ASTM E133-92(2005)

Standard Specification for Distillation Equipment

ABSTRACT
This specification covers distillation equipment. The equipment shall consist of the following: distillation flasks, condenser, cooling bath, metal shield or enclosure for flask (type 1 or type 2), heat source (gas burner or electric heater), flask support (type 1 or type 2), graduated cylinders, and thermometers.
SCOPE
1.1 This specification covers distillation equipment used in the following ASTM test methods: D 86, D 850, and (for approved alternative requirements only) Test Method D 1078.
1.2 Some items of equipment included in this specification are common to all methods; other items are not. Therefore, those portions of this specification pertinent to the need must be selected.
1.3 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.

General Information

• Status: Historical
• Publication Date: 30-Sep-2005
• Technical Committee: E41 - Laboratory Apparatus
• Drafting Committee: E41.01 - Laboratory Ware and Supplies

Relations

• Replaces: ASTM E133-92(2000)e1 - Standard Specification for Distillation Equipment
• Effective Date: 01-Oct-2005
• Replaced By: ASTM E133-92(2010) - Standard Specification for Distillation Equipment
• Effective Date: 01-Jul-2010
• Referred By: ASTM D4530-15(2020) - Standard Test Method for Determination of Carbon Residue (Micro Method)
• Effective Date: 01-Oct-2005
• Referred By: ASTM E769-22 - Standard Test Methods for Odor of Methanol, Ethanol, <emph type="ital">n</emph>-Propanol, and Isopropanol
• Effective Date: 01-Oct-2005
• Referred By: ASTM D3326-07(2017) - Standard Practice for Preparation of Samples for Identification of Waterborne Oils
• Effective Date: 01-Oct-2005
• Referred By: ASTM D850-21 - Standard Test Method for Distillation of Industrial Aromatic Hydrocarbons and Related Materials
• Effective Date: 01-Oct-2005
• Referred By: ASTM D1078-11(2019) - Standard Test Method for Distillation Range of Volatile Organic Liquids
• Effective Date: 01-Oct-2005
• Referred By: ASTM D524-15(2019) - Standard Test Method for Ramsbottom Carbon Residue of Petroleum Products
• Effective Date: 01-Oct-2005
• Referred By: ASTM D189-06(2019) - Standard Test Method for Conradson Carbon Residue of Petroleum Products
• Effective Date: 01-Oct-2005

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation: E133 – 92 (Reapproved 2005)
Standard Specification for
Distillation Equipment
This standard is issued under the fixed designation E133; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope 4. Distillation Flasks
1.1 This specification covers distillation equipment used in 4.1 Flasks of heat-resistant glass shall be provided as
the following ASTM test methods: D86, D850, and (for indicated in Fig. 3 and shall comply with the requirements of
approved alternative requirements only) Test Method D1078. Specification E1405.
1.2 Some items of equipment included in this specification
5. Condenser and Cooling Bath
are common to all methods; other items are not. Therefore,
5.1 Typical approved types of condenser and cooling bath
those portions of this specification pertinent to the need must
be selected. are included in Fig. 1 and Fig. 2. These items are common to
all methods covered by this specification.
1.3 The values stated in inch-pound units are to be regarded
as standard. The values given in parentheses are mathematical 5.2 The condenser shall be made of seamless brass tubing,
22 in. (55.88 cm) in length. It shall be ⁄16 in. (14.29 mm) in
conversions to SI units that are provided for information only
and are not considered standard. outside diameter, and shall have a wall thickness of 0.031 to
0.036 in. (0.08 to 0.09 cm).
2. Referenced Documents
5.3 Thecondensershallbesetsothatapproximately15.5in.
2.1 ASTM Standards: (39.4 cm) of the tube will be in contact with the cooling
D86 Test Method for Distillation of Petroleum Products at medium, with about 2 in. (5 cm) outside the cooling bath at the
Atmospheric Pressure upper end, and about 4 ⁄2 in. (11 cm) outside at the lower end.
D850 Test Method for Distillation of Industrial Aromatic The length of tube projecting at the upper end shall be straight
Hydrocarbons and Related Materials and shall be set at an angle of 75° with the vertical.The section
D1078 Test Method for Distillation Range of Volatile Or- of the tube inside the cooling bath may be either straight or
ganic Liquids bent in any suitable continuous, smooth curve. The average
E1 Specification for ASTM Liquid-in-Glass Thermometers gradient shall be 0.26 in. (0.66 cm)/linear in. (2.54 cm) of
E1272 Specification for Laboratory Glass Graduated Cylin- condenser tube (sine of angle of 15°), and no section of the
ders immersed portion of the condenser tube shall have a gradient
E1405 Specification for Laboratory Glass Distillation less than 0.24 in. (0.61 cm) nor more than 0.28 in. (0.71 cm)/
Flasks linearin.oftube.Theprojectinglowerportionofthecondenser
tube shall be curved downward for a length of 3 in. (7.62 cm)
3. Apparatus Assembly
and slightly backward so as to ensure contact with the wall of
3.1 Typical assemblies of the apparatus are shown in Fig. 1
the receiving graduate at a point approximately 1 to 1 ⁄4 in.
and Fig. 2. (2.54 to 3.18 cm) below the top of the graduate when it is in
position to receive the distillate. The lower end of the con-
1 denser tube shall be cut off at an acute angle so that the tip may
This specification is under the jurisdiction of ASTM Committee E41 on
Laboratory Apparatus and is the direct responsibility of Subcommittee E41.01 on be brought into contact with the wall of the cylinder.
Apparatus.
5.4 The capacity of the cooling bath shall be not less than
Current edition approved Oct. 1, 2005. Published December 2005. Originally 3
340 in. (5.55 L) of cooling medium. The arrangement of the
´1
approved in 1958. Last previous edition approved in 2000 as E133 – 92 (2000) .
tube in the cooling bath shall be such that its center line shall
DOI: 10.1520/E0133-92R05.
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
be not less than 1 ⁄4 in. (3.18 cm) below the plane of the top of
contact ASTM Customer Service at [e-mail]. For Annual Book of ASTM 3
the bath at its point of entrance and not less than ⁄4 in. (1.91
Standards volume information, refer to the standard’s Document Summary page on
cm) above the floor of the bath at its exit.
the ASTM website.
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E133 – 92 (2005)
FIG. 1 Apparatus Assembly Using Gas Burner
6. Metal Shield or Enclosure for Flask
6.1 Type 1 Shield (Fig. 1) is 19 in. (48.26 cm) high, 11 in.
(27.94 cm) long, and 8 in. (20.32 cm) wide, made of sheet
metal of approximately 22 gauge. It shall have a door on one
narrow side, and two openings 1 in. (2.54 cm) in diameter,
equally spaced in each of the two narrow sides, with a slot cut
in one side for the vapor tube. The centers of these four
openings shall be 8 ⁄2 in. (21.59 cm) below the top of the
shield.There shall be three ⁄4-in. (1.27 cm) holes in each of the
four sides, with their centers 1 in. above the base of the shield.
6.2 Type 2 Shield (Fig. 2)is17 ⁄4 in. (44.45 cm) high, 8 in.
(20.32 cm) long, and 8 in. wide, made of sheet metal of
approximately 22 gauge, with a window on the front side. The
open bottom of the shield shall be spaced approximately 2 in.
(5 cm) from the base of the unit. The rear of the shield shall
have an elliptical hole for the vapor tube. A flask-adjusting
knob shall
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