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ASTM D1353-13(2021)

(Test Method)

Standard Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products

Standard Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products

SIGNIFICANCE AND USE
3.1 This test method describes the analytical measurement of residual matter in solvents that are intended to be 100 % volatile at 105 °C ± 5 °C. Volatile solvents are used in the manufacture of paint, varnish, lacquer, and other related products, and the presence of any residue may affect the product quality or efficiency of the process. This test method is useful in manufacturing control and assessing compliance with specifications.
SCOPE
1.1 This test method covers the determination of the nonvolatile matter in volatile solvents for use in paint, varnish, lacquer, and related products.  
1.2 The following applies to all specified limits in this standard; for purposes of determining conformance with this standard, an observed value or a calculated value shall be rounded off “to the nearest unit” in the last right-hand digit used in expressing the specification limit, in accordance with the rounding-off method of Practice E29.  
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.4 For hazard information and guidance, see the supplier’s Material Safety Data Sheet for materials listed in this test method.  
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 5.  
1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

General Information

Status
Published
Publication Date
30-Jun-2021
ICS
87.060.30 - Solvents
Technical Committee
D01 - Paint and Related Coatings, Materials, and Applications
Drafting Committee
D01.35 - Solvents, Plasticizers, and Chemical Intermediates
Current Stage
Ref Project

Relations

Refers
ASTM E299-17 - Standard Test Method for Trace Amounts of Peroxides In Organic Solvents
Effective Date
01-Feb-2017
Refers
ASTM E177-14 - Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
Effective Date
01-May-2014
Refers
ASTM E177-13 - Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
Effective Date
01-May-2013
Refers
ASTM E691-13 - Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
Effective Date
01-May-2013
Refers
ASTM E691-11 - Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
Effective Date
01-Nov-2011
Refers
ASTM E177-10 - Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
Effective Date
01-Oct-2010
Refers
ASTM E177-08 - Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
Effective Date
01-Oct-2008
Refers
ASTM E29-08 - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
Effective Date
01-Oct-2008
Refers
ASTM E691-08 - Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method
Effective Date
01-Oct-2008
Refers
ASTM E299-08 - Standard Test Method for Trace Amounts of Peroxides In Organic Solvents
Effective Date
01-Apr-2008
Refers
ASTM E177-06b - Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
Effective Date
15-Nov-2006
Refers
ASTM E29-06b - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
Effective Date
15-Nov-2006
Refers
ASTM E177-06a - Standard Practice for Use of the Terms Precision and Bias in ASTM Test Methods
Effective Date
01-Nov-2006
Refers
ASTM E29-06a - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
Effective Date
15-Sep-2006
Refers
ASTM E29-06 - Standard Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications
Effective Date
01-May-2006

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ASTM D1353-13(2021) - Standard Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related ProductsASTM D1353-13(2021) - Standard Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products
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ASTM D1353-13(2021) - Standard Test Method for Nonvolatile Matter in Volatile Solvents for Use in Paint, Varnish, Lacquer, and Related Products
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This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: D1353 − 13 (Reapproved 2021)
Standard Test Method for
Nonvolatile Matter in Volatile Solvents for Use in Paint,
Varnish, Lacquer, and Related Products
This standard is issued under the fixed designation D1353; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope 2. Referenced Documents
2.1 ASTM Standards:
1.1 This test method covers the determination of the non-
E29 Practice for Using Significant Digits in Test Data to
volatile matter in volatile solvents for use in paint, varnish,
Determine Conformance with Specifications
lacquer, and related products.
E177 Practice for Use of the Terms Precision and Bias in
1.2 The following applies to all specified limits in this
ASTM Test Methods
standard; for purposes of determining conformance with this
E299 Test Method for Trace Amounts of Peroxides In
standard, an observed value or a calculated value shall be
Organic Solvents
rounded off “to the nearest unit” in the last right-hand digit
E691 Practice for Conducting an Interlaboratory Study to
used in expressing the specification limit, in accordance with
Determine the Precision of a Test Method
the rounding-off method of Practice E29.
3. Significance and Use
1.3 The values stated in SI units are to be regarded as
standard. No other units of measurement are included in this 3.1 This test method describes the analytical measurement
of residual matter in solvents that are intended to be 100 %
standard.
volatile at 105 °C 6 5 °C. Volatile solvents are used in the
1.4 For hazard information and guidance, see the supplier’s
manufacture of paint, varnish, lacquer, and other related
Material Safety Data Sheet for materials listed in this test
products, and the presence of any residue may affect the
method.
product quality or efficiency of the process. This test method is
useful in manufacturing control and assessing compliance with
1.5 This standard does not purport to address all of the
specifications.
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
4. Apparatus
priate safety, health, and environmental practices and deter-
mine the applicability of regulatory limitations prior to use.
4.1 Oven, thermostatically controlled at 105 °C 6 5 °C.
For specific hazard statements, see Section 5.
4.2 Dish, evaporating, platinum, 125-mL. A platinum
1.6 This international standard was developed in accor-
evaporating dish is preferred. Alternatively, an aluminum or
dance with internationally recognized principles on standard-
porcelain dish may be used (see Note 1).
ization established in the Decision on Principles for the
NOTE 1—Precision data were determined utilizing only platinum
Development of International Standards, Guides and Recom-
dishes.
mendations issued by the World Trade Organization Technical
Barriers to Trade (TBT) Committee.
4.3 Cylinder, graduated, 100-mL.
4.4 Analytical Balance, precision to 60.1 mg.
This test method is under the jurisdiction of ASTM Committee D01 on Paint
and Related Coatings, Materials, andApplications and is the direct responsibility of
Subcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates. For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Current edition approved July 1, 2021. Published August 2021. Originally contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
approved in 1954. Last previous edition approved in 2013 as D1353 – 13. DOI: Standards volume information, refer to the standard’s Document Summary page on
10.1520/D1353-13R21. the ASTM website.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States
D1353 − 13 (2021)
5. Hazards Nonvolatile Matter in Volatile Solvents for Use in Paint,
Varnish, Lacquer, and Related Products, conducted in 2012.
5.1 Warning—Certain solvents and chemical
Eight laboratories participated in the study, testing a single
intermediates, particularly, but not only ethers and unsaturated
material. Every analyst was instructed to report duplicate test
compounds, may form peroxides during storage. These perox-
results in this study. Practice E691 was followed for the study
ides may present a violent explosion hazard when the chemi-
design; the details are given in ASTM Research Report No.
calsareevaporated.Whenperoxideformationislikelybecau
...

