EN ISO 15009:2013

Soil quality - Gas chromatographic determination of the content of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons - Purge-and-trap method with thermal desorption (ISO 15009:2012)

This International standard specifies a method for quantitative gas-chromatographic determination of volatile hydrocarbons, naphthalene and volatile halogenated hydrocarbons in soil. This International standard is applicable to all types of soil. NOTE In the case of unsaturated peaty soils, absorption of the extraction solution may occur. The lower limit of determination is dependent on the equipment used and the quality of the methanol grade used for the extraction of the soil sample. Under the conditions specified in this International Standard the following limits of determinations apply (expressed on basis of dry matter): Typical limit of determination when using GC-FID: Volatile aromatic hydrocarbons: 0,1 mg/kg Typical limit of determination when using GC-ECD: Volatile halogenated hydrocarbons: 0,01 mg/kg. Lower limits of determination for some compounds can be achieved by using mass spectrometry (MS) with selected ion detection.

Bodenbeschaffenheit - Gaschromatographische Bestimmung des Anteils an flüchtigen aromatischen Kohlenwasserstoffen, Naphthalin und flüchtigen Halogenkohlenwasserstoffen - Purge-und-Trap-Anreicherung mit thermischer Desorption (ISO 15009:2012)

Diese Internationale Norm legt ein quantitatives gaschromatographisches Verfahren zur Bestimmung von flüchtigen aromatischen Kohlenwasserstoffen, Naphthalin und flüchtigen Halogenkohlenwasserstoffen im Boden fest.
Diese Internationale Norm ist auf alle Bodenarten anwendbar.
ANMERKUNG   Im Fall von ungesättigten Torfböden kann es zur Absorption des Lösungsmittels kommen.
Die untere Bestimmungsgrenze ist abhängig von der verwendeten Prüfeinrichtung und dem Reinheitsgrad des Methanols, mit dem die Bodenprobe extrahiert wird.
Unter den in dieser Internationalen Norm festgelegten Bedingungen gelten folgende Bestimmungsgrenzen (bezogen auf Trockensubstanz):
a)   Typische Bestimmungsgrenzen bei Anwendung von Gaschromatographie mit Flammenionisations-detektor (GC FID):
-   für flüchtige aromatische Kohlenwasserstoffe: 0,1 mg/kg.
b)   Typische Bestimmungsgrenzen bei Anwendung von Gaschromatographie mit Elektroneneinfang¬detektor (GC ECD):
-   für flüchtige Halogenkohlenwasserstoffe: 0,01 mg/kg.
Niedrigere Bestimmungsgrenzen für einige Verbindungen können durch Anwendung der Massenspektrometrie (MS) mit selektiver Ionendetektion erreicht werden.

Qualité du sol - Détermination par chromatographie en phase gazeuse des teneurs en hydrocarbures aromatiques volatils, en naphtalène et en hydrocarbures halogénés volatils - Méthode par purge et piégeage avec désorption thermique (ISO 15009:2012)

Kakovost tal - Določevanje hlapnih aromatskih ogljikovodikov, naftalena in hlapnih halogeniranih ogljikovodikov s plinsko kromatografijo - Metoda "purge-and-trap" s toplotno desorpcijo (ISO 15009:2012)

Ta mednarodni standard opisuje metodo za določevanje hlapnih ogljikovodikov, naftalena in hlapnih halogeniranih ogljikovodikov v tleh s kvantitativno plinsko kromatografijo. Ta mednarodni standard se uporablja za vse vrste tal. OPOMBA V primeru nenasičenih šotnih tal lahko pride do absorpcije ekstrakcijske raztopine. Nižja meja določevanja je odvisna od uporabljene opreme in kakovosti stopnje metanola, ki se uporablja za ekstrakcijo vzorca tal. Pod pogoji, določenimi v tem mednarodnem standardu, se uporabljajo naslednje meje določevanj (izraženo na podlagi suhe snovi):
a) tipična meja določevanja z uporabo plinske kromatografije/plamenske ionizacijske detekcije (GC/FID):
– hlapni aromatski ogljikovodiki: 0,1 mg/kg;
b) tipična meja določevanja z uporabo plinske kromatografije/detektorja na zajetje elektronov (GC/EDC):
– hlapni halogenirani ogljikovodiki: 0,01 mg/kg.
Nižje meje določevanja za nekatere zmesi se lahko dosežejo z masno spektrometrijo (MS) z izbrano detekcijo iona.

