SIST EN 71-7:2014+A3:2020
(Main)Safety of toys - Part 7: Finger paints - Requirements and test methods
Safety of toys - Part 7: Finger paints - Requirements and test methods
This part of EN 71 specifies requirements for the substances and materials used in finger paints and applies to finger paints only.
Additional requirements are specified for markings, labelling and containers.
Sicherheit von Spielzeug - Teil 7: Fingermalfarben - Anforderungen und Prüfverfahren
Dieser Teil der EN 71 legt Anforderungen an die in Fingermalfarben verwendeten Stoffe und Materialien fest und gilt nur für Fingermalfarben.
Für Beschriftung, Kennzeichnung und Behälter sind zusätzliche Anforderungen festgelegt.
Sécurité des jouets - Partie 7: Peintures au doigt - Exigences et méthodes d'essai
La présente partie de l'EN 71 fixe des exigences relatives aux substances et produits utilisés dans les peintures au doigt et s’applique uniquement aux peintures au doigt.
Des exigences complémentaires sont données pour le marquage, l'étiquetage et l'emballage.
Varnost igrač - 7. del: Prstne barve - Zahteve in preskusne metode (vključno z dopolnilom A3)
General Information
Relations
Standards Content (Sample)
SLOVENSKI STANDARD
01-junij-2020
Nadomešča:
SIST EN 71-7:2014+A2:2018
Varnost igrač - 7. del: Prstne barve - Zahteve in preskusne metode (vključno z
dopolnilom A3)
Safety of toys - Part 7: Finger paints - Requirements and test methods
Sicherheit von Spielzeug - Teil 7: Fingermalfarben - Anforderungen und Prüfverfahren
Sécurité des jouets - Partie 7: Peintures au doigt - Exigences et méthodes d'essai
Ta slovenski standard je istoveten z: EN 71-7:2014+A3:2020
ICS:
97.200.50 Igrače Toys
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
EN 71-7:2014+A3
EUROPEAN STANDARD
NORME EUROPÉENNE
April 2020
EUROPÄISCHE NORM
ICS 97.200.50
English Version
Safety of toys - Part 7: Finger paints - Requirements and
test methods
Sécurité des jouets - Partie 7: Peintures au doigt - Sicherheit von Spielzeug - Teil 7: Fingermalfarben -
Exigences et méthodes d'essai Anforderungen und Prüfverfahren
This European Standard was approved by CEN on 9 January 2018 and includes Amendment 3 approved by CEN on 13 February
2020.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 71-7:2014+A3:2020 E
worldwide for CEN national Members.
Contents Page
European foreword . 5
Introduction . 7
1 Scope . 8
2 Normative references . 8
3 Terms and definitions . 8
4 Requirements . 9
4.1 General . 9
4.2 Colourants . 9
4.3 Preservatives . 10
4.4 Migration of certain elements . 10
4.5 Limits for impurities . 10
4.5.1 Limits for primary aromatic amines . 10
4.5.2 Limits for other impurities . 11
4.6 Taste and smell . 12
4.7 pH-value . 12
4.8 Binding agents, extenders, humectants and surfactants . 12
4.9 N-Nitrosamines . 12
4.10 Containers . 13
5 Product information . 13
5.1 General . 13
5.2 Marking . 13
5.2.1 Primary packaging . 13
5.2.2 Container . 14
Annex A (informative) Non-exhaustive list of colourants which are commonly used in finger
paints, and need to be in compliance with both the general and specified purity
requirements . 15
Annex B (normative) List of preservatives allowed for use in finger paints . 21
Annex C (informative) Ingredients used in the manufacture of finger paints . 26
Annex D (normative) Method for the detection of certain azo colourants and determination
