EN 16167:2012

Sludge, treated biowaste and soil - Determination of polychlorinated biphenyls (PCB) by gas chromatography with mass selective detection (GC-MS) and gas chromatography with electron-capture detection (GC-ECD)

This European Standard specifies a method for quantitative determination of seven selected polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 and PCB180) in sludge, treated biowaste and soil using GC-MS and GC-ECD (see Table 2).
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this European Standard, limit of application of 1 µg/kg (expressed as dry matter) may be achieved.
Sludge and treated biowaste may differ in properties and also in the expected contamination levels of PCBs and presence of interfering substances. These differences make it impossible to describe one general procedure. This European Standard contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.

Schlamm, behandelter Bioabfall und Boden - Bestimmung von polychlorierten Biphenylen (PCB) mittels Gaschromatographie mit massenspektrometrischer Detektion (GC-MS) und Gaschromatographie mit Elektroneneinfangdetektion (GC-ECD)

This European Standard specifies a method for quantitative determination of seven selected polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 and PCB180) in sludge, treated biowaste and soil using GC-MS and GC-ECD (see Table 2).
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this European Standard, limit of application of 1 µg/kg (expressed as dry matter) can be achieved.
Sludge and treated biowaste may differ in properties and also in the expected contamination levels of PCBs and presence of interfering substances. These differences make it impossible to describe one general procedure. This European Standard contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.

Boues, biodéchets traités et sols - Détermination des biphényles polychlorés (PCB) par chromatographie en phase gazeuse-spectrométrie de masse (CG-SM) et chromatographie en phase gazeuse avec détection par capture d'électrons (CG-DCE)

La présente Norme européenne spécifie une méthode de détermination quantitative, par CG-SM et CG ECD, de sept biphényles polychlorés choisis (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 et PCB180) dans les boues, les biodéchets traités et les sols (voir Tableau 2).
Tableau 2 - Analytes cibles de la présente Norme européenne
Analyte cible   CAS-RNa  
PCB28   2,4,4’-trichlorobiphényle   7012-37-5
PCB52   2,2’,5,5’-tétrachlorobiphényle   35693-99-3
PCB101   2,2’,4,5,5’-pentachlorobiphényle   37680-37-2
PCB118   2,3’,4,4’,5-pentachlorobiphényle   31508-00-6
PCB138   2,2’,3,4,4’,5’-hexachlorobiphényle   35056-28-2
PCB153   2,2’,4,4’,5,5’-hexachlorobiphényle   35065-27-1
PCB180   2,2’,3,4,4’,5,5’-heptachlorobiphényle   35065-29-3
a   CAS-RN   Numéro d'enregistrement CAS (Chemical Abstracts Service Registry Number)
La limite de détection dépend des composés à analyser, de l’équipement utilisé, de la qualité des produits chimiques utilisés pour l’extraction de l’échantillon et la purification de l’extrait.
Dans les conditions spécifiées dans la présente Norme européenne, une limite d'application de 1 µg/kg (exprimée sur matière sèche) peut être atteinte.
Les boues et les biodéchets traités peuvent présenter des différences en termes de propriétés, de niveaux prévus de contamination par les PCB et de présence de substances interférentes. En raison de ces différences, il est impossible de décrire un mode opératoire général. La présente Norme européenne contient des tables de décision basées sur les propriétés de l'échantillon ainsi que sur le mode opératoire d'extraction et de purification à utiliser.

Blato, obdelani biološki odpadki in tla - Določevanje polikloriranih bifenilov (PCB) s plinsko kromatografijo z masno selektivno detekcijo (GC/MS) in s plinsko kromatografijo z detekcijo z zajetjem elektronov (GC/ECD)

Ta evropski standard določa metodo za kvantitativno določevanje sedmih izbranih polikloriranih bifenilov (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 in PCB180) v blatu, obdelanih bioloških odpadkih in tleh z uporabo metod GC-MS in GC-ECD. Meja detekcije je odvisna od determinant, uporabljene opreme, kakovosti kemikalij, uporabljenih za ekstrakcijo vzorca in očiščenje izvlečka. Pod pogoji, določenimi v tem evropskem standardu, se lahko doseže meja uporabe 1 μg/kg (izraženo kot suha snov). Blato in obdelani biološki odpadki se lahko razlikujejo glede lastnosti, predvidenih stopenj onesnaženja s polikloriranimi bifenili in prisotnosti motečih snovi. Zaradi teh razlik ni možen opis enega splošnega postopka. Ta evropski standard vključuje tabele odločanja, ki temeljijo na lastnostih vzorca, in postopek za ekstrakcijo in očiščenje, ki ga je treba uporabiti.