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4.1 This test method is useful for determining low levels of acidity, below 0.05 %, in organic compounds and hydrocarbon mixtures. The total acidity is calculated as acetic acid or milligrams of sodium hydroxide per gram of sample.  
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SCOPE
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SCOPE
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ASTM D801-02(2022)(Test Method)
Standard Test Methods for Sampling and Testing Dipentene

SIGNIFICANCE AND USE
3.1 The testing procedures described in these test methods have been in use for many years and emphasize the physical properties rather than the chemical composition of dipentene. These procedures were sufficient when dipentene was used primarily as a solvent. Currently, however, dipentene finds application as a chemical raw material and a knowledge of its chemical composition is therefore important. Test Methods D6387 describe a capillary gas chromatography method which is suitable for determining both the major and minor components found in dipentene.
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1.1 These test methods cover procedures for sampling and testing dipentene and related terpene solvents, consisting chiefly of monocyclic terpene hydrocarbons distilling above the range for turpentine.  
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4  
Detection and Removal of Separated Water  
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Appearance  
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Standard Test Method for Acetone, Methyl Acetate, and Parachlorobenzotrifluoride Content of Paints, and Coatings by Solid Phase Microextraction-Gas Chromatography

SIGNIFICANCE AND USE
5.1 In order to calculate the volatile organic content (VOC) of paints containing EPA exempt solvents, it is necessary to know the acetone, methyl acetate, or parachlorobenzotrifluoride content. This gas chromatographic test method provides a simple and direct way for measuring these solvents. Each analyte is measured with respect to a unique internal standard. For acetone, the internal standard used is acetone-d6, for methyl acetate it is methyl acetate-d3, and for PCBTF it is metachlorobenzotrifluoride (MCBTF). These unique analyte/internal standard pairs behave very nearly as single solvents with respect to evaporation rate and adsorption rate onto a coated silica fiber (SPME) but are separable on a gas chromatograph (GC) capillary column. The only critical analytical technique required for successfully performing this test method is the ability of an analyst to weigh a paint sample and internal standard, corresponding to the analyte of interest, into a septum capped vial. After weighing, solvent evaporation has no effect on the final value of the determination. Since whole paint is not injected into the gas chromatograph, the analytical system is never compromised.
SCOPE
1.1 This test method is for the determination of acetone, methyl acetate, or parachlorobenzotrifluoride (PCBTF), or combination of any of the three, in paints and coatings, by solid phase microextraction (SPME) headspace sampling, and subsequent injection into a gas chromatograph. It has been evaluated for cellulose nitrate, acrylic, and urethane solvent-borne systems. The established working range of this test method is: acetone, 28 to 90 %; methyl acetate, 12 to 22 %; parachlorobenzotrifluoride, 10 to 17 %. There is no reason to believe that it will not work outside these ranges. A minor modification of this test method would make it suitable for the analysis of the same analytes in water-borne coatings (see Note 1).
Note 1: Water-borne paints are internally standardized and diluted with water followed by addition of solid sodium chloride.  
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.  
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.  
1.4 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

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