Footwear - Critical substances potentially present in footwear and footwear components - Test method to quantitatively determine polycyclic aromatic hydrocarbons (PAHs) in footwear materials (ISO 16190:2021)

This document specifies a method to determine the amounts of polycyclic aromatic hydrocarbons
(PAHs) in footwear and footwear components.
NOTE A list of relevant materials can be found in ISO/TR 16178:2021, Table 1[3].

Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische Substanzen - Prüfverfahren zur quantitativen Bestimmung polyzyklischer aromatischer Kohlenwasserstoffe (PAK) in Schuhwerkstoffen (ISO 16190:2021)

Dieses Dokument legt ein Verfahren zur quantitativen Bestimmung polyzyklischer aromatischer Kohlenwasserstoffe (PAK) in Schuhen und Schuhbestandteilen fest.
ANMERKUNG Eine Liste betroffener Werkstoffe kann ISO/TR 16178, Tabelle 1, entnommen werden.
WARNUNG - Die Anwendung dieser Norm umfasst gefährliche Stoffe. Sie bezweckt nicht, sämtliche in Zusammenhang mit seiner Anwendung stehenden Sicherheits- oder Umweltprobleme zu behandeln. Es liegt in der Verantwortung der Anwender dieser Norm, die geeigneten Maßnahmen zu ergreifen, um den Sicherheits- und Gesundheitsschutz des Personals und der Umwelt vor Anwendung des Dokuments sicherzustellen und die diesem Zweck dienenden gesetzlichen und behördlichen Anforderungen zu erfüllen.

Chaussures - Substances critiques potentiellement présentes dans les chaussures et les composants de chaussures - Méthode d’essai pour déterminer quantitativement les hydrocarbures aromatiques polycycliques (HAP) dans les matériaux de chaussures (ISO 16190:2021)

Le présent document spécifie une méthode pour déterminer la quantité d’hydrocarbures aromatiques polycycliques (HAP) dans les chaussures et les composants de chaussures.
NOTE            Une liste des matériaux pertinents peut être consultée dans l’ISO/TR 16178:2021, Tableau 1[3].

Obutev - Kritične snovi, ki so lahko v obutvi in delih obutve - Preskusna metoda za kvantitativno ugotavljanje policikličnih aromatskih ogljikovodikov (PAH) v obutvenih materialih (ISO 16190:2021)

Ta dokument določa metodo za ugotavljanje količine policikličnih aromatskih ogljikovodikov (PAH) v obutvi in delih obutve.
OPOMBA: Seznam ustreznih materialov je na voljo v standardu ISO/TR 16178:2021, preglednica 1[3].

General Information

Status
Published
Public Enquiry End Date
31-Mar-2021
Publication Date
08-Dec-2021
Technical Committee
Current Stage
6060 - National Implementation/Publication (Adopted Project)
Start Date
01-Dec-2021
Due Date
05-Feb-2022
Completion Date
09-Dec-2021

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SLOVENSKI STANDARD
SIST EN ISO 16190:2022
01-januar-2022
Nadomešča:
SIST-TS CEN ISO/TS 16190:2014
Obutev - Kritične snovi, ki so lahko v obutvi in delih obutve - Preskusna metoda za
kvantitativno ugotavljanje policikličnih aromatskih ogljikovodikov (PAH) v
obutvenih materialih (ISO 16190:2021)
Footwear - Critical substances potentially present in footwear and footwear components
- Test method to quantitatively determine polycyclic aromatic hydrocarbons (PAHs) in
footwear materials (ISO 16190:2021)
Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische
Substanzen - Prüfverfahren zur quantitativen Bestimmung polyzyklischer aromatischer
Kohlenwasserstoffe (PAK) in Schuhwerkstoffen (ISO 16190:2021)
Chaussures - Substances critiques potentiellement présentes dans les chaussures et les
composants de chaussures - Méthode d’essai pour déterminer quantitativement les
hydrocarbures aromatiques polycycliques (HAP) dans les matériaux de chaussures (ISO
16190:2021)
Ta slovenski standard je istoveten z: EN ISO 16190:2021
ICS:
61.060 Obuvala Footwear
SIST EN ISO 16190:2022 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN ISO 16190:2022