General Information

• Status: Withdrawn
• Publication Date: 21-Aug-2012
• Withdrawal Date: 14-Aug-2018
• ICS: 13.030.01 - Wastes in general
• ICS: 13.080.10 - Chemical characteristics of soils
• Technical Committee: CEN/TC 444 - Environmental characterization
• Drafting Committee: CEN/TC 444/WG 2 - Organic analysis
• Current Stage: 9960 - Withdrawal effective - Withdrawal
• Completion Date: 15-Aug-2018
• Directive: 86/278/EEC - Protection of the environment, and in particular of the soil, when sewage sludge is used in agriculture
• Mandate: M/330 - Mandate given to CEN for the development of horizontal standards in the fields of sludge, biowaste and soil.
• Ref Project: SIST EN 16167:2013 - Sludge, treated biowaste and soil - Determination of polychlorinated biphenyls (PCB) by gas chromatography with mass selective detection (GC-MS) and gas chromatography with electron-capture detection (GC-ECD)

Relations

• Replaced By: EN 16167:2018 - Soil, treated biowaste and sludge - Determination of polychlorinated biphenyls (PCB) by gas chromatography with mass selective detection (GC-MS) and gas chromatography with electron-capture detection (GC-ECD)
• Effective Date: 22-Aug-2018

Standards Content (Sample)

2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Schlamm, behandelter Bioabfall und Boden - Bestimmung von polychlorierten Biphenylen (PCB) mittels Gaschromatographie mit Massenspektrometrie-Kopplung (GC-MS) und Gaschromatographie mit Elektroneneinfangdetektion (GC-ECD)Boues, bio-déchets traités et sols - Détermination des biphényles polychlorés (PCB) par chromatographie en phase gazeuse-spectrométrie de masse (CG-SM) et chromatographie en phase gazeuse avec détection par capture d'électrons (CG-DCE)Sludge, treated biowaste and soil - Determination of polychlorinated biphenyls (PCB) by gas chromatography with mass selective detection (GC-MS) and gas chromatography with electron-capture detection (GC-ECD)13.080.10Chemical characteristics of soils13.030.20Liquid wastes. SludgeICS:Ta slovenski standard je istoveten z:EN 16167:2012SIST EN 16167:2013en,fr,de01-februar-2013SIST EN 16167:2013SLOVENSKI
STANDARD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 16167
August 2012 ICS 13.030.01; 13.080.10 English Version
Sludge, treated biowaste and soil - Determination of polychlorinated biphenyls (PCB) by gas chromatography with mass selective detection (GC-MS) and gas chromatography with electron-capture detection (GC-ECD)
Boues, bio-déchets traités et sols - Détermination des biphényles polychlorés (PCB) par chromatographie en phase gazeuse-spectrométrie de masse (CG-SM) et chromatographie en phase gazeuse avec détection par capture d'électrons (CG-DCE)
Schlamm, behandelter Bioabfall und Boden - Bestimmung von polychlorierten Biphenylen (PCB) mittels Gaschromatographie mit massenspektrometrischer Detektion (GC-MS) und Gaschromatographie mit Elektroneneinfangdetektion (GC-ECD) This European Standard was approved by CEN on 24 May 2012.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre:
Avenue Marnix 17,
B-1000 Brussels © 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16167:2012: ESIST EN 16167:2013

Repeatability and reproducibility data . 29A.1 Materials used in the interlaboratory comparison study . 29A.2 Interlaboratory comparison results . 29Annex B (informative)
Examples for retention times of PCBs . 31Bibliography . 32 SIST EN 16167:2013

WARNING — Persons using this European Standard should be familiar with usual laboratory practice. This European Standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any national regulatory conditions. IMPORTANT — It is absolutely essential that tests conducted according to this European Standard be carried out by suitably trained staff. SIST EN 16167:2013

PCB28 2,4,4'-trichlorobiphenyl 7012-37-5 PCB52 2,2',5,5'-tetrachlorobiphenyl 35693-99-3 PCB101 2,2',4,5,5'-pentachlorobiphenyl 37680-37-2 PCB118 2,3',4,4',5-pentachlorobiphenyl 31508-00-6 PCB138 2,2',3,4,4',5'-hexachlorobiphenyl 35056-28-2 PCB153 2,2',4,4',5,5'-hexachlorobiphenyl 35065-27-1 PCB180 2,2',3,4,4',5,5'-heptachlorobiphenyl 35065-29-3 a CAS-RN Chemical Abstracts Service Registry Number. The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this European Standard, limit of application of 1 µg/kg (expressed as dry matter) can be achieved.
Sludge and treated biowaste may differ in properties and also in the expected contamination levels of PCBs and presence of interfering substances. These differences make it impossible to describe one general procedure. This European Standard contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.
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