EN 12122:2005
(Main)Chemicals used for treatment of water intended for human consumption - Ammonia solution
Chemicals used for treatment of water intended for human consumption - Ammonia solution
This European Standard is applicable to ammonia solution used for treatment of water intended for human consumption. It describes the characteristics and specifies the requirements of ammonia solution and refers to the corresponding analytical methods. It gives information for its use in water treatment. It also determines the rules relating to safe handling and use of ammonia solution (see Annex B).
Produkte zur Aufbereitung von Wasser für den menschlichen Gebrauch - Ammoniaklösung
Diese Europäische Norm gilt für Ammoniaklösung zur Aufbereitung von Wasser für den menschlichen
Gebrauch. Sie beschreibt die Eigenschaften von Ammoniaklösung, legt die Anforderungen an
Ammoniaklösung fest und verweist auf die entsprechenden Analysenverfahren. Sie gibt Informationen für die
Anwendung von Ammoniaklösung in der Wasseraufbereitung. Sie legt darüber hinaus Regeln für die sichere
Handhabung und Benutzung von Ammoniaklösung fest (siehe Anhang B).
Produits chimiques utilisés pour le traitement de l'eau destinée à la consommation humaine - Ammoniaque
Le présent document s�applique à l�ammoniaque utilisée pour le traitement de l�eau destinée à consommation
humaine. Il décrit les caractéristiques et spécifie les exigences et les méthodes d'analyses correspondantes
applicables à l�ammoniaque. Il donne des informations pour son emploi dans le traitement de l'eau. Il fixe
également les règles relatives à la sécurité d�emploi et de manipulation de l�ammoniaque (voir Annexe B).
Kemikalije, ki se uporabljajo za pripravo pitne vode - Raztopina amonijaka
General Information
Relations
Standards Content (Sample)
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.Kemikalije, ki se uporabljajo za pripravo pitne vode - Raztopina amonijakaProdukte zur Aufbereitung von Wasser für den menschlichen Gebrauch - AmmoniaklösungProduits chimiques utilisés pour le traitement de l'eau destinée a la consommation humaine - AmmoniaqueChemicals used for treatment of water intended for human consumption - Ammonia solution71.100.80Chemicals for purification of water13.060.20Pitna vodaDrinking waterICS:Ta slovenski standard je istoveten z:EN 12122:2005SIST EN 12122:2005en01-september-2005SIST EN 12122:2005SLOVENSKI
STANDARDSIST EN 12122:20001DGRPHãþD
EUROPEAN STANDARD NORME EUROPÉENNE EUROPÄISCHE NORM
EN 12122
June 2005 ICS 71.100.80 Supersedes EN 12122:1998 English version
Chemicals used for treatment of water intended for human consumption - Ammonia solution
Produits chimiques utilisés pour le traitement de l'eau destinée à la consommation humaine - Ammoniaque
Produkte zur Aufbereitung von Wasser für den menschlichen Gebrauch - Ammoniaklösung This European Standard was approved by CEN on 25 April 2005.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION EUROPÄISCHES KOMITEE FÜR NORMUNG
Management Centre: rue de Stassart, 36
B-1050 Brussels © 2005 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 12122:2005: ESIST EN 12122:2005
GENERAL INFORMATION ON AMMONIA SOLUTION.18 ANNEX B (NORMATIVE)
GENERAL RULES RELATING TO SAFETY.19 BIBLIOGRAPHY.20
Conformity with this European standard does not confer or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this document is subject to regulation or control by National Authorities.
Description 3.1 Identification 3.1.1 Chemical name Ammonium hydroxide. 3.1.2 Synonym or common name Ammonia solution. 3.1.3 Relative molecular mass 35,05. 3.1.4 Empirical formula NH4OH. SIST EN 12122:2005
1) Chemical Abstracts Service Registry Number. 2) European Inventory of Existing Commercial Chemical Substances. 3) 100 kPa = 1 bar. SIST EN 12122:2005
to 30 % of NH3 form explosive mixtures. Ammonia solution reacts with acids to form ammonium salts. It reacts with carbon dioxide, e.g. from air, to form carbonate. 4 Purity criteria 4.1 General This document specifies the minimum purity requirements for ammonia solution used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities. NOTE
Users of this product should check the national regulations in order to clarify whether it is of appropriate purity for treatment of water intended for human consumption, taking into account raw water quality, required dosage, contents of other impurities and additives used in the product not stated in this product standard . Limits have been given for impurities and chemical parameters where these are likely to be present in significant quantities from the current production process and raw materials. If the production process or raw materials leads to significant quantities of impurities, by-products or additives being present, this shall be notified to the user. 4.2 Composition of commercial product The commercial product shall contain at least a mass fraction of 25 % of ammonia in water. The product shall contain the stated concentration of NH3 within ± 5 %. 4.3 Impurities and main by-products Due to the manufacturing process by-products are not relevant. The product shall conform to the requirements specified in table 1. SIST EN 12122:2005
Table 1: Impurities Impurity Limit in mg/kg of the product Residue after evaporation 30 Iron (Fe) 10
4.4 Chemical parameters The product shall conform to the requirements specified in Table 2.
Table 2 – Chemical parameters
Parameter Limit mg/kg of commercial product Antimony (Sb) max. 1 Arsenic (As) max. 5 Cadmium (Cd) max. 0,5 Chromium (Cr) max. 5 Lead (Pb) max. 5 Mercury (Hg) max. 0,1 Nickel (Ni) max. 5 Selenium (Se) max. 2 NOTE : Pesticides and polycyclic aromatic hydrocarbons and cyanides are not relevant in ammonia solution because the raw materials used in the manufacturing are free of them. For parametric values of ammonia solution on trace metal content in drinking water, see [1].
5 Test methods 5.1 Sampling Observe the general recommendations of ISO 3165 and take account of ISO 6206 and see [3]. SIST EN 12122:2005
b) take the sample required in a bottle fitted with an internal solid screw-stopper and rubber gasket. Tighten the stopper as soon as the sample is in the bottle.
5.1.2 Sampling from drums, carboys and bottles General : Do not use suction during the withdrawal of the sample, especially with concentrated solutions, since reduction of pressure readily depletes the solution of ammonia gas. 5.1.2.1 Drums SAFETY PRECAUTIONS : Do not use compressed air to discharge ammonia solution from drums. Sample from drums by pouring, by siphoning or by means of a polyethylene or polypropylene sampling 'thief'. If the sample is to be obtained from pouring, use a specially constructed elevated platform to hold the drum, and a screw-in pourer and funnel to facilitate transfer and reduce the risk from splashing. If the sample is to be obtained by siphoning, use a suitable siphon constructed from stainless steel, polyethylene, polypropylene or glass. Start the siphon by applying a slight air pressure to the drum, e.g. from a hand bellows or bulb, provided that the end of the delivery tube is below the level of liquid in the drum. If a polyethylene or polypropylene sampling 'thief' is used to draw the sample, use the procedure described in 5.1.1. 5.1.2.2 Carboys SAFETY PRECAUTIONS : Do not use compressed air to discharge ammonia solution from carboys. Sample from carboys by pouring, by siphoning, by the use of a polyethylene or polypropylene sampling 'thief'' or by the use of a hand-operated pump. If the sample is to be obtained by pouring, use a properly constructed carboy tilter.
NOTE :
Polyethylene or polypropylene siphons incorporating bell
...
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