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SIST EN ISO 16190:2022


EN ISO 16190
EUROPEAN STANDARD

NORME EUROPÉENNE

November 2021
EUROPÄISCHE NORM
ICS 61.060 Supersedes CEN ISO/TS 16190:2013
English Version

Footwear - Critical substances potentially present in
footwear and footwear components - Test method to
quantitatively determine polycyclic aromatic
hydrocarbons (PAHs) in footwear materials (ISO
16190:2021)
Chaussures - Substances critiques potentiellement Schuhe - Möglicherweise in Schuhen und
présentes dans les chaussures et les composants de Schuhbestandteilen vorhandene kritische Substanzen -
chaussures - Méthode d'essai pour déterminer Prüfverfahren zur quantitativen Bestimmung
quantitativement les hydrocarbures aromatiques polyzyklischer aromatischer Kohlenwasserstoffe (PAK)
polycycliques (HAP) dans les matériaux de chaussures in Schuhwerkstoffen (ISO 16190:2021)
(ISO 16190:2021)
This European Standard was approved by CEN on 7 November 2021.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 16190:2021 E
worldwide for CEN national Members.

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SIST EN ISO 16190:2022
EN ISO 16190:2021 (E)
Contents Page
European foreword . 3

2

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SIST EN ISO 16190:2022
EN ISO 16190:2021 (E)
European foreword
This document (EN ISO 16190:2021) has been prepared by Technical Committee ISO/TC 216
"Footwear" in collaboration with Technical Committee CEN/TC 309 “Footwear” the secretariat of which
is held by UNE.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by May 2022, and conflicting national standards shall be
withdrawn at the latest by May 2022.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes CEN ISO/TS 16190:2013.
Any feedback and questions on this document should be directed to the users’ national standards
body/national committee. A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland,
Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of
North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the
United Kingdom.
Endorsement notice
The text of ISO 16190:2021 has been approved by CEN as EN ISO 16190:2021 without any modification.

3

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SIST EN ISO 16190:2022

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SIST EN ISO 16190:2022
INTERNATIONAL ISO
STANDARD 16190
First edition
2021-11
Footwear — Critical substances
potentially present in footwear and
footwear components — Test method
to quantitatively determine polycyclic
aromatic hydrocarbons (PAHs) in
footwear materials
Chaussures — Substances critiques potentiellement présentes dans
les chaussures et les composants de chaussures — Méthode d’essai
pour déterminer quantitativement les hydrocarbures aromatiques
polycycliques (HAP) dans les matériaux de chaussures
Reference number
ISO 16190:2021(E)
© ISO 2021

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SIST EN ISO 16190:2022
ISO 16190:2021(E)
COPYRIGHT PROTECTED DOCUMENT
© ISO 2021
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on
the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below
or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii
  © ISO 2021 – All rights reserved

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SIST EN ISO 16190:2022
ISO 16190:2021(E)
Contents Page
Foreword .iv
Introduction . vi
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 1
6 Apparatus . 5
7 Sample preparation .5
8 Procedure .5
8.1 Extraction . 5
8.2 Optional: Solid-phase extraction (SPE) clean-up . 6
8.3 Determination by GC-MS or GC-MS/MS . . 6
9 Expression of results . 6
9.1 Determination of the PAH content . 6
9.1.1 For each PAH . 6
9.1.2 When a sum of PAHs is requested. 6
9.2 Performance of the test method . 7
10 Test report . 7
Annex A (informative) Examples of chromatographic conditions for GC-MS and GC-MS/MS .8
Bibliography .11
iii
© ISO 2021 – All rights reserved