General Information

• Status: Withdrawn
• Publication Date: 09-Apr-2013
• Withdrawal Date: 15-Mar-2016
• ICS: 13.080.10 - Chemical characteristics of soils
• Technical Committee: CEN/TC 345 - Characterization of soils
• Drafting Committee: CEN/TC 345 - Characterization of soils
• Current Stage: 9960 - Withdrawal effective - Withdrawal
• Completion Date: 16-Mar-2016
• Ref Project: SIST EN ISO 15009:2013 - Soil quality - Gas chromatographic determination of the content of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons - Purge-and-trap method with thermal desorption (ISO 15009:2012)

Relations

• Replaced By: EN ISO 15009:2016 - Soil quality - Gas chromatographic determination of the content of volatile aromatic hydrocarbons, naphthalene and volatile halogenated hydrocarbons - Purge-and-trap method with thermal desorption (ISO 15009:2016)
• Effective Date: 23-Mar-2016

Standards Content (Sample)

SLOVENSKI STANDARD
01-maj-2013
.DNRYRVWWDO'RORþHYDQMHKODSQLKDURPDWVNLKRJOMLNRYRGLNRYQDIWDOHQDLQKODSQLK
KDORJHQLUDQLKRJOMLNRYRGLNRYVSOLQVNRNURPDWRJUDILMR0HWRGDSXUJHDQGWUDSV
WRSORWQRGHVRUSFLMR,62
Soil quality - Gas chromatographic determination of the content of volatile aromatic
hydrocarbons, naphthalene and volatile halogenated hydrocarbons - Purge-and-trap
method with thermal desorption (ISO 15009:2012)
Bodenbeschaffenheit - Gaschromatographische Bestimmung des Anteils an flüchtigen
aromatischen Kohlenwasserstoffen, Naphthalin und flüchtigen
Halogenkohlenwasserstoffen - Purge-und-Trap-Anreicherung mit thermischer Desorption
(ISO 15009:2012)
Qualité du sol - Détermination par chromatographie en phase gazeuse des teneurs en
hydrocarbures aromatiques volatils, en naphtalène et en hydrocarbures halogénés
volatils - Méthode par purge et piégeage avec désorption thermique (ISO 15009:2012)
Ta slovenski standard je istoveten z: EN ISO 15009:2013
ICS:
13.080.10 .HPLMVNH]QDþLOQRVWLWDO Chemical characteristics of
soils
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EUROPEAN STANDARD
EN ISO 15009
NORME EUROPÉENNE
EUROPÄISCHE NORM
April 2013
ICS 13.080.10
English Version
Soil quality - Gas chromatographic determination of the content
of volatile aromatic hydrocarbons, naphthalene and volatile
halogenated hydrocarbons - Purge-and-trap method with
thermal desorption (ISO 15009:2012)
Qualité du sol - Détermination par chromatographie en Bodenbeschaffenheit - Gaschromatographische
phase gazeuse des teneurs en hydrocarbures aromatiques Bestimmung des Anteils an flüchtigen aromatischen
volatils, en naphtalène et en hydrocarbures halogénés Kohlenwasserstoffen, Naphthalin und flüchtigen
volatils - Méthode par purge et piégeage avec désorption Halogenkohlenwasserstoffen - Purge-und-Trap-
thermique (ISO 15009:2012) Anreicherung mit thermischer Desorption (ISO 15009:2012)
This European Standard was approved by CEN on 21 March 2013.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European
Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national
standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by translation
under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same
status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United
Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

Management Centre: Avenue Marnix 17, B-1000 Brussels
© 2013 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 15009:2013: E
worldwide for CEN national Members.

Contents Page
Foreword .3

Foreword
The text of ISO 15009:2012 has been prepared by Technical Committee ISO/TC 190 “Soil quality” of the
International Organization for Standardization (ISO) and has been taken over as EN ISO 15009:2013 by
Technical Committee CEN/TC 345 “Characterization of soils” the secretariat of which is held by NEN.
This European Standard shall be given the status of a national standard, either by publication of an identical
text or by endorsement, at the latest by October 2013, and conflicting national standards shall be withdrawn at
the latest by October 2013.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. CEN [and/or CENELEC] shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following
countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech
Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece,
Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,
Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom.
Endorsement notice
The text of ISO 15009:2012 has been approved by CEN as EN ISO 15009:2013 without any modification.