of free primary aromatic amines . 28
D.1 General . 28
D.2 Reagents . 29
D.3 Apparatus . 30
D.4 Instrumentation . 30
D.5 Sampling procedure . 30
D.6 Procedure. 31
D.7 Calculation . 40
D.8 Precision . 41
D.8.1 Linearity . 41
D.8.2 Limits of Detection (LOD) and Quantification (LOQ) . 41
D.8.3 Repeatability and reproducibility data for soluble aromatic amines . 42
D.8.4 Repeatability and reproducibility data for reductively cleaved aromatic amines . 43
D.8.5 Recovery . 44
D.9 Report . 46
D.10 Additional Information . 46
Annex E (normative) Method for the determination of hexachlorobenzene, polychlorinated
biphenyls and %benzo[a]pyrene& . 47
E.1 Principle . 47
E.2 Standards, reagents and solvents . 47
E.3 Apparatus . 49
E.4 Instrumentation . 50
E.5 Sampling . 50
E.6 Procedure . 50
E.6.1 General . 50
E.6.2 Sample preparation . 50
E.6.3 Solvent extraction . 50
E.6.4 Solid phase extraction . 51
E.6.5 Sample concentration for determining HCB and PCB congeners . 51
E.6.6 Sample concentration for determining B[α]P . 51
E.6.7 Gas chromatography conditions . 51
E.6.8 Mass spectrometry . 52
E.6.9 SIM mode . 52
E.7 Calculation. 57
E.8 Precision . 60
E.8.1 Linearity . 60
E.8.2 Limits of detection (LOD) and Quantification (LOQ) . 60
E.8.3 Repeatability and reproducibility data for HCB, PCB congeners and B[α]P . 60
E.8.4 Recovery . 61
E.9 Report . 62
E.10 Additional information . 62
Annex F (informative) Rationale . 66
F.1 Finger paints (see 3.1 and 3.2) . 66
F.2 Colourants (see 4.2.1) . 66
F.3 Preservatives (see 4.3) . 66
F.4 Elements (see 4.4) . 66
F.5 Primary aromatic amines (see 4.5.1.2, Tables 1 and 2 and Annex D) . 66
F.6 Limit for %Benzo[a]Pyrene& (see 4.5.2) . 67
F.7 Embittering agents (see 4.6) . 67
F.8 pH value (see 4.7) . 67
F.9 N-Nitrosamines (see 4.9) . 67
F.10 Container (see 4.10) . 68
F.11 Labelling phrases (see 5.2.1.2) . 68
F.12 List of polychlorinated biphenyl congeners (see Annex E). 68
F.13 Reference materials (see Annex D and E) . 68
F.14 PCB Analytical Method (see E.6) . 69
Annex G (informative) Significant technical changes between this European Standard and
the previous version . 70
Annex ZA (informative) Relationship between this European Standard and the Essential
Requirements of EU Directive 2009/48/EC . 71
Bibliography . 72
European foreword
This document (EN 71-7:2014+A3:2020) has been prepared by Technical Committee CEN/TC 52
“Safety of toys”, the secretariat of which is held by DS.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by October 2020 and conflicting national standards shall
be withdrawn at the latest by October 2020.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
This document supersedes %EN 71-7:2014+A2:2018.&
This document includes Amendment 1 approved by CEN on 2017-08-31.
This document includes Amendment 2 approved by CEN on 2018-01-09.
This document includes Amendment 3 approved by CEN on 2020-02-13.
The start and finish of text introduced or altered by amendment is indicated in the text by tags !",
#$ and %&.
This document has been prepared under a mandate given to CEN by the European Commission and the
European Free Trade Association, and supports essential requirements of EU Directive 2009/48/EC.
For relationship with EU Directive 2009/48/EC, see informative Annex ZA, which is an integral part of
this document.
