EN ISO 16017-1:2000

Indoor, ambient and workplace air - Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography - Part 1: Pumped sampling (ISO 16017-1:2000)

This part of ISO 16017 gives general guidance for the sampling and analysis of volatile organic compounds (VOCs)
in air. It is applicable to ambient, indoor and workplace atmospheres and the assessment of emissions from
materials in small- or full-scale test chambers.
This part of ISO 16017 is appropriate for a wide range of VOCs, including hydrocarbons, halogenated hydrocarbons,
esters, glycol ethers, ketones and alcohols. A number of sorbents 1) are recommended for the sampling of
these VOCs, each sorbent having a different range of applicability. Very polar compounds will generally require
derivatization, very low boiling compounds will only be partially retained by the sorbents, depending on ambient
temperature, and can only be estimated qualitatively. Semi-volatile compounds will be fully retained by the
sorbents, but may only be partially recovered. Compounds for which this part of ISO 16017 has been tested are
given in tables. This part of ISO 16017 may be applicable to compounds not listed, but in these cases it is
advisable to use a back-up tube containing the same or a stronger sorbent.
This part of ISO 16017 is applicable to the measurement of airborne vapours of VOCs in a concentration range of
approximately 0,5 _g/ m3 to 100 mg/m3 individual compound.
The upper limit of the useful range is set by the sorptive capacity of the sorbent used and by the linear dynamic
range of the gas chromatograph column and detector or by the sample-splitting capability of the analytical
instrumentation used. The sorptive capacity is measured as a breakthrough volume of air, which determines the
maximum air volume that shall not be exceeded when sampling.
The lower limit of the useful range depends on the noise level of the detector and on blank levels of analyte and/or
interfering artefacts on the sorbent tubes. Artefacts are typically sub-nanogram for well-conditioned Tenax GR and
carbonaceous sorbents such as Carbopack/Carbotrap type materials, carbonized molecular sieves and molecular
sieves such as Spherocarb, or pure charcoal; at low nanogram levels for Tenax TA and at 5 ng to 50 ng levels for
other porous polymers such as Chromosorbs and Porapaks. Sensitivity is typically limited to 0,5 _g/m_ for 10-litre
air samples with this latter group of sorbents because of their inherent high background.
The procedure specified in this part of ISO 16017 is applicable to low flowrate personal sampling pumps and gives
a time-weighted average result. It is not applicable to the measurement of instantaneous or short-term fluctuations
in concentration.
1) The sorbents listed in annex C and elsewhere in this International Standard are those known to perform as specified under
this part of ISO 16017. Each sorbent or product that is identified by a trademarked name is unique and has a sole manufacturer;
however, they are widely available from many different suppliers. This information is given for the convenience of users of this
part of ISO 16017 and does not constitute an endorsement by ISO of the product named. Equivalent products may be used if
they can be shown to lead to the same results.

Innenraumluft, Außenluft und Luft am Arbeitsplatz - Probenahme und Analyse flüchtiger organischer Verbindungen durch Sorptionsröhrchen/thermische Desorption/Kapillar-Gaschromatographie - Teil 1: Probenahme mit einer Pumpe (ISO 16017-1:2000)

Dieser Teil der ISO 16017 gibt allgemeine Hinweise für die Probenahme und Analyse flüchtiger organischer Verbindungen (VOC) in der Luft. Die Internationale Norm ist anwendbar für Außenluft, Innenraumluft und Luft am Arbeitsplatz und für die Bewertung von Emissionen aus Materialien in kleinen Prüfkammern oder Prüfräumen. Diese Internationale Norm ist für eine große Bandbreite von VOC, einschließlich Kohlenwasserstoffen, halogenierten Kohlen-wasserstoffen, Estern, Glykolethern, Ketonen und Alkoholen, anwendbar. Eine Vielzahl an Sorbenzien 1 ) wird für die Probe-nahme dieser VOC empfohlen; jedes Sorbenz hat einen unterschiedlichen Anwendungsbereich. Sehr polare Verbindungen er-fordern im allgemeinen eine Derivatisierung. Verbindungen mit sehr niedrigem Siedepunkt werden - in Abhängigkeit von den Außentemperaturen - nur partiell von den Sorbenzien zurückgehalten und können nur qualitativ abgeschätzt werden. Semi-flüchtige Verbindungen werden vollständig durch die Sorbenzien zurückgehalten, können aber nur zum Teil wiedergefunden werden. Die Verbindungen, die im Rahmen dieses Teils der ISO 16017 geprüft wurden, sind in den Tabellen aufgeführt. Die Interna-tionale Norm kann auch zur Bestimmung nicht aufgeführter Verbindungen angewendet werden; in diesen Fällen ist es aber rat-sam, ein Sicherheitsröhrchen am Ende der Probenahmeapparatur mit dem gleichen oder einem stärkeren Sorbenz zu ver-wenden.
Dieser Teil der ISO 16017 ist anwendbar für die Messung von luftgetragenen VOC-haltigen Dämpfen im Konzentrations-bereich
von ungefähr 0,5 microg/m - bis 100 mg/m 3 für jede einzelne Verbindung. Die obere Nachweisgrenze eines sinnvollen Anwendungsbereiches wird durch die Sorptionskapazität des verwendeten Sorbenz und durch den linearen dynamischen Bereich der Gaschromatographiesäule und des Detektors oder durch die Beschaffenheit des Probensplits in dem verwendeten analytischen Gerät festgelegt...(Abgeschnitten)