INTERNATIONAL ISO
STANDARD 15009
Second edition
2012-07-01
Soil quality — Gas chromatographic
determination of the content of
volatile aromatic hydrocarbons,
naphthalene and volatile halogenated
hydrocarbons — Purge-and-trap method
with thermal desorption
Qualité du sol — Détermination par chromatographie en phase gazeuse
des teneurs en hydrocarbures aromatiques volatils, en naphtalène et
en hydrocarbures halogénés volatils — Méthode par purge et piégeage
avec désorption thermique
Reference number
ISO 15009:2012(E)
©
ISO 2012
ISO 15009:2012(E)
All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized in any form or by any means,
electronic or mechanical, including photocopying and microfilm, without permission in writing from either ISO at the address below or ISO’s
member body in the country of the requester.
ISO copyright office
Case postale 56 • CH-1211 Geneva 20
Tel. + 41 22 749 01 11
Fax + 41 22 749 09 47
E-mail [e-mail]
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Published in Switzerland
ii © ISO 2012 – All rights reserved

ISO 15009:2012(E)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Principle . 2
4 Reagents . 2
4.1 Water, free of volatile aromatic and volatile halogenated hydrocarbons. 2
4.2 Internal standard compounds . 2
4.3 Standard compounds . 3
4.4 Methanol (CAS RN 67-56-1) . 4
4.5 Adsorbing agent . 4
4.6 Cooling water for purge and trap . 4
4.7 Inert carrier gas for the gas chromatograph . 4
4.8 Nitrogen or helium as inert gas for the purge equipment . 4
4.9 Standard solutions . 4
5 Apparatus . 5
6 Sampling, preservation and sample pretreatment . 7
6.1 General . 7
6.2 Sampling using vials prefilled with methanol . 7
6.3 Sampling using coring tube method . 7
7 Procedure . 7
7.1 Blank determination . 7
7.2 Extraction . 8
7.3 Purge and trap . 8
7.4 Gas chromatographic analysis . 8
8 Calculation .10
9 Expression of results . 11
10 Precision . 11
11 Test report . 11
Annex A (informative) Relative retention time with respect to ethylbenzene-D10 of volatile aromatic
hydrocarbons and volatile halogenated hydrocarbons on the following columns: CP-Sil 5 CB
and CP-Sil 13 CB .12
Annex B (normative) Check on internal standards .13
Annex C (informative) Validation .14
Annex D (informative) Information on purge-and-trap instruments .17
Bibliography .18
ISO 15009:2012(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies
(ISO member bodies). The work of preparing International Standards is normally carried out through ISO
technical committees. Each member body interested in a subject for which a technical committee has been
established has the right to be represented on that committee. International organizations, governmental and
non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International
Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.
The main task of technical committees is to prepare International Standards. Draft International Standards
adopted by the technical committees are circulated to the member bodies for voting. Publication as an
International Standard requires approval by at least 75 % of the member bodies casting a vote.
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent
rights. ISO shall not be held responsible for identifying any or all such patent rights.
ISO 15009 was prepared by Technical Committee ISO/TC 190, Soil quality, Subcommittee SC 3, Chemical
methods and soil characteristics.
This second edition cancels and replaces the first edition (ISO 15009:2002), which has been technically revised.
iv © ISO 2012 – All rights reserved

INTERNATIONAL STANDARD ISO 15009:2012(E)
Soil quality — Gas chromatographic determination of the
content of volatile aromatic hydrocarbons, naphthalene and
volatile halogenated hydrocarbons — Purge-and-trap method
with thermal desorption
1 Scope
This International Standard specifies a method for quantitative gas chromatographic determination of volatile
hydrocarbons, naphthalene and volatile halogenated hydrocarbons in soil.
This International Standard is applicable to all types of soil.
NOTE In the case of unsaturated peaty soils, absorption of the extraction solution may occur.
The lower limit of determination is dependent on the equipment used and the
...