EN 71, Safety of toys, consists of the following parts:
— Part 1: Mechanical and physical properties
— Part 2: Flammability
— Part 3: Migration of certain elements
— Part 4: Experimental sets for chemistry and related activities
— Part 5: Chemical toys (sets) other than experimental sets
— Part 7: Finger paints – Requirements and test methods
— Part 8: Activity toys for domestic use
— Part 9: Organic chemical compounds – Requirements
— Part 10: Organic chemical compounds – Sample preparation and extraction
— Part 11: Organic chemical compounds – Methods of analysis
— Part 12: N-Nitrosamines and N-nitrosatable substances
— Part 13: Olfactory board games, cosmetic kits and gustative games
— Part 14: Trampolines for domestic use
!NOTE 1 In addition to the above parts of EN 71, the following guidance documents have been
published: CEN Technical Report CEN/TR 15071, Safety of toys - National translations of warnings and
instructions for use in EN 71 and CEN/TR 15371 (all parts), Safety of toys – Interpretations."
This part 7 of the EN 71 series is intended to be read in conjunction with EN 71, part 1.
NOTE 2 Words in italics are defined in Clause 3 (Terms and definitions).
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Introduction
This European Standard contains requirements which are intended to reduce the risks to children when
finger paints are used as intended or in a foreseeable way, bearing in mind the behaviour of children. It
is intended to complete the essential safety requirements of Directive 2009/48/EC by providing special
requirements for finger paints.
It is recognized that finger paints when compared to other toy products present different risks because
of the intended use by fingers or hands and the age of the child. For example, prolonged skin contact or
possible ingestion of paint material cannot be ruled out. Therefore, the safety requirements outlined in
other parts of EN 71 needed to be expanded upon for finger paints. In order to address the risks
associated with the use of finger paints by children, this part of EN 71 contains requirements relating to
preservatives as well as other ingredients that may be used in the manufacture of finger paints and
requirements relating to impurities, migration of certain elements and other attributes.
Chemical Abstract Service Registry Number (CAS), European Inventory of Existing Chemical Substances
Number (EINECS) or Colour Index Number given in the tables are provided for information purposes
only.
1 Scope
This part of EN 71 specifies requirements for the substances and materials used in finger paints and
applies to finger paints only.
Additional requirements are specified for markings, labelling and containers.
2 Normative references
The following documents, in whole or in part, are normatively referenced in this document and are
indispensable for its application. For dated references, only the edition cited applies. For undated
references, the latest edition of the referenced document (including any amendments) applies.
EN 71-3, Safety of toys - Part 3: Migration of certain elements
EN 71-12, Safety of toys - Part 12: N-Nitrosamines and N-nitrosatable substances
EN ISO 787-9, General methods of test for pigments and extenders - Part 9: Determination of pH value of
aqueous suspension (ISO 787-9)
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1
finger paint
aqueous semi-solid or liquid, coloured mixture specially designed for children to apply directly to
suitable surfaces with the fingers and hands
3.2
colourant
pigment or dyestuff
Note 1 to entry: For definitions of pigment and dyestuff, see EN ISO 4618.
3.3
extender
material in granular or powder form, insoluble in the medium and used to modify or influence certain
physical properties
[SOURCE: EN ISO 4618:2006, 2.98]
3.4
humectant
substance that delays the drying process
3.5
binding agent
water soluble or miscible, non-volatile component that binds the paint to the surface to which it has
been applied
3.6
preservative
substance that prevents the growth of undesirable micro-organisms
3.7
surfactant
surface active substance
3.8
embittering agent
substance that gives the product a bitter taste
4 Requirements
NOTE The requirements of this standard apply to finger paints in the form used by the child. In the case of
powdered finger paints (for example to which water might be added before use) the requirements apply to the
finger paint prepared according to the manufacturer's instructions.
4.1 General
Finger paints shall not contain dangerous substances or mixtures in amounts which can harm the health
of children using them.
NOTE 1 For more information, see Directive 1999/45/EC [2] and Regulation No. (EC) 1272/2008 [1].