Air intérieur, air ambiant et air des lieux de travail -Echantillonnage et analyse des composés organiques volatils par tube à adsorption/désorption thermique/chromatographie en phase gazeuse sur capillaire - Partie 1: Echantillonnage par pompage (ISO 16017-1:2000)

La présente partie de l'ISO 16017 donne des lignes directrices générales portant sur l'échantillonnage et l'analyse
des composés organiques volatils (COV) dans l'air. Elle est applicable aux atmosphères ambiantes, à l'intérieur
des bâtiments et sur les lieux de travail, ainsi qu'à l'évaluation des émissions par des matériaux dans des
chambres d'essai de petite taille ou en grandeur réelle.
La présente partie de l'ISO 16017 convient à un grand nombre de COV, y compris les hydrocarbures, les
hydrocarbures halogénés, les esters, les éthers de glycol, les cétones et les alcools. Certains adsorbants1) sont
recommandés pour l'échantillonnage de ces COV, chaque adsorbant ayant des applications particulières. Les
composés fortement polaires doivent généralement être dérivés; les composés à point d'ébullition très bas sont
seulement partiellement retenus par les adsorbants, selon la température ambiante, et leur évaluation ne peut être
que qualitative. En revanche, les composés semi-volatils sont totalement retenus par les adsorbants mais ne
peuvent être que partiellement récupérables. Les composés pour lesquels la présente partie de l'ISO 16017 a fait
l'objet d'essais sont indiqués dans les tableaux. La présente partie de l'ISO 16017 peut s'appliquer à des
composés non cités, mais dans ce cas il est conseillé de prévoir un tube avec une deuxième plage contenant le
même adsorbant, ou un adsorbant plus puissant.
La présente partie de l'ISO 16017 est applicable au mesurage des vapeurs de COV en suspension dans l'air dans
une étendue de concentrations des composés organiques individuels comprise entre 0,5 μg/m3 et 100 mg/m3
environ.
La limite supérieure de l'étendue utile est déterminée par la capacité d'adsorption de l'adsorbant utilisé et par
l'étendue dynamique linéaire de la colonne et du détecteur du chromatographe en phase gazeuse ou par la
capacité de séparation des échantillons des instruments d'analyse utilisés. La capacité d'adsorption est mesurée
sous forme d'un volume de claquage de l'air qui détermine le volume d'air maximal ne devant pas être dépassé
lors de l'échantillonnage.
La limite inférieure de l'étendue utile dépend du niveau de bruit du détecteur et des niveaux à blanc de l'analyte
et/ou des artefacts d'interférences sur les tubes à adsorption. Ces artefacts sont généralement d'un ordre inférieur
au nanogramme pour les Tenax GR et les adsorbants carbonés tels que les matériaux de type
Carbopack/Carbotrap, les tamis moléculaires au carbone et les tamis moléculaires tels que le Spherocarb, ou le
charbon pur; ils correspondent à de faibles niveaux de l'ordre du nanogramme pour le Tenax TA et au niveau situé
1) Les adsorbants cités à l'annexe C et ailleurs dans la présente partie de l'ISO 16017 sont ceux qui ont un comportement
connu pour être conforme à la présente partie de l'ISO 16017. Chaque adsorbant ou produit identifié par un nom de marque
commerciale est unique et est produit par un seul fabricant; il peut cependant être disponible auprès de plusieurs fournisseurs.
Cette information est donnée à l'intention des utilisateurs de la présente partie de l'ISO 16017 et ne signifie nullement que l'ISO
approuve ou recommande l'emploi exclusif des produits ainsi désignés. Des produits équivalents peuvent être utilisés s'il est
démontré qu'ils conduisent aux mêmes résultats.
entre 5 ng et 50 ng pour les autres polymères poreux tels que les Chromosorbs et les Porapaks. La sensibilité est
généralement limitée à 0,5 μg/m3 pour des écha

