Paints and varnishes - Determination of volatile organic compound (VOC) - Gas-chromatographic method with headspace injection for VOC determination (ISO 17895:2024)

This document specifies the sampling and testing of low volatile organic compound (VOC) coating materials and their raw materials. In particular, this document specifies a gas-chromatographic method to quantitatively determine the VOC content (i.e. the content of organic compounds with boiling points up to 250 °C) under standard conditions (101,325 kPa). It is applicable to VOC contents between 0,01 % and 0,1 % by mass.
This document does not apply to the determination of the semi-volatile organic compounds (SVOC) content, which is covered in ISO 11890-2.
This document does not apply to volatile organic and volatile inorganic compounds that cannot be determined by gas chromatography.
The procedure for identifying the appropriate method for the determination of VOC content and the SVOC content of coating materials and their raw materials is described in ISO/TR 5601.

Beschichtungsstoffe - Bestimmung des Gehaltes an flüchtigen organischen Verbindungen (VOC) - Gaschromatographisches Verfahren mit Dampfrauminjektion zur Bestimmung des Gehaltes an flüchtigen organischen Verbindungen (ISO 17895:2024)

Dieses Dokument legt die Probenahme und die Prüfung von Beschichtungsstoffen mit niedrigem VOC Gehalt und deren Rohstoffen fest. Insbesondere legt dieses Dokument ein gaschromatographisches Verfahren zur quantitativen Bestimmung des VOC Gehaltes (d. h. den Gehalt an flüchtigen organischen Verbindungen mit einem Siedepunkt von höchstens 250 °C) unter Normaldruckbedingungen (101,325 kPa) fest. Er ist für VOC Gehalte zwischen 0,01 % und 0,1 % Massenanteil anwendbar.
Dieses Dokument ist nicht für die Bestimmung des Gehaltes an schwerflüchtigen organischen Verbindungen (SVOC) anwendbar, die in ISO 11890 2 behandelt werden.
Dieses Dokument ist nicht für flüchtige organische und flüchtige anorganische Verbindungen anwendbar, die nicht mittels Gaschromatographie bestimmt werden können.
Das Verfahren zur Ermittlung des geeigneten Verfahrens zur Bestimmung des VOC-Gehaltes und des SVOC-Gehaltes von Beschichtungsstoffen und deren Rohstoffen ist in ISO/TR 5601 beschrieben.
WARNUNG — Die Anwendung dieses Dokumentes kann den Einsatz gefährlicher Stoffe, Arbeitsgänge und Geräte bedingen. Diese Norm beansprucht nicht, alle damit verbundenen Sicherheitsprobleme zu behandeln. Es liegt in der Verantwortung des Anwenders dieses Dokuments, vor der Anwendung geeignete Maßnahmen für die Sicherheit und den Gesundheitsschutz des Personals zu ergreifen und die Anwendbarkeit anderer Auflagen hinsichtlich dieses Zweckes zu bestimmen.

Peintures et vernis - Détermination de la teneur en composés organiques volatils (COV) - Méthode par chromatographie en phase gazeuse avec injection dans l'espace de tête pour la détermination des COV (ISO 17895:2024)

Le présent document spécifie l'échantillonnage et les essais relatifs aux produits de peinture à faible teneur en composés organiques volatils (COV) et à leurs matières premières. Le présent document spécifie notamment une méthode par chromatographie en phase gazeuse permettant de déterminer quantitativement la teneur en COV (c'est-à-dire la teneur en composés organiques ayant un point d'ébullition inférieur ou égal à 250 °C) dans des conditions normalisées (101,325 kPa). Cette méthode est applicable à des teneurs en COV comprises entre 0,01 % et 0,1 % en masse.
Le présent document ne s’applique pas à la détermination de la teneur en composés organiques semi‑volatils (COSV), laquelle est traitée dans l’ISO 11890-2.
Le présent document ne s'applique pas aux composés organiques volatils et aux composés inorganiques volatils dont la teneur ne peut pas être déterminée par chromatographie en phase gazeuse.
Le mode opératoire permettant d’identifier la méthode appropriée pour la détermination de la teneur en COV et de la teneur en COSV des produits de peinture et de leurs matières premières est décrit dans l’ISO/TR 5601.

