SIST EN 14111:2022

Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of iodine value

This document specifies a titrimetric method for the determination of iodine value in Fatty Acid Methyl Esters, hereinafter referred as FAME.
The precision statement of this test method was determined in a Round Robin exercise with iodine values in the range 111 g iodine/100 g to 129 g iodine/100 g.
The test method is also applicable for lower iodine values, however, the precision statement is not established for iodine values below 111 g iodine/100 g.
WARNING — The use of this document can involve hazardous materials, operations and equipment. This document does not purport to address all of the safety problems associated with its use. It is the responsibility of users of this document to take appropriate measures to ensure the safety and health of personnel prior to the application of the document, and to determine the applicability of any other restrictions for this purpose.

Erzeugnisse aus pflanzlichen und tierischen Fetten und Ölen - Fettsäure-Methylester (FAME) - Bestimmung der Iodzahl

Dieses Dokument legt ein titrimetrisches Verfahren zur Bestimmung der Iodzahl von Fettsäure Methylestern, nachfolgend FAME genannt, fest.
Die Präzisionsangabe dieses Prüfverfahrens wurde in einem Ringversuch mit Iodzahlen im Bereich 111 g Iod/100 g bis 129 g Iod/100 g bestimmt.
Dieses Prüfverfahren gilt auch für niedrigere Iodzahlen, die Präzisionsangabe wird jedoch nicht für Iodzahlen unter 111 g Iod/100 g festgelegt.
WARNUNG — Die Anwendung dieses Dokumentes kann die Anwendung gefährlicher Stoffe, Arbeitsgänge und Geräte mit sich bringen. Dieses Dokument beansprucht nicht, alle damit verbundenen Sicherheitsprobleme zu behandeln. Es liegt in der Verantwortung des Anwenders dieses Dokuments, geeignete Sicherheits  und Gesundheitsschutzmaßnahmen vorzusehen und im Vorfeld die Anwendbarkeit von einschränkenden Vorschriften zu klären.

Produits dérivés des corps gras - Esters méthyliques d'acides gras (EMAG) - Détermination de l'indice d'iode

Le présent document spécifie une méthode titrimétrique de détermination de l’indice d’iode des esters méthyliques d’acides gras, ci-après appelés EMAG.
Les mesures de fidélité de la présente méthode d’essai ont été déterminées lors d’un essai interlaboratoires avec des indices d’iode compris entre 111 g d’iode/100 g et 129 g d’iode/100 g.
La méthode d’essai s’applique également à des indices d’iode plus faibles ; cependant, les mesures de fidélité ne sont pas établies pour des indices d’iode inférieurs à 111 g d’iode/100 g.
AVERTISSEMENT - Le présent document peut impliquer l’utilisation de produits, de manipulations et d’équipements dangereux. Le présent document n’a pas pour objet d’aborder tous les problèmes de sécurité liés à son utilisation. Il incombe à l’utilisateur du présent document de prendre les mesures appropriées pour assurer l’hygiène et la sécurité du personnel avant l’application du présent document, et de déterminer l’applicabilité de toute autre restriction.

Derivati maščob in olj - Metil estri maščobnih kislin (FAME) - Določevanje jodnega števila

Ta dokument določa titrimetrijsko metodo za ugotavljanje jodnega števila v metilnih estrih maščobnih kislin (v nadaljevanju: FAME).
Izjava o natančnosti te preskusne metode je bila določena z medlaboratorijsko vajo z jodnimi števili v razponu od 111 g joda/100 g do 129 g joda/100 g.
Preskusna metoda se lahko uporablja tudi za nižje vrednosti joda, vendar izjava o natančnosti ni določena za jodna števila pod 111 g joda/100 g.
OPOZORILO: Pri uporabi tega dokumenta so lahko prisotni nevarni materiali, postopki in oprema. Ta dokument ne obravnava vseh varnostnih težav, ki se navezujejo na njegovo uporabo. Za sprejetje ustreznih ukrepov za zagotavljanje varnosti in zdravja osebja pred uporabo dokumenta ter za določanje, ali so potrebne morebitne druge omejitve za ta namen, so odgovorni uporabniki tega dokumenta.

