Paints and varnishes - Wettability - Part 2: Determination of the surface free energy of solid surfaces by measuring the contact angle (ISO 19403-2:2024)

ISO 19403-2:2017 specifies a test method to measure the contact angle for the determination of the surface free energy of a solid surface. The method can be applied for the characterization of substrates and coatings.
NOTE 1 For the determination of the surface free energy of polymers and coatings, either the method in accordance with Owens, Wendt, Rabel and Kaelble or the method in accordance with Wu is used preferably.
NOTE 2 The morphological and chemical homogeneity have an influence on the measuring results.
NOTE 3 The procedures indicated in ISO 19403-2:2017 are based on the state-of-the-art employing the drop projection method in penumbral shadow. Other methods are not excluded.
NOTE 4 Measuring the contact angle on powders is not part of ISO 19403-2:2017. For further information, see the bibliography.

Beschichtungsstoffe - Benetzbarkeit - Teil 2: Bestimmung der freien Oberflächenenergie fester Oberflächen durch Messung des Kontaktwinkels (ISO 19403-2:2024)

Dieses Dokument legt ein Prüfverfahren zum Messen des Kontaktwinkels für die Bestimmung der freien Oberflächenenergie einer festen Oberfläche fest. Das Verfahren kann zur Charakterisierung von Substraten und Beschichtungen eingesetzt werden.
ANMERKUNG 1   Zur Bestimmung der freien Oberflächenenergie von Polymeren und Beschichtungen wird bevorzugt entweder das Verfahren nach Owens, Wendt, Rabel und Kaelble [3] [4] [5] oder das Verfahren nach Wu angewendet.
ANMERKUNG 2   Die morphologische und die chemische Homogenität haben einen Einfluss auf die Messergebnisse. Die in diesem Dokument dargestellten Vorgehensweisen basieren auf dem Stand der Technik bei der Anwendung des Tropfenprojektionsverfahrens im Halbschattenbild. Andere Verfahren sind nicht ausgeschlossen.
Die Messung des Kontaktwinkels an Pulvern ist nicht Bestandteil dieses Dokumentes.

Peintures et vernis - Mouillabilité - Partie 2: Détermination de l'énergie libre de surface des surfaces solides par la mesure de l'angle de contact (ISO 19403-2:2024)

Le présent document spécifie une méthode d'essai permettant de mesurer l'angle de contact afin de déterminer l'énergie libre de surface d'une surface solide. Cette méthode peut être utilisée pour la caractérisation de substrats et revêtements.
NOTE 1 La détermination de l'énergie libre de surface de polymères et de revêtements se fait de préférence conformément à la méthode d'Owens, Wendt, Rabel et Kaelble ou à la méthode de Wu.
NOTE 2 L'homogénéité morphologique et chimique influe sur les résultats des mesurages.
NOTE 3 Les modes opératoires indiqués dans le présent document s'appuient sur les dernières techniques connues employant la méthode de projection de la goutte dans la pénombre. Les autres méthodes ne sont pas exclues.
NOTE 4 Le mesurage de l'angle de contact sur des poudres ne fait pas partie du présent document. Pour plus d'informations, voir la Bibliographie.

Barve in laki - Omočljivost - 2. del: Določanje proste površinske energije površin trdnih teles z merjenjem stičnega kota (ISO 19403-2:2024)

General Information

Status
Published
Public Enquiry End Date
02-Dec-2023
Publication Date
10-Dec-2024
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
27-Nov-2024
Due Date
01-Feb-2025
Completion Date
11-Dec-2024

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SLOVENSKI STANDARD
01-januar-2025
Nadomešča:
SIST EN ISO 19403-2:2020
Barve in laki - Omočljivost - 2. del: Določanje proste površinske energije površin
trdnih teles z merjenjem stičnega kota (ISO 19403-2:2024)
Paints and varnishes - Wettability - Part 2: Determination of the surface free energy of
solid surfaces by measuring the contact angle (ISO 19403-2:2024)
Beschichtungsstoffe - Benetzbarkeit - Teil 2: Bestimmung der freien Oberflächenenergie
fester Oberflächen durch Messung des Kontaktwinkels (ISO 19403-2:2024)
Peintures et vernis - Mouillabilité - Partie 2: Détermination de l'énergie libre de surface
des surfaces solides par la mesure de l'angle de contact (ISO 19403-2:2024)
Ta slovenski standard je istoveten z: EN ISO 19403-2:2024
ICS:
87.040 Barve in laki Paints and varnishes
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 19403-2
EUROPEAN STANDARD
NORME EUROPÉENNE
September 2024
EUROPÄISCHE NORM
ICS 87.040 Supersedes EN ISO 19403-2:2020
English Version
Paints and varnishes - Wettability - Part 2: Determination
of the surface free energy of solid surfaces by measuring
the contact angle (ISO 19403-2:2024)
Peintures et vernis - Mouillabilité - Partie 2: Beschichtungsstoffe - Benetzbarkeit - Teil 2:
Détermination de l'énergie libre de surface des Bestimmung der freien Oberflächenenergie fester
surfaces solides par la mesure de l'angle de contact Oberflächen durch Messung des Kontaktwinkels (ISO
(ISO 19403-2:2024) 19403-2:2024)
This European Standard was approved by CEN on 17 August 2024.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2024 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 19403-2:2024 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 19403-2:2024) has been prepared by Technical Committee ISO/TC 35 "Paints
and varnishes" in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes” the
secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by March 2025, and conflicting national standards shall
be withdrawn at the latest by March 2025.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 19403-2:2020.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 19403-2:2024 has been approved by CEN as EN ISO 19403-2:2024 without any
modification.
International
Standard
ISO 19403-2
Second edition
Paints and varnishes —
2024-09
Wettability —
Part 2:
Determination of the surface
free energy of solid surfaces by
measuring the contact angle
Peintures et vernis — Mouillabilité —
Partie 2: Détermination de l'énergie libre de surface des surfaces
solides par la mesure de l'angle de contact
Reference number
ISO 19403-2:2024(en) © ISO 2024

ISO 19403-2:2024(en)
© ISO 2024
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
ISO 19403-2:2024(en)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Apparatus and materials . 2
6 Sampling . 3
7 Procedure . 3
7.1 General for measuring on the horizontal drop .3
7.1.1 Setting up the contact angle measuring system .3
7.1.2 Test conditions .4
7.1.3 Conditioning of the test panels .4
7.2 Measurement .4
7.2.1 General .4
7.2.2 Static method .4
7.2.3 Dynamic method (progressive contact angle) .5
7.2.4 Determination of the contact angle .6
8 Ev a luat ion . 6
8.1 General .6
8.2 Owens-Wendt-Rabel-Kaelble method (OWRK method) .6
8.3 Wu method .7
9 Precision . 8
9.1 General .8
9.2 Repeatability limit, r . .8
9.3 Reproducibility limit, R .8
9.4 Calculation in accordance with the Owens-Wendt-Rabel-Kaelble method .8
10 Test report . 9
Annex A (informative) Notes on measuring practice . 10
Bibliography . 14

iii
ISO 19403-2:2024(en)
Foreword
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bodies (ISO member bodies). The work of preparing International Standards is normally carried out through
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