associated with its use. It is the responsibility of the user Inorganic Coatings
of this standard to establish appropriate safety and health
B849Specification for Pre-Treatments of Iron or Steel for
practices and determine the applicability of regulatory limita- Reducing Risk of Hydrogen Embrittlement
tions prior to use.
B850GuideforPost-CoatingTreatmentsofSteelforReduc-
ing the Risk of Hydrogen Embrittlement
2. Referenced Documents
D3951Practice for Commercial Packaging
2
2.1 ASTM Standards:
3. Terminology
B117Practice for Operating Salt Spray (Fog) Apparatus
B183Practice for Preparation of Low-Carbon Steel for
3.1 Definitions—Many items used in this specification are
Electroplating
defined in Terminology B374.
B242Guide for Preparation of High-Carbon Steel for Elec-
3.2 Definitions of Terms Specific to This Standard:
troplating
3.2.1 significant surface, n—that portion of a coated arti-
B320Practice for Preparation of Iron Castings for Electro-
cle’s surface where the coating is required to meet all the
plating
requirements of the coating specification for that article.
B322Guide for Cleaning Metals Prior to Electroplating
Significant surfaces are usually those that are essential to the
B374Terminology Relating to Electroplating
serviceability or function of the article, or that can be a source
B487Test Method for Measurement of Metal and Oxide
of corrosion products or tarnish films that interfere with the
Coating Thickness by Microscopical Examination of
function or desirable appearance of the article.
Cross Section
3.2.2 Discussion—Significant surfaces are those surfaces
B499Test Method for Measurement of CoatingThicknesses
that are identified by the purchaser by, for example, indicating
by the Magnetic Method: Nonmagnetic Coatings on
them on an engineering drawing of the product or marking a
Magnetic Basis Metals
sample item of the product.
B504Test Method for Measurement of Thickness of Metal-
lic Coatings by the Coulometric Method
4. Classification
B507Practice for Design ofArticles to Be Electroplated on
Racks 4.1 There is one class of zinc nickel coating defined as
follows:
4.1.1 Class 1—Deposits having a minimum of 5 and maxi-
1
This specification is under the jurisdiction of ASTM Committee B08 on
mum 12 mass % nickel, the balance being zinc.
Metallic and Inorganic Coatingsand is the direct responsibility of Subcommittee
B08.06 on Soft Metals.
4.2 There are five chromate conversion coating types that
Current edition approved Jan. 1, 2010. Published February 2010. Originally
are defined as follows:
approved in 1993. Last previous edition approved in 12004 as B841–99(2004).
DOI: 10.1520/B0841-99R09.
4.2.1 Type A—With colorless (blue bright) conversion
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
coatings,
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
4.2.2 Type B—With yellow iridescent conversion coatings,
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. 4.2.3 Type C—With bronze conversion coatings,
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
1

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B841−99(2010)
4.2.4 Type D—With black chromate conversion coatings, 6.2.1 Thecoatingshallconsistofazincnickelalloythathas
and a minimum of 5 and maximum 12 mass percent nickel, the
4.2.5 Type E—Any of the above plus organic topcoat. balance being zinc.
6.2.2 The coating shall be produced from an aqueous
NOTE 1—Whereas colored chromate conversion coatings are usually
electropl
...

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