Notranji in zunanji zrak ter zrak na delovnem mestu - Vzorčenje in analiza hlapnih organskih spojin z absorpcijskimi cevkami in kapilarno plinsko kromatografijo s toplotno desorpcijo - 1. del: Vzorčenje s črpanjem (ISO 16017–1.2000)

General Information

• Status: Published
• Publication Date: 14-Nov-2000
• ICS: 13.040.01 - Air quality in general
• Technical Committee: CEN/TC 264 - Air quality
• Drafting Committee: CEN/TC 264 - Air quality
• Current Stage: 9093 - Decision to confirm - Review Enquiry
• Start Date: 15-Mar-2011
• Completion Date: 15-Mar-2011
• Ref Project: SIST EN ISO 16017-1:2002 - Indoor, ambient and workplace air - Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography - Part 1: Pumped sampling (ISO 16017-1:2000)

Standards Content (Sample)

SLOVENSKI STANDARD
01-maj-2002
1RWUDQMLLQ]XQDQML]UDNWHU]UDNQDGHORYQHPPHVWX9]RUþHQMHLQDQDOL]DKODSQLK
RUJDQVNLKVSRMLQ]DEVRUSFLMVNLPLFHYNDPLLQNDSLODUQRSOLQVNRNURPDWRJUDILMRV
WRSORWQRGHVRUSFLMRGHO9]RUþHQMHVþUSDQMHP,62±
Indoor, ambient and workplace air - Sampling and analysis of volatile organic
compounds by sorbent tube/thermal desorption/capillary gas chromatography - Part 1:
Pumped sampling (ISO 16017-1:2000)
Innenraumluft, Außenluft und Luft am Arbeitsplatz - Probenahme und Analyse flüchtiger
organischer Verbindungen durch Sorptionsröhrchen/thermische Desorption/Kapillar-
Gaschromatographie - Teil 1: Probenahme mit einer Pumpe

(ISO 16017-1:2000)
Air intérieur, air ambiant et air des lieux de travail -Echantillonnage et analyse des
composés organiques volatils par tube a adsorption/désorption
thermique/chromatographie en
phase gazeuse sur capillaire - Partie 1: Echantillonnage par pompage (ISO 16017-
1:2000)
Ta slovenski standard je istoveten z: EN ISO 16017-1:2000
ICS:
13.040.01 Kakovost zraka na splošno Air quality in general
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

INTERNATIONAL ISO
STANDARD 16017-1
First edition
2000-11-15
Indoor, ambient and workplace air —
Sampling and analysis of volatile organic
compounds by sorbent tube/thermal
desorption/capillary gas
chromatography —
Part 1:
Pumped sampling
Air intérieur, air ambiant et air des lieux de travail — Échantillonnage et
analyse des composés organiques volatils par tube à
adsorption/désorption thermique/chromatographie en phase gazeuse sur
capillaire —
Partie 1: Échantillonnage par pompage
Reference number
ISO 16017-1:2000(E)
©
ISO 2000
ISO 16017-1:2000(E)
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ISO 16017-1:2000(E)
Contents Page
Foreword.iv
1 Scope .1
2 Normative references .2
3 Terms and definitions .2
4 Principle.3
5 Reagents and materials .3
6 Apparatus .5
7 Sample tube conditioning.6
8 Calibration of pump.7
9 Sampling.7
10 Procedure .8
10.1 Safety precautions.8
10.2 Desorption and analysis .8
10.3 Calibration .9
10.4 Determination of sample concentration.10
10.5 Determination of desorption efficiency.10
11 Calculations.10
11.1 Mass concentration of analyte .10
11.2 Volume concentration of analyte .11
12 Interferences .11
13 Performance characteristics .11
14 Test report .12
15 Quality control.12
Annex A (normative) Determination of breakthrough volumes from gas standards.21
Annex B (normative) Determination of breakthrough volume from the extrapolated retention volume.22
Annex C (informative) Description of sorbent types .23
Annex D (informative) Guidance on sorbent selection .24
Annex E (informative) Guidance on sorbent use .25
Annex F (informative) Summary of data on overall uncertainty, precision, bias and storage.26
Bibliography.28
ISO 16017-1:2000(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO
member bodies). The work of preparing International Standards is normally carried out through ISO technical
committees. Each member body interested in a subject for which a technical committee has been established has
the right to be represented on that committee. International organizations, governmental and non-governmental, in
liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical
Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 3.
Draft International Standards adopted by the technical committees are circulated to the member bodies for voting.
Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this part of ISO 16017 may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights.
International Standard ISO 16017-1 was prepared by Technical Committee ISO/TC 146, Air quality, Subcommittee
SC 6, Indoor air.
ISO 16017 consists of the following parts, under the general title Indoor, ambient and workplace air — Sampling
and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography:
� Part 1: Pumped sampling
� Part 2: Diffusive sampling
Annexes A and B form a normative part of this part of ISO 16017. Annexes C through F are for information only.
iv © ISO 2000 – All rights reserved