Barve in laki - Določanje hlapnih organskih spojin (VOC) - Metoda plinske kromatografije s "headspace" injiciranjem za določanje hlapnih organskih spojin (ISO 17895:2024)

General Information

Status
Published
Public Enquiry End Date
02-Apr-2023
Publication Date
11-Dec-2024
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
03-Dec-2024
Due Date
07-Feb-2025
Completion Date
12-Dec-2024

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SLOVENSKI STANDARD
01-januar-2025
Nadomešča:
SIST EN ISO 17895:2005
Barve in laki - Določanje hlapnih organskih spojin (VOC) - Metoda plinske
kromatografije s "headspace" injiciranjem za določanje hlapnih organskih spojin
(ISO 17895:2024)
Paints and varnishes - Determination of volatile organic compound (VOC) - Gas-
chromatographic method with headspace injection for VOC determination (ISO
17895:2024)
Beschichtungsstoffe - Bestimmung des Gehaltes an flüchtigen organischen
Verbindungen (VOC) - Gaschromatographisches Verfahren mit Dampfrauminjektion zur
Bestimmung des Gehaltes an flüchtigen organischen Verbindungen (ISO 17895:2024)
Peintures et vernis - Détermination de la teneur en composés organiques volatils (COV)
- Méthode par chromatographie en phase gazeuse avec injection dans l'espace de tête
pour la détermination des COV (ISO 17895:2024)
Ta slovenski standard je istoveten z: EN ISO 17895:2024
ICS:
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
87.040 Barve in laki Paints and varnishes
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

EN ISO 17895
EUROPEAN STANDARD
NORME EUROPÉENNE
August 2024
EUROPÄISCHE NORM
ICS 87.040 Supersedes EN ISO 17895:2005
English Version
Paints and varnishes - Determination of volatile organic
compound (VOC) - Gas-chromatographic method with
headspace injection for VOC determination (ISO
17895:2024)
Peintures et vernis - Détermination de la teneur en Beschichtungsstoffe - Bestimmung des Gehaltes an
composés organiques volatils (COV) - Méthode par flüchtigen organischen Verbindungen in
chromatographie en phase gazeuse avec injection dans wasserverdünnbaren Dispersionsfarben (In-can VOC)
l'espace de tête pour la détermination des COV (ISO (ISO 17895:2024)
17895:2024)
This European Standard was approved by CEN on 3 August 2024.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2024 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 17895:2024 E
worldwide for CEN national Members.

Contents Page
European foreword . 3

European foreword
This document (EN ISO 17895:2024) has been prepared by Technical Committee ISO/TC 35 "Paints and
varnishes" in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes” the
secretariat of which is held by DIN.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by February 2025, and conflicting national standards
shall be withdrawn at the latest by February 2025.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN ISO 17895:2005.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Türkiye and the
United Kingdom.
Endorsement notice
The text of ISO 17895:2024 has been approved by CEN as EN ISO 17895:2024 without any modification.

International
Standard
ISO 17895
Second edition
Paints and varnishes —
2024-08
Determination of volatile
organic compound (VOC) — Gas-
chromatographic method with
headspace injection for VOC
determination
Peintures et vernis — Détermination de la teneur en composés
organiques volatils (COV) — Méthode par chromatographie
en phase gazeuse avec injection dans l'espace de tête pour la
détermination des COV
Reference number
ISO 17895:2024(en) © ISO 2024
ISO 17895:2024(en)
© ISO 2024
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
ISO 17895:2024(en)
Contents Page
Foreword .iv
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 3
5 Required information . 3
6 Apparatus . 3
7 Reagents . 5
8 Procedure . 6
8.1 Number of determinations .6
8.2 Sample preparation .6
8.2.1 General .6
8.2.2 Dilution of original sample .6
8.2.3 Preparation of test samples for analysis without multiple standard additions .6
8.2.4 Preparation of test samples for analysis with multiple standard additions .6
8.3 Analysis .7
8.3.1 General .7
8.3.2 Headspace injector .7
8.3.3 Gas chromatograph .7
8.3.4 Determination of integration end point .8
9 Ev a luat ion . 8
10 Calculation . 9
10.1 General .9
10.2 Method 1: VOC content, as a percentage by mass, of the product “ready for use” .9
10.3 Method 2: VOC content, in grams per litre, of the product “ready for use” .10
11 Precision .11
11.1 General .11
11.2 Repeatability limit, r .11
11.3 Reproducibility limit, R . 12
12 Test report .12
Annex A (informative) Gas chromatogram of the reference compound mixture and tetradecane .13
Bibliography . 14

iii
ISO 17895:2024(en)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out through
ISO technical committees. Each member body interested in a subject for which a technical committee
has been established has the right to be represented on that committee. International organizations,
governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely
with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are described
in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the different types
of ISO document should be noted. This document was drafted in accordance with the editorial rules of the
ISO/IEC Directives, Part 2 (see www.iso.org/directives).
ISO draws attention to the possibility that the implementation of this document may involve the use of (a)
patent(s). ISO takes no position concerning the evidence, validity or ap
...

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