General Information

• Status: Published
• Public Enquiry End Date: 19-Apr-2021
• Publication Date: 23-Aug-2022
• ICS: 67.200.10 - Animal and vegetable fats and oils
• Technical Committee: KŽP - Agricultural food products
• Current Stage: 6060 - National Implementation/Publication (Adopted Project)
• Start Date: 05-Aug-2022
• Due Date: 10-Oct-2022
• Completion Date: 24-Aug-2022
• Mandate: M/245 - Mandate to CEN for the elaboration and adoption of standards concerning minimum requirement specifications including test methods for Fatty Acid MethylEster (FAME) as fuel for diesel engines and for space heating
• Ref Project: EN 14111:2022 - Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of iodine value

Relations

• Replaces: SIST EN 14111:2003 - Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of iodine value
• Effective Date: 01-Sep-2022

Standards Content (Sample)

SLOVENSKI STANDARD
SIST EN 14111:2022
01-september-2022
Nadomešča:
SIST EN 14111:2003
Derivati maščob in olj - Metil estri maščobnih kislin (FAME) - Določevanje jodnega
števila
Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of iodine value
Erzeugnisse aus pflanzlichen und tierischen Fetten und Ölen - Fettsäure-Methylester
(FAME) - Bestimmung der Iodzahl
Produits dérivés des corps gras - Esters méthyliques d'acides gras (EMAG) -
Détermination de l'indice d'iode
Ta slovenski standard je istoveten z: EN 14111:2022
ICS:
67.200.10 Rastlinske in živalske Animal and vegetable fats
maščobe in olja and oils
SIST EN 14111:2022 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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SIST EN 14111:2022

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SIST EN 14111:2022


EN 14111
EUROPEAN STANDARD

NORME EUROPÉENNE

June 2022
EUROPÄISCHE NORM
ICS 67.200.10 Supersedes EN 14111:2003
English Version

Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) -
Determination of iodine value
Produits dérivés des corps gras - Esters méthyliques Erzeugnisse aus pflanzlichen und tierischen Fetten und
d'acides gras (EMAG) - Détermination de l'indice d'iode Ölen - Fettsäure-Methylester (FAME) - Bestimmung
der Iodzahl
This European Standard was approved by CEN on 23 April 2022.

CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.

This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.





EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2022 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 14111:2022 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
SIST EN 14111:2022
EN 14111:2022 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 5
5 Reagents . 6
6 Apparatus . 6
7 Sampling . 6
8 Preparation . 6
9 Procedure . 6
10 Calculation . 7
11 Expression of results . 7
12 Precision . 7
13 Test report . 8
Annex A (informative) Result of an interlaboratory trial . 9
Bibliography . 10

2

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SIST EN 14111:2022
EN 14111:2022 (E)
European foreword
This document (EN 14111:2022) has been prepared by Technical Committee CEN/TC 307 “Oilseeds,
vegetable and animal fats and oils and their by-products - Methods of sampling and analysis”, the
secretariat of which is held by AFNOR.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by December 2022, and conflicting national standards shall
be withdrawn at the latest by December 2022.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes EN 14111:2003.
In comparison with the previous edition, the following technical modifications have been made:
— glass weighing scoops should no longer be inserted into the flask.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
Any feedback and questions on this document should be directed to the users’ national standards body.
A complete listing of these bodies can be found on the CEN website.
According to the CEN-CENELEC Internal Regulations, the national standards organisations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia,
Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland,
Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Republic of North
Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United
Kingdom.
3

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SIST EN 14111:2022
EN 14111:2022 (E)
Introduction
This document is based on EN ISO 3961 [1] which was specifically adapted for the determination of
iodine value of Fatty Acid Methyl Esters (FAME).
4

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SIST EN 14111:2022
EN 14111:2022 (E)
1 Scope
This document specifies a titrimetric method for the determination of iodine value in Fatty Acid Methyl
Esters, hereinafter referred as FAME.
The precision statement of this test method was determined in a Round Robin exercise with iodine values
in the range 111 g iodine/100 g to 129 g iodine/100 g.
The test method is also applicable for lower iodine values; however, the precision statement is not
established for iodine values below 111 g iodine/100 g.
WARNING — The use of this document can involve hazardous materials, operations and equipment. This
document does not purport to address all of the safety problems as
...