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SIST EN ISO 16190:2022
ISO 16190:2021(E)
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to
the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see
www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 216, Footwear, in collaboration with
the European Committee for Standardization (CEN) Technical Committee CEN/TC 309, Footwear, in
accordance with the Agreement on technical cooperation between ISO and CEN (Vienna Agreement).
This first edition cancels and replaces the first edition Technical Specification (ISO/TS 16190:2013),
which has been technically revised. The main changes compared with the previous edition are as
follows:
— the Introduction has been added;
— in the Scope, editorial changes have been made and a note has been added;
— the Normative references have been updated;
— Clause 3 “Terms and definitions” has been added and the following clauses have been renumbered;
— Clause 5 “Reagents” has been renamed and major technical changes have been made;
— Clause 6 “Apparatus” has been renamed, further equipment has been added and further minor
technical changes have been made;
— Clause 7 “Sample preparation” has been added, which has been mainly taken from ISO/TS 16190:2013,
6.2, and the following clauses have been renumbered;
— in Clause 8 “Procedure”, major technical changes and editorial changes have been made;
— Clause 9 “Expression of results” has been renamed and subclause headings have been added;
— 9.1.2 “When a sum of PAH is requested” has been added;
— in 9.2 “Performance of the test method”, the limit of quantification has been changed;
— in Clause 10 g), the option to state a sum of PAH has been added;
iv
  © ISO 2021 – All rights reserved

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SIST EN ISO 16190:2022
ISO 16190:2021(E)
— Annex A has been added.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www.iso.org/members.html.
v
© ISO 2021 – All rights reserved

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SIST EN ISO 16190:2022
ISO 16190:2021(E)
Introduction
Certain polycyclic aromatic hydrocarbons (PAHs) have been identified as carcinogenic. Thus, several
countries have restricted them in articles such as footwear, e.g. in the European Union by Commission
[1] [2]
Regulation (EU) 2018/1513 amending Regulation (EC) No 1907/2006 .
Restricted PAHs according to Regulation (EC) No 1907/2006 are Benzo[a]pyrene (BaP), Benzo[e]pyrene
(BeP), Benzo[a]anthracene (BaA), Chrysene (CHR), Benzo[b]fluoranthene (BbFA), Benzo[j]fluoranthene
(BjFA), (g) Benzo[k]fluoranthene (BkFA) and Dibenzo[a,h]anthracene (DBAhA).
Further PAHs are restricted by footwear brands in their restricted substances lists (RSLs).
vi
  © ISO 2021 – All rights reserved

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SIST EN ISO 16190:2022
INTERNATIONAL STANDARD ISO 16190:2021(E)
Footwear — Critical substances potentially present in
footwear and footwear components — Test method to
quantitatively determine polycyclic aromatic hydrocarbons
(PAHs) in footwear materials
WARNING — The use of this document involves hazardous materials. It does not purport
to address all of the safety or environmental problems associated with its use. It is the
responsibility of users of this document to take appropriate measures to ensure the safety and
health of personnel and the environment prior to the application of this document, and to fulfil
the relevant requirements for this purpose.
1 Scope
This document specifies a method to determine the amounts of polycyclic aromatic hydrocarbons
(PAHs) in footwear and footwear components.
[3]
NOTE A list of relevant materials can be found in ISO/TR 16178:2021, Table 1 .
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 4787, Laboratory glassware — Volumetric instruments — Methods for testing of capacity and for use
3 Terms and definitions
No terms and definitions are listed in this document.
ISO and IEC maintain terminological databases for use in standardization at the following addresses:
— ISO Online browsing platform: available at https:// www .iso .org/ obp
— IEC Electropedia: available at http:// www .electropedia .org/
4 Principle
The test sample is extracted using toluene at 60 °C in an ultrasonic bath for 1 h. An aliquot is then
analysed using a gas chromatograph with mass selective detector.
5 Reagents
WARNING — Toluene is flammable. In addition, PAHs can cause cancer. Therefore, they should
be treated taking into account relevant regulations on occupational health and safety.
Unless otherwise specified, analytical grade chemicals shall be used.
1
© ISO 2021 – All rights reserved

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...