INTERNATIONAL STANDARD ISO 16017-1:2000(E)
Indoor, ambient and workplace air — Sampling and analysis of
volatile organic compounds by sorbent tube/thermal
desorption/capillary gas chromatography —
Part 1:
Pumped sampling
1 Scope
This part of ISO 16017 gives general guidance for the sampling and analysis of volatile organic compounds (VOCs)
in air. It is applicable to ambient, indoor and workplace atmospheres and the assessment of emissions from
materials in small- or full-scale test chambers.
This part of ISO 16017 is appropriate for a wide range of VOCs, including hydrocarbons, halogenated hydro-
1)
carbons, esters, glycol ethers, ketones and alcohols. A number of sorbents are recommended for the sampling of
these VOCs, each sorbent having a different range of applicability. Very polar compounds will generally require
derivatization, very low boiling compounds will only be partially retained by the sorbents, depending on ambient
temperature, and can only be estimated qualitatively. Semi-volatile compounds will be fully retained by the
sorbents, but may only be partially recovered. Compounds for which this part of ISO 16017 has been tested are
given in tables. This part of ISO 16017 may be applicable to compounds not listed, but in these cases it is
advisable to use a back-up tube containing the same or a stronger sorbent.
This part of ISO 16017 is applicable to the measurement of airborne vapours of VOCs in a concentration range of
3 3
approximately 0,5�g/ m to 100 mg/m individual compound.
The upper limit of the useful range is set by the sorptive capacity of the sorbent used and by the linear dynamic
range of the gas chromatograph column and detector or by the sample-splitting capability of the analytical
instrumentation used. The sorptive capacity is measured as a breakthrough volume of air, which determines the
maximum air volume that shall not be exceeded when sampling.
The lower limit of the useful range depends on the noise level of the detector and on blank levels of analyte and/or
interfering artefacts on the sorbent tubes. Artefacts are typically sub-nanogram for well-conditioned Tenax GR and
carbonaceous sorbents such as Carbopack/Carbotrap type materials, carbonized molecular sieves and molecular
sieves such as Spherocarb, or pure charcoal; at low nanogram levels for Tenax TA and at 5 ng to 50 ng levels for
�
other porous polymers such as Chromosorbs and Porapaks. Sensitivity is typically limited to 0,5 �g/m for 10-litre
air samples with this latter group of sorbents because of their inherent high background.
The procedure specified in this part of ISO 16017 is applicable to low flowrate personal sampling pumps and gives
a time-weighted average result. It is not applicable to the measurement of instantaneous or short-term fluctuations
in concentration.
1) The sorbents listed in annex C and elsewhere in this International Standard are those known to perform as specified under
this part of ISO 16017. Each sorbent or product that is identified by a trademarked name is unique and has a sole manufacturer;
however, they are widely available from many different suppliers. This information is given for the convenience of users of this
part of ISO 16017 and does not constitute an endorsement by ISO of the product named. Equivalent products may be used if
they can be shown to lead to the same results.
ISO 16017-1:2000(E)
2 Normative references
The following normative documents contain provisions which, through reference in this text, constitute provisions of
this part of ISO 16017. For dated references, subsequent amendments to, or revisions of, any of these publications
do not apply. However, parties to agreements based on this part of ISO 16017 are encouraged to investigate the
possibility of applying the most recent editions of the normative documents indicated below. For undated
references, the latest edition of the normative document referred to applies. Members of ISO and IEC maintain
registers of currently valid International Standards.
ISO 5725-1:1994, Accuracy (trueness and precision) of measurement methods and results — Part 1: General
principles and definitions.
ISO 5725-2:1994, Accuracy (trueness and precision) of measurement methods and results — Part 2: Basic method
for the determination of repeatability and reproducibility of a standard measurement method.
ISO 6141:2000, Gas analysis — Requirements for certificates for calibration gases and gas mixtures.
ISO 6145-1:1986, Gas analysis — Preparation of calibration gas mixtures using dynamic volumetric methods —
Part 1: Methods of calibration.
ISO 6145-3:1986, Gas analysis — Preparation of calibration gas mixtures — Dynamic volumetric methods —
Part 3: Periodic injections into a flowing gas stream.
ISO 6145-4:1986, Gas analysis — Preparation of calibration gas mixtures — Dynamic volumetric methods —
Part 4: Continuous injection method.
2)
ISO 6145
...