Finger paints shall not fulfil the criteria of any of the following hazard classes:
— “acute toxicity” (hazard class 3.1),
— “Skin corrosion/irritation” (hazard class 3.2),
— “Serious eye damage/eye irritation” (hazard class 3.3),
— “Respiratory or skin sensitisation” (hazard class 3.4),
— “Germ cell mutagenicity” (hazard class 3.5),
— “Carcinogenicity” (hazard class 3.6),
— “Reproductive toxicity” (hazard class 3.7),
— “Specific target organ toxicity — single exposure” (hazard class 3.8),
— “Specific target organ toxicity — repeated exposure” (hazard class 3.9),
— “Aspiration hazard” (hazard class 3.10).
NOTE 2 The classification is detailed in Regulation (EC) No. 1272/2008 [1] (Annex I, Part 3: Health Hazards).
4.2 Colourants
4.2.1 Only colourants and colouring materials which are not fulfilling the hazard criteria in 4.1 shall
be used in finger paints.
NOTE A non-exhaustive list of commonly used colourants, subject to meeting purity requirements, is given in
Annex A consisting of colourants falling in one or more of the following categories: Colourants permitted for use in
food and/or cosmetics and other pigments which meet the general requirements of 4.1.
4.2.2 Finger paints shall not contain azo colourants that by cleavage of one or more azo groups can
produce the primary aromatic amines listed in Tables 1 and 2 when tested in accordance with the test
method specified in Annex D.
4.3 Preservatives
Finger paints shall be preserved using only the preservatives listed in Annex B. The determination of
preservatives shall be in accordance with the methods approved under EU Cosmetics Legislation, where
available (see Directive 82/434/EEC [6], Directive 83/514/EEC [7], Directive 85/490/EEC [8],
Directive 93/73/EEC [9], Directive 95/32/EC [10], Directive 96/45/EC [11]). When tested in
accordance with these methods, the maximum concentrations specified in the column ”maximum
allowed concentration” of Table B.1 and the limitations and requirements specified in the column
”Limitations and requirements” of Table B.1 shall be observed.
4.4 Migration of certain elements
When tested in accordance with EN 71-3 the concentration of elements shall not exceed the limit values
specified in EN 71-3.
4.5 Limits for impurities
4.5.1 Limits for primary aromatic amines
4.5.1.1 The primary aromatic amines listed in Table 1 shall not be determinable when tested in
accordance with the test method in Annex D.
Table 1 — Primary aromatic amines
Primary aromatic amines CAS number
Benzidine 92–87–5
2-Naphthylamine 91–59–8
95–69–2
4-Chloro-2-methyl-aniline (4-Chloro-o-
toluidine)
4-Aminobiphenyl 92–67–1
4.5.1.2 Finger paints shall not contain carcinogenic primary aromatic amines (see Table 2 for a non-
exhaustive list of relevant substances) in a total amount exceeding 20 mg/kg, with no individual
primary aromatic amine exceeding 10 mg/kg, when tested in accordance with Annex D. The limitation
does not apply to aromatic aminocarboxylic acids or aminosulfonic acids.
Table 2 — Other carcinogenic primary aromatic amines (non-exhaustive list)
Carcinogenic primary aromatic amine CAS number
o-Aminoazotoluene (4-o-tolyazo-o-toluidine) 97–56–3
2-Amino-4-nitro-toluene (5-Nitro-o-toluidine) 99–55–8
4-Chloroaniline 106–47–8
2,4-Diaminoanisole 615–05–4
4,4'-Diaminodiphenylmethane (4,4'-Methylenedianiline) 101–77–9
a 91–94–1
3,3'-Dichlorobenzidine
3,3'-Dimethoxybenzidine 119–90–4
3,3'-Dimethylbenzidine 119–93–7
3,3'-Dimethyl-4,4'-diaminodiphenylmethane 838–88–0
p-Cresidine (6-Methoxy-m-toluidine) 120–71–8
101–14–4
2,2’-Dichloro-4,4’-methylenedianiline
(4,4'-Methylene-bis-2-chloroaniline)
4,4'-Oxydianiline 101–80–4
4,4'-Thiodianiline 139–65–1
o-Toluidine 95–53–4
2,4-Xylidine 95–68–1
2,6-Xylidine 87–62–7
4-Amino-3-fluorophenol 399–95–1
6-Amino-2-ethoxynaphthalene 293733–21–8
2-Methoxyaniline (o-anisidine) 90–04–0
4-Aminoazobenzene 60–09–3
4-Methyl-m-phenylenediamine 95–80–7
(Toluene-2,4-diamine)
2,4,5-Trimethylaniline 137–17–7
Aniline 62–53–3
a
%For certain pigments limit values for 3,3’-Dichlorobenzidine are given in
Annex A&.
