EN ISO 23702-1:2018

Leather - Organic fluorine - Part 1: Determination of non-volatile compounds by extraction method using liquid chromatography/tandem mass spectrometry detector (LC-MS/MS) (ISO 23702-1:2018)

This document specifies a test method for detection and quantification of extractable neutral, ionic, long, medium and short chain perfluorinated and poly-fluorinated substances in leather and coated leather.
This document, taking into account the three-dimensional distribution of the fibres within leather, makes the evaluation of the perfluorinated and poly-fluorinated substances with respect to the mass.
Classes of regulated compounds listed in Annex A, Table A.1, include acids, telomers, sulfonates and sulphonamide alcohols. Classes of other non-regulated compounds that can be determined by this document are defined in Annex B, Table B.1.

Leder - Organisches Fluor - Teil 1: Bestimmung der nichtflüchtigen Verbindungen durch ein Extraktionsverfahren mit Flüssigkeitschromatographie/Tandem-Massenspektrometrie-Detektor (LC-MS/MS) (ISO 23702-1:2018)

Diese Norm legt ein Prüfverfahren für den Nachweis und die quantitative Bestimmung von extrahierbaren, neutralen, ionischen perfluorierten und polyfluorierten Substanzen mit kurzer und mittlerer Kettenlänge in Leder fest.
Unter Berücksichtigung der dreidimensionalen Faserverteilung innerhalb des Leders bewertet diese Norm die perfluorierten und polyfluorierten Substanzen im Hinblick auf die Masse.
Die in Tabelle A.1 des normativen Anhangs A angeführten Klassen der regulierten Verbindungen schließen Säuren, Telomere, Sulfonate und Sulfonamidalkohole ein. Die Klassen anderer, nicht regulierteer Verbindungen, die mit dieser Norm bestimmt werden können, sind in Anhang B, Tabelle B.1 festgelegt.

Cuir - Fluor organique - Partie 1: Détermination de la teneur en composés non volatils par une méthode d'extraction utilisant la chromatographie en phase liquide couplée à un détecteur par spectrométrie de masse en tandem (LC-MS/MS) (ISO 23702-1:2018)

Le présent document spécifie une méthode d'essai de détection et de quantification de substances perfluorées et polyfluorées neutres, ioniques, à chaîne longue, moyenne et courte, extractibles dans le cuir et le cuir verni.
Le présent document, tenant compte de la distribution tridimensionnelle des fibres dans le cuir, réalise l'évaluation des substances perfluorées et polyfluorées par rapport à la masse.
Les classes de composés réglementés répertoriés dans le Tableau A.1 de l'Annexe A comprennent des acides, des télomères, des sulfonates et des alcools sulfonamides. Les classes d'autres composés non réglementés qui peuvent être déterminés par le présent document sont définies dans le Tableau B.1 de l'Annexe B.

Usnje - Organski fluor - 1. del: Določevanje nehlapnih spojin z metodo ekstrakcije z uporabo tekoče kromatografije/tandemski masni spektrometer (LC-MS/MS) (ISO 23702-1:2018)

Ta dokument določa preskusno metodo za odkrivanje in kvantifikacijo izločljivih nevtralnih, ionskih, dolgoverižnih, srednjeverižnih in kratkoverižnih perfluoriranih in polifluoriranih snovi v usnju in premazanem usnju.
Ta dokument, upoštevajoč tridimenzionalno porazdelitev vlaken v usnju, vrednoti perfluorirane in polifluorirane snovi glede na maso.
Razredi predpisanih spojin, navedenih v preglednici A.1 dodatka A, vključujejo kisline, telomerje, sulfonate in sulfonamid alkohole. Razredi drugih nepredpisanih spojin, ki jih je mogoče določiti s tem dokumentov, so opredeljeni v preglednici B.1 dodatka B.

General Information

• Status: Withdrawn
• Publication Date: 20-Nov-2018
• Withdrawal Date: 27-Jun-2023
• ICS: 59.140.30 - Leather and furs
• Technical Committee: CEN/TC 289 - Leather
• Drafting Committee: CEN/TC 289/WG 1 - Chemical test methods
• Ref Project: SIST EN ISO 23702-1:2019 - Leather - Organic fluorine - Part 1: Determination of non-volatile compounds by extraction method using liquid chromatography/tandem mass spectrometry detector (LC-MS/MS) (ISO 23702-1:2018)

Relations

• Replaced By: EN ISO 23702-1:2023 - Leather - Per- and polyfluoroalkyl substances - Part 1: Determination of non-volatile compounds by extraction method using liquid chromatography (ISO 23702-1:2023)
• Effective Date: 21-Jul-2021

Standards Content (Sample)

SLOVENSKI STANDARD
01-januar-2019
8VQMH2UJDQVNLIOXRUGHO'RORþHYDQMHQHKODSQLKVSRMLQ]PHWRGRHNVWUDNFLMH
]XSRUDERWHNRþHNURPDWRJUDILMHWDQGHPVNLPDVQLVSHNWURPHWHU/&0606,62