SLOVENSKI STANDARD
oSIST prEN 14111:2021
01-maj-2021
Derivati maščob in olj - Metil estri maščobnih kislin (FAME) - Določevanje jodnega
števila
Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) - Determination of iodine value
Erzeugnisse aus pflanzlichen und tierischen Fetten und Ölen - Fettsäure-Methylester
(FAME) - Bestimmung der Iodzahl
Produits dérivés des corps gras - Esters méthyliques d'acides gras (EMAG) -
Détermination de l'indice d'iode
Ta slovenski standard je istoveten z: prEN 14111
ICS:
67.200.10 Rastlinske in živalske Animal and vegetable fats
maščobe in olja and oils
oSIST prEN 14111:2021 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

---------------------- Page: 1 ----------------------
oSIST prEN 14111:2021

---------------------- Page: 2 ----------------------
oSIST prEN 14111:2021


DRAFT
EUROPEAN STANDARD
prEN 14111
NORME EUROPÉENNE

EUROPÄISCHE NORM

March 2021
ICS 67.200.10 Will supersede EN 14111:2003
English Version

Fat and oil derivatives - Fatty Acid Methyl Esters (FAME) -
Determination of iodine value
Produits dérivés des corps gras - Esters méthyliques Erzeugnisse aus pflanzlichen und tierischen Fetten und
d'acides gras (EMAG) - Détermination de l'indice d'iode Ölen - Fettsäure-Methylester (FAME) - Bestimmung
der Iodzahl
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 307.

If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.

CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.

Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.

Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.


EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION

EUROPÄISCHES KOMITEE FÜR NORMUNG

CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2021 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 14111:2021 E
worldwide for CEN national Members.

---------------------- Page: 3 ----------------------
oSIST prEN 14111:2021
prEN 14111:2021 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 5
4 Principle . 5
5 Reagents . 6
6 Apparatus . 6
7 Sampling . 6
8 Preparation . 6
9 Procedure . 6
10 Calculation . 7
11 Expression of results . 7
12 Precision . 7
13 Test report . 8
Annex A (informative) Result of an interlaboratory trial . 9
Bibliography . 10

2

---------------------- Page: 4 ----------------------
oSIST prEN 14111:2021
prEN 14111:2021 (E)
European foreword
This document (prEN 14111:2021) has been prepared by Technical Committee CEN/TC 307 “Oilseeds,
vegetable and animal fats and oils and their by-products - Methods of sampling and analysis”, the
secretariat of which is held by AFNOR.
This document is currently submitted to the CEN Enquiry.
This document will supersede EN 14111:2003.
In comparison with the previous edition, the following technical modifications have been made:
— glass weighing scoops should no longer be inserted into the flask.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association.
3

---------------------- Page: 5 ----------------------
oSIST prEN 14111:2021
prEN 14111:2021 (E)
Introduction
This document is based on EN ISO 3961 [1] which was specifically adapted for the determination of
iodine value of Fatty Acid Methyl Esters (FAME).
4

---------------------- Page: 6 ----------------------
oSIST prEN 14111:2021
prEN 14111:2021 (E)
1 Scope
This document specifies a titrimetric method for the determination of iodine value in Fatty Acid Methyl
Esters, hereinafter referred as FAME.
The precision statement of this test method was determined in a Round Robin exercise with iodine values
in the range 111 g iodine/100 g to 129 g iodine/100 g.
The test method is also applicable for lower iodine values, however, the precision statement is not
established for iodine values below 111 g iodine/100 g.
WARNING — The use of this document can involve hazardous materials, operations and equipment. This
document does not purport to address all of the safety problems associated with its use. It is the
responsibility of users of this document to take appropriate measures to ensure the safety and health of
personnel prior to the application of the document, and to determine the applicability of any other
restrictions for this purpose.
2 Normative references
The following documents are referred to in the text in such a way that some or all of their c
...