4.5.2 Limits for other impurities
Finger paints shall not contain the impurities specified in Table 3, column 1 above the limits specified in
column 2 when colourants specified in Table 3, column 3 are used, when tested in accordance with
Annex E.
Table 3 — Impurities in finger paints
Impurity Limit Finger paints of concern
mg/kg
Polychlorinated 2 Finger paints containing
biphenyls colourant products
containing chlorine or
manufactured in chlorinated
solvents
Hexachlorobenzene 5 Finger paints containing
colourant products
containing chlorine or
manufactured in chlorinated
solvents
Benzo (a) pyrene 0,05 Only for finger paints
containing carbon black
4.6 Taste and smell
Finger paints shall not be sweetened, flavoured or fragranced.
An embittering agent in accordance with the following list (see Table 4) shall be added in order to
discourage and minimize the ingestion of paint. The bitterness shall stay in the product during product
lifetime.
The bitterness should be sensorically detectable in a dilution with water 1:100.
Table 4 — Embittering agents
Embittering agent CAS number
Naringin CAS 10236–47–2
%Denatonium benzoate& CAS 3734–33–6
NOTE The relative bitterness of these substances is approximately 1:3000 (naringin : denatonium benzoate).
The following levels have been found suitable: naringin 1 %; denatonium benzoate 0,0004 % (4 mg/kg).
4.7 pH-value
The pH-value of the finger paint shall be between 4,0 and 10,0 when tested in accordance with
EN ISO 787-9.
4.8 Binding agents, extenders, humectants and surfactants
Only binding agents, extenders, humectants and surfactants which are not fulfilling the hazard criteria in
4.1 shall be used in finger paints.
NOTE 1 See Annex C for a list of compounds known to be commonly used.
NOTE 2 The classification is detailed in Regulation (EC) No. 1272/2008 [1] (Annex I, Part 3: Health Hazards).
4.9 N-Nitrosamines
When tested in accordance with EN 71-12 the concentration of N-nitrosamines shall not exceed the
limit values specified in EN 71-12.
4.10 Containers
The containers used for finger paints shall not possess a form, odour, colour, appearance, packaging,
labelling, volume or size, such that it is likely that consumers, especially children, will confuse them
with foodstuffs and in consequence place them or the finger paints in their mouths, or suck or ingest
them.
5 Product information
5.1 General
Markings shall be clearly visible, easily legible, indelible, understandable and accurate. All markings
shall be in the national language(s) of the country(ies) of sale.
NOTE EN 71–1 contains further marking requirements.
If the container is also the primary packaging all information under 5.2.1 shall also be given on the
container. All information shall draw the attention of users or their supervisors to the inherent hazards
and risks of harm involved in using the finger paint and to the way of avoiding such hazards and risks.
5.2 Marking
5.2.1 Primary packaging
NOTE Primary packaging is referred to as consumer packaging in Directive 2009/48/EC or as outer
packaging in Regulation EC No. 1272/2008.
5.2.1.1 Manufacturer's identification
The primary packaging shall bear the name, trade name and/or trade mark and the address of the
manufacturer, his authorized representative or the importer.
5.2.1.2 Labelling phrases
The primary packaging shall carry the following warning:
“Warning. Children under 3 years of age should be supervised by adults.”
The word “Warning” may be followed by, e.g. an exclamation mark or other punctuation marks. The
word “Warning” may be written in capital letters.