Leather - Organic fluorine - Part 1: Determination of non-volatile compounds by
extraction method using liquid chromatography/tandem mass spectrometry detector (LC-
MS/MS) (ISO 23702-1:2018)
Leder - Organisches Fluor - Teil 1: Bestimmung der nichtflüchtigen Verbindungen durch
ein Extraktionsverfahren mit Flüssigkeitschromatographie/Tandem-Massenspektrometrie
-Detektor (LC-MS/MS) (ISO 23702-1:2018)
Cuir - Fluor organique - Partie 1: Détermination de la teneur en composés non volatils
par une méthode d'extraction utilisant la chromatographie en phase liquide couplée à un
détecteur par spectrométrie de masse en tandem (LC-MS/MS) (ISO 23702-1:2018)
Ta slovenski standard je istoveten z: EN ISO 23702-1:2018
ICS:
59.140.30 Usnje in krzno Leather and furs
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 23702-1
EUROPEAN STANDARD
NORME EUROPÉENNE
November 2018
EUROPÄISCHE NORM
ICS 59.140.30
English Version
Leather - Organic fluorine - Part 1: Determination of non-
volatile compounds by extraction method using liquid
chromatography/tandem mass spectrometry detector (LC-
MS/MS) (ISO 23702-1:2018)
Cuir - Fluor organique - Partie 1: Détermination de la Leder - Organisches Fluor - Teil 1: Bestimmung der
teneur en composés non volatils par une méthode nichtflüchtigen Verbindungen durch ein
d'extraction utilisant la chromatographie en phase Extraktionsverfahren mit
liquide couplée à un détecteur par spectrométrie de Flüssigkeitschromatographie/Tandem-
masse en tandem (LC-MS/MS) (ISO 23702-1:2018) Massenspektrometrie-Detektor (LC-MS/MS) (ISO
23702-1:2018)
This European Standard was approved by CEN on 3 October 2018.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 23702-1:2018 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 23702-1:2018) has been prepared by Technical Committee IULTCS
"International Union of Leather Technologists and Chemists Societies" in collaboration with Technical
Committee CEN/TC 289 “Leather” the secretariat of which is held by UNI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by May 2019, and conflicting national standards shall be
withdrawn at the latest by May 2019.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 23702-1:2018 has been approved by CEN as EN ISO 23702-1:2018 without any
modification.
INTERNATIONAL ISO
STANDARD 23702-1
IULTCS/IUC 39-1
First edition
2018-09
Leather — Organic fluorine —
Part 1:
Determination of the non-volatile
compound content by extraction
method using liquid chromatography/
tandem mass spectrometry detector
(LC-MS/MS)
Cuir — Fluor organique —
Partie 1: Détermination de la teneur en composés non volatils par
une méthode d'extraction utilisant la chromatographie en phase
liquide couplée à un détecteur par spectrométrie de masse en tandem
(LC-MS/MS)
Reference numbers
ISO 23702-1:2018(E)
IULTCS/IUC 39-1:2018(E)
©
ISO 2018
ISO 23702-1:2018(E)
IULTCS/IUC 39-1:2018(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2018
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: [phone]
Fax: [phone]
Email: [e-mail]
Website: www.iso.org
Published in Switzerland
ii © ISO 2018 – All rights reserved

ISO 23702-1:2018(E)
IULTCS/IUC 39-1:2018(E)
Contents  Page
Foreword .iv
Introduction .v
1  Scope .1
2  Normative references .1
3  Terms and definitions .1
4  Principle . 2
5  Reagents . 2
6  Apparatus . 3
7  Testing procedure . 4
7.1 Sampling and preparation of the sample . 4
7.2 Extraction procedure . 4
7.2.1 Extraction . 4
7.2.2 Interferences . 4
7.3 Analytical procedure . 4
8  Calculation and expression of results . 5
8.1 Calibration curve . 5
8.2 Calculation of the result . 5
9  Precision . 5
10  Test report . 6
Annex A (informative) Classes of highly fluorinated regulated compounds determinable by
this document . 7
Annex B (informative) Other relevant compounds of concern .8
Annex C (informative) LC-MS/MS chromatographic conditions .9
Annex D (informative) Interferences .16
Annex E (informative) Accuracy .17
Bibliography .19
ISO 23702-1:2018(E)
IULTCS/IUC 39-1:2018(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
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ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/patents).
Any trade name used in this document is information given for the convenience of users and does not
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For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
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.org/iso/foreword .html.
This document was prepared by the Chemical Test Commission of the International Union of Leather
Technologists and Chemists Societies (IUC Commission, IULTCS) in collaboration with the European
Committee for Standardization (CEN) Technical Committee CEN/TC 289, Leather, the secretariat of
which is held by UNI, in accordance with the Agreement on technical cooperation between ISO and CEN
(Vienna Agreement).
IULTCS, originally formed in 1897, is a world-wide organization of professional leather societies to
further the advancement of leather
...