SLOVENSKI STANDARD
oSIST prEN ISO 16190:2021
01-marec-2021
Obutev - Kritične snovi, ki so lahko v obutvi in delih obutve - Preskusna metoda za
kvantitativno ugotavljanje policikličnih aromatskih ogljikovodikov (PAH) v
obutvenih materialih (ISO/DIS 16190:2021)
Footwear - Critical substances potentially present in footwear and footwear components
- Test method to quantitatively determine polycyclic aromatic hydrocarbons (PAH) in
footwear materials (ISO/DIS 16190:2021)
Schuhe - Möglicherweise in Schuhen und Schuhbestandteilen vorhandene kritische
Substanzen - Prüfverfahren zur quantitativen Bestimmung polyzyklischer aromatischer
Kohlenwasserstoffe (PAK) in Schuhwerkstoffen (ISO/DIS 16190:2021)
Chaussures - Substances critiques potentiellement présentes dans la chaussure et les
composants de chaussure - Méthodes d'essai pour déterminer quantitativement les
hydrocarbures aromatiques polycycliques (HAP) dans les matériaux de chaussure
(ISO/DIS 16190:2021)
Ta slovenski standard je istoveten z: prEN ISO 16190
ICS:
61.060 Obuvala Footwear
oSIST prEN ISO 16190:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
oSIST prEN ISO 16190:2021

---------------------- Page: 2 ----------------------
oSIST prEN ISO 16190:2021
DRAFT INTERNATIONAL STANDARD
ISO/DIS 16190
ISO/TC 216 Secretariat: UNE
Voting begins on: Voting terminates on:
2021-01-07 2021-04-01
Footwear — Critical substances potentially present in
footwear and footwear components — Test method to
quantitatively determine polycyclic aromatic hydrocarbons
(PAH) in footwear materials
Chaussures — Substances critiques potentiellement présentes dans la chaussure et les composants
de chaussure — Méthodes d'essai pour déterminer quantitativement les hydrocarbures aromatiques
polycycliques (HAP) dans les matériaux de chaussure
ICS: 61.060
THIS DOCUMENT IS A DRAFT CIRCULATED
This document is circulated as received from the committee secretariat.
FOR COMMENT AND APPROVAL. IT IS
THEREFORE SUBJECT TO CHANGE AND MAY
NOT BE REFERRED TO AS AN INTERNATIONAL
STANDARD UNTIL PUBLISHED AS SUCH.
IN ADDITION TO THEIR EVALUATION AS
ISO/CEN PARALLEL PROCESSING
BEING ACCEPTABLE FOR INDUSTRIAL,
TECHNOLOGICAL, COMMERCIAL AND
USER PURPOSES, DRAFT INTERNATIONAL
STANDARDS MAY ON OCCASION HAVE TO
BE CONSIDERED IN THE LIGHT OF THEIR
POTENTIAL TO BECOME STANDARDS TO
WHICH REFERENCE MAY BE MADE IN
Reference number
NATIONAL REGULATIONS.
ISO/DIS 16190:2021(E)
RECIPIENTS OF THIS DRAFT ARE INVITED
TO SUBMIT, WITH THEIR COMMENTS,
NOTIFICATION OF ANY RELEVANT PATENT
RIGHTS OF WHICH THEY ARE AWARE AND TO
©
PROVIDE SUPPORTING DOCUMENTATION. ISO 2021

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oSIST prEN ISO 16190:2021
ISO/DIS 16190:2021(E)

COPYRIGHT PROTECTED DOCUMENT
© ISO 2021
All rights reserved. Unless otherwise specified, or required in the context of its implementation, no part of this publication may
be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting
on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address
below or ISO’s member body in the country of the requester.
ISO copyright office
CP 401 • Ch. de Blandonnet 8
CH-1214 Vernier, Geneva
Phone: +41 22 749 01 11
Email: copyright@iso.org
Website: www.iso.org
Published in Switzerland
ii © ISO 2021 – All rights reserved

---------------------- Page: 4 ----------------------
oSIST prEN ISO 16190:2021
ISO/DIS 16190:2021(E)

Contents Page
Foreword .iv
Introduction .v
1 Scope . 1
2 Normative references . 1
3 Terms and definitions . 1
4 Principle . 1
5 Reagents . 1
6 Apparatus . 4
7 Sample preparation . 5
8 Procedure. 5
8.1 Extraction . 5
8.2 Optional: SPE Clean up . 5
8.3 Determination by GC-MS . 5
8.4 Precision of the test method. 6
9 Expression of results . 6
10 Test report . 6
Bibliography . 7
© ISO 2021 – All rights reserved iii

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oSIST prEN ISO 16190:2021
ISO/DIS 16190:2021(E)

Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has been established has the right to be represented on that committee. International
organizations, governmental and non-governmental, in liaison with ISO, also take part in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are
described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identified during the development of the document will be in the Introduction and/or
on the ISO list of patent declarations received (see www .iso .org/ patents).
Any trade name used in this document is information given for the convenience of users and does not
constitute an endorsement.
For an explanation of the voluntary nature of standards, the meaning of ISO specific terms and
expressions related to conformity assessment, as well as information about ISO's adherence to the
World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT), see www .iso .org/
iso/ foreword .html.
This document was prepared by Technical Committee ISO/TC 216, Footwear.
This first edition cancels and replaces ISO/TS 16190:2013, which has been technically revised.
Any feedback or questions on this document should be directed to the user’s national standards body. A
complete listing of these bodies can be found at www .iso .org/ members .html.
iv © ISO 2021 – All rights reserved

---------------------- Page: 6 ----------------------
oSIST prEN ISO 16190:2021
ISO/DIS 16190:2021(E)

Introduction
In the European Union according to Regulation (EC) No 1272/2013 [1] amending Annex XVII to
Regulation (EC) No 1907/2006 (REACH) [2], Annex XVII, Entry 50, [1] articles such as, footwear shall
not be placed on the market for supply to the general public, if any of their rubber or plastic components
that come into direct, as well as prolonged or short-term repetitive, contact with the human skin or
the oral cavity, under normal or reasonably foreseeable conditions of use, contain more than 1 mg/kg
(0,0001 % by weight of this component) of any of the following PAHs.
Further information can be found in the ECHA guideline [3].
According to Regulation (EU) 2018/1513 [4] amending Annex XVII to Regulation (EC) No 1907/2006
(REACH) by Entry 72, (c) footwear shall not be placed on the market after 1 November 2020, if they
contain more than 1 mg/kg (0,0001 % by weight of this component) of any of the following PAHs.
This restriction shall not apply to: (a) clothing, related accessories or footwear, or parts of clothing,
related accessories or footwear, made exclusively of natural leather, fur or hide; (b) non-textile fasteners
and non-textile decorative attachments; (c) second-hand clothing, related accessories, textiles other
than clothing or footwear. It shall also not apply to clothing, related accessories, textiles other than
clothing, or footwear within the scope of Regulation (EU) 2016/425 or Regulation (EU) 2017/745.
Restricted PAHs according to REACH are Benzo[a]pyrene (BaP), Benzo[e]pyrene (BeP), Benzo[a]
anthracene (BaA), Chrysene (CHR), Benzo[b]fluoranthene (BbFA), Benzo[j]fluoranthene (BjFA), (g)
Benzo[k]fluoranthene (BkFA), Dibenzo[a,h]anthracene (DBAhA).
The PAHs Benzo(g,h,i)perylene, Fluoranthene, Phenanthrene and Pyrene have been added to the
REACH Candidate List of SVHC https:// echa .europa .eu/ candidate -list -table.
© ISO 2021 – All rights reserved v

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oSIST prEN ISO 16190:2021

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oSIST prEN ISO 16190:2021
DRAFT INTERNATIONAL STANDARD ISO/DIS 16190:2021(E)
Footwear — Critical substances potentially present in
footwear and footwear components — Test method to
quantitatively determine polycyclic aromatic hydrocarbons
(PAH) in footwear materials
WARNING — The use of this standard involves hazardous materials. It does not purport to address
all of the safety or environmental problems associated with its use. It is the responsibility of
users of this standard to take appropriate measures to ensure the safety and health of personnel
and the environment prior to application of the standard, and fulfil statutory and regulatory
requirements for this purpose.
1 Scope
This document specifies a method to determine the amounts of polycyclic aromatic hydrocarbons
(PAH) in footwear and footwear components.
NOTE A list of relevant materials can be found in ISO/TR 16178, Table 1.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
ISO 4787, Laboratory glassware — Volumetric instruments — Methods for testing of capacity and for use
ISO/TR 16178, Footwear — Critical substances potentially present in footwear and footwear components
ISO 28540:2011, Water quality — Determination of 16 polycyclic aromatic hydrocarbons (PAH) in water —
Method using gas chromatography with mass spectrometric detection (GC-MS)
3 Terms and definitions
No terms and defi
...

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