!NOTE H- and P-phrase information specified in Regulation (EC) No. 1272/2008 [1] can be required by
certain dangerous substances and dangerous mixtures supplied in the finger paint (e.g. EuH 208 on
sensitization)."
Finger paints supplied in powder form shall additionally bear the following warning:
!“Warning. Mix with water in accordance with the instructions before giving to a child. Avoid
inhalation of the powder.”"
Finger paints supplied in powder form should bear instructions that indicate how to mix with water and
in particular, the correct ratio of water to powder. This information may alternatively be placed in
documentation supplied with the toy.
Additionally there shall be information included for finger paints supplied as a powder to avoid
inhalation of the powder.
5.2.1.3 Indication of preservative(s) and embittering agent(s)
The primary packaging shall be labelled with an indication of the preservative(s) and embittering
agent(s) used.
Preservatives shall be identified by their chemical name or INCI (name) or E-number, where available.
5.2.2 Container
The container shall bear the name, trade name and/or trade mark and the address of the manufacturer,
his authorized representative or the importer.
Manufacturers shall ensure that their toys bear a type, batch, serial or model number or other element
allowing their identification, or, where the size or nature of the toy does not allow it, that the required
information is provided on the packaging or in a document accompanying the toy.
Annex A
(informative)
Non-exhaustive list of colourants which are commonly used in finger paints,
and need to be in compliance with both the general and specified purity
requirements
General Requirements
The colourants used in the manufacture of finger paints should be of technical quality and a purity
suitable for the intended use. !Deleted text."
Specific Requirements
When using the colourants of Table A.1 in finger paints it is important to apply the restrictions and
specifications set out in column 6 of this table. #Certain restrictions, e.g. those referring to Regulation
(EC) No 1223/2009, may mean that the particular colourant is unsuitable for use in a finger paint.$
Table A.1 — Organic colourants which are commonly used in finger paints
a
No. Colour CI number CAS number Restrictions, specifications
C.I. Generic Name
and information
b
1 Yellow Pigment Yellow 1 11680 2512–29–0
See footnote
Amine limits.
e
Excess coupling component
less than 1 000 ppm
b
2 Pigment Yellow 3 11710 6486–23–3
See footnote
Amine limits.
e
Excess coupling component
less than 1 000 ppm
3 Pigment Yellow 12 21090 6358–85–6 3,3’-
dichlorobenzidine ≤ 5 mg/kg
d
4 Pigment Yellow 13 21100 5102–83–0 See footnote
3,3’-
dichlorobenzidine ≤ 5 mg/kg
5 Pigment Yellow 14 21095 5468–75–7 3,3’-
dichlorobenzidine ≤ 5 mg/kg
6 Pigment Yellow 17 21105 4531–49–1 3,3’-
dichlorobenzidine ≤ 5 mg/kg
7 Pigment Yellow 74 11741 6358–31–2 Amine limits.
e
Excess coupling component
less than 1 000 ppm
8 Pigment Yellow 138 56300 30125–47–4
a
No. Colour CI number CAS number Restrictions, specifications
C.I. Generic Name
and information
9 Yellow Pigment Yellow 139 56298 36888–99–0
10 Pigment Yellow 151 13980
11 Pigment Yellow 154 11781 68134–22–5 Amine limits.
e
Excess coupling component
less than 1 000 ppm
12 Pigment Yellow 155 200310 68516–73–4
13 Pigment Yellow 185 56290 76199–85–4
14 Natural Yellow 3 75300 458–37–7 E 100
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
15 Natural Yellow 6 75100 27876–94–4
16 Natural Yellow 26 75130 E 160 a
“Food Orange 5” Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
17 Natural Yellow 27 75135 502–65–8 E 160 d
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
18 Orange Pigment Orange 13 21110 3520–72–7 Amine limits and coupling
e
component limits
Combinations with Pigment
Black 7 shall be checked for
release of 3,3’ dichlorobenzene
3,3’-
dichlorobenzidine ≤ 5 mg/kg
19 Pigment Orange 34 21115 15793–73–4 Amine limits and coupling
e
component limits
Combinations with Pigment
Black 7 shall be checked for
release of 3,3’ dichlorobenzene
3,3’-
dichlorobenzidine ≤ 5 mg/kg
b
20 Orange Pigment Orange 43 71105 4424–06–0 See footnote
21 Pigment Orange 71 561200 86432–50–8
22 Pigment Orange 73 56117 84632–59–7
23 Natural Orange 4 75120 1393–63–1 E 160 b
Food grade, see current
a
No. Colour CI number CAS number Restrictions, specifications
C.I. Generic Name
and information
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
24 Red Pigment Red 48:2 c 7023–61–2
15865:2
c
25 Pigment Red 57:1 15850:1 5281–04–9
26 Pigment Red 63:1 15880:1 6417–83–0
27 Pigment Red 68 15525 5850–80–6
28 Pigment Red 83 58000:1 104074–25–1
d
29 Pigment Red 122 73915 980–26–7 See footnote
30 Pigment Red 181 73360 2379–74–0
31 Pigment Red 214 200660 82643–43–4
32 Pigment Red 242 20067 52238–92–3
33 Pigment Red 254 56110 84632–65–5
34 Pigment Red 255 561050 54660–00–3
35 Pigment Red 264 561300
36 Pigment Red 272 561150
37 Natural Red 4 75470 1390–65–4, E 120
1260–17–9
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
d
38 Violet Pigment Violet 19 73900 1047–16–1 See footnote
d
39 Pigment Violet 23 51319 215247–95–3, See footnote
6358–30–1
40 Blue Pigment Blue 15 74160 147–14–8, Limits as specified in existing
12239–87–1, chemical regulations in EU (see
27614–71–7, reg. (EC) No. 1709/2006
68987–63–3, “REACH, Annex XVII)
16040–69–0 respectively EU member states
Pigment Blue 15:2 and 15:4 are
surface treated. Before using
surface treated substances,
manufacturers are well advised
to contact their suppliers
regarding composition and
hazards.
d
41 Pigment Blue 16 74100 574–93–6 See footnote
42 Pigment Blue 60 69800 81–77–6
a
No. Colour CI number CAS number Restrictions, specifications
C.I. Generic Name
and information
b
43 Green Pigment Green 7 74260 1328–53–6 See footnote
44 Pigment Green 36 74265 14302–13–7
45 Natural Green 3 75810 8049–84–1, E 140 and E 141
11006–34–1
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
a
The Colour Index is published by The Society of Dyers and Colourists, PO Box 244, Perkin House 82 Grattan
Road, Bradford, West Yorkshire BD1 2JB, United Kingdom, www.colour-index.org. Colourants are classified using
both their CI Generic name and their constitution number. These relate only to the “essential colourant” as defined
by the Colour Index. The CAS numbers given are also taken from this database and again refer only to the
“essential colourant”.
b
This substance is restricted in Regulation (EC) No 1223/2009 [5] as follows: “Not to be used in eye products”
or “Not to be used in products applied to mucous membranes”, as applicable.
c
The insoluble barium, strontium and zirconium lakes, salts and pigments of these colourants are also
permitted. According to Directive 2009/48/EC requirements on these elements need to be taken in consideration.
d
This substance is restricted in Regulation (EC) No 1223/2009 [5] as follows: ” Rinse-off products”.
e
Azo colourants are typically formed by a reaction sequence of diazotisation of a primary aromatic amine which
is referred to as the diazo component, followed by reaction (aka coupling) with a compound having active
methylene groups referred to as a coupling component.
Table A.2 — Non organic colourants which are commonly used in finger paints
No. Colour a CI number CAS number Restrictions, specifications
C.I. Generic Name
and information
46 Yellow Pigment Yellow 42 77492 51274–00–1 Iron oxide yellow
E 172
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
47 Red Pigment Red 101 77491 1309–37–1 E 172
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
48 Blue Pigment Blue 29 77007 1317–97–1, Ultramarine
57455–37–5
49 White Pigment White 4 77947 1314–13–2 Zinc Oxide
50 Pigment White 6 77891 13463–67–7 E 171
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
51 Pigment White 18 77220 207–439–9, E 170
208–915–9
Chalk
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
Mixture Calcium carbonate,
Magnesium carbonate
52 Pigment White 19 77004, 8047–76–5 Aluminium silicate, hydrated
53 Silver 77820 E 174
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
54 Pigment White 21 77120 7727–43–7 Blancfixe
55 Pigment White 25 77231 91315–45–6 Gypsum
56 Aluminium, zinc, -
magnesium and
calcium stearates
57 Black Pigment Black 6 77266 1333–86–4 Carbon black
food contact quality
58 Pigment Black 7 77266 1333–86–4 Carbon black
food contact quality
59 Pigment Black 11 77499 12227–89–3 E 172
Food grade, see current
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
60 Brown Pigment Metal 3 77480 7440–57–5 E 175
Gold
Food grade, see current
European legislation
%Commission Regulation
(EU) No 231/2012 [15].&)
61 Orange Ferrous oxide 77489 Ferrous oxide E 172 (Mix)
Not in CI
Food grade, see current
online
European legislation
(%Commission Regulation
(EU) No 231/2012 [15].&)
a
The Colour Index is published by The Society of Dyers and Colourists, PO Box 244, Perkin House 82 Grattan
Road, Bradford, West Yorkshire BD1 2JB, United Kingdom, www.colour-index.org. Colourants are classified using
both their CI Generic name and their constitution number. These relate only to the “essential colourant” as defined
by the Colour Index. The CAS numbers given are also taken from this database and again refer only to the
“essential colourant”.
Annex B
(normative)
List of preservatives allowed for use in finger paints
!
Table B.1 — Preservatives
Ref. Substance EC-Number CAS-Number Maximum allowed Limitations and
nr. concentration requirements
1 Benzoic acid 200–618–2, 65–85–0, 0,5 % (acid)
sodium benzoate 208–534–8 532–32–1
2 Ammonium benzoate, 217–468–9, 1863–63–4, 0,5 % (acid)
calcium benzoate, 218–235–4, 2090–05–3,
potassium benzoate, 209–481–3, 582–25–2,
magnesium benzoate, 209–045–2, 553–70–8,
MEA-benzoate, 224–387–2, 4337–66–0,
methyl benzoate, 202–259–7, 93–58–3,
ethyl benzoate, 202–284–3, 93–89–0,
propyl benzoate 219–020–8, 2315–68–6,
butyl benzoate, 205–252–7, 136–60–7,
isobutyl benzoate, 204–401–3, 120–50–3,
isopropyl benzoate, 213–361–6, 939–48–0,
phenyl benzoate 202–293–2 93–99–2
3 Propionic acid, 201–176–3, 79–09–4, 2 % (acid)
ammonium propionate, 241–503–7, 17496–08–1,
calcium propionate, 223–795–8, 4075–81–4,
magnesium propionate, 209–166–0, 557–27–7,
potassium propionate, 206–323–5, 327–62–8,
sodium propionate 205–290–4 137–40–6
4 Hexa-2,4-dienoic acid and 203–768–7, 110–44–1, 0,6 % (acid)
its salts: 231–321–6, 7492–55–9,
Sorbic acid, 231–819–3, 7757–81–5,
calcium sorbate, 246–376–1 24634–61–5
sodium sorbate,
potassium sorbate
5 Biphenyl-2-ol (o- 201–993–5 90–43–7, 0,2 % expressed as the
Phenylphenol) 205–055–6, 132–27–4, phenol
sodium o-phenylphenate, 237–243–9, 13707–65–8,
potassium o- 282–227–7 84145–04–0
phenylphenate,
MEA o-phenylphenate
Ref. Substance EC-Number CAS-Number Maximu
...
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