Fuel cell technologies - Part 6-107: Micro fuel cell power systems - Safety - Indirect water-reactive (Division 4.3) compounds

Technologies des piles à combustible - Partie 6-107: Systèmes à micropiles à combustible - Sécurité - Composés hydroréactifs indirects (division 4.3)

Tehnologije gorivnih celic - 6-107. del: Elektroenergetski sistemi z mikro gorivnimi celicami - Varnost - Trdne spojine, ki reagirajo z vodo (del 4.3)

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Status
Not Published
Public Enquiry End Date
16-Mar-2023
Technical Committee
Current Stage
4020 - Public enquire (PE) (Adopted Project)
Start Date
04-Jan-2023
Due Date
24-May-2023
Completion Date
11-May-2023

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SLOVENSKI STANDARD
oSIST prEN IEC 62282-6-107:2023
01-marec-2023
Tehnologije gorivnih celic - 6-107. del: Elektroenergetski sistemi z mikro gorivnimi
celicami - Varnost - Trdne spojine, ki reagirajo z vodo (del 4.3)
Fuel cell technologies - Part 6-107: Micro fuel cell power systems - Safety - Indirect
water-reactive (Division 4.3) compounds
Ta slovenski standard je istoveten z: prEN IEC 62282-6-107:2022
ICS:
27.070 Gorilne celice Fuel cells
oSIST prEN IEC 62282-6-107:2023 en
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.

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oSIST prEN IEC 62282-6-107:2023

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oSIST prEN IEC 62282-6-107:2023
105/951/CDV

COMMITTEE DRAFT FOR VOTE (CDV)
PROJECT NUMBER:
IEC 62282-6-107 ED1
DATE OF CIRCULATION: CLOSING DATE FOR VOTING:
2022-12-23 2023-03-17
SUPERSEDES DOCUMENTS:
105/809/CD, 105/823/CC

IEC TC 105 : FUEL CELL TECHNOLOGIES
SECRETARIAT: SECRETARY:
Germany Mr David Urmann
OF INTEREST TO THE FOLLOWING COMMITTEES: PROPOSED HORIZONTAL STANDARD:


Other TC/SCs are requested to indicate their interest, if any, in this
CDV to the secretary.
FUNCTIONS CONCERNED:
EMC ENVIRONMENT QUALITY ASSURANCE SAFETY
SUBMITTED FOR CENELEC PARALLEL VOTING NOT SUBMITTED FOR CENELEC PARALLEL VOTING
Attention IEC-CENELEC parallel voting
The attention of IEC National Committees, members of CENELEC,
is drawn to the fact that this Committee Draft for Vote (CDV) is
submitted for parallel voting.
The CENELEC members are invited to vote through the CENELEC
online voting system.

This document is still under study and subject to change. It should not be used for reference purposes.
Recipients of this document are invited to submit, with their comments, notification of any relevant patent rights of which they are aware
and to provide supporting documentation.

TITLE:
Fuel cell technologies – Part 6-107: Micro fuel cell power systems – Safety – Indirect water-reactive (Division 4.3)
compounds

PROPOSED STABILITY DATE: 2026

NOTE FROM TC/SC OFFICERS:


Copyright © 2022 International Electrotechnical Commission, IEC. All rights reserved. It is permitted to download this
electronic file, to make a copy and to print out the content for the sole purpose of preparing National Committee positions.
You may not copy or "mirror" the file or printed version of the document, or any part of it, for any other purpose without
permission in writing from IEC.

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oSIST prEN IEC 62282-6-107:2023
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CONTENTS

FOREWORD . 3
INTRODUCTION . 5
1 Scope . 6
1.1 Fuels and technologies covered by this part . 6
2 Normative references . 6
3 Terms and definitions . 6
4 Safety Principles. 7
5 General safety requirements . 7
5.1 General . 7
5.2 Chemical Safety Requirements . 7
5.3 Material requirements . 8
5.4 Mechanical design requirements . 8
5.4.1 General . 8
5.4.2 Micro fuel cell power system . 9
5.4.3 Fuel cartridge . 9
5.4.4 Fuel valves and connections . 9
5.4.5 Electrical requirements . 9
5.4.6 FMEA . 9
5.4.7 Functional safety requirements . 9
5.4.8 Small parts . 9
6 Abnormal operating and fault conditions testing and requirements . 9
7 Instructions and warnings for micro fuel cell power systems and fuel cartridges . 9
8 Type tests for micro fuel cell power systems and fuel cartridges . 10
8.1 General . 10
8.2 Leakage and gas loss measurement protocols . 10
8.2.1 General . 10
8.3 Type tests . 11
8.3.1 Pressure differential tests . 11
8.3.2 Vibration Test . 11
8.3.3 Temperature cycling test . 11
8.3.4 High temperature exposure test . 11
8.3.5 Drop test . 11
8.3.6 Compressive loading test . 12
8.3.7 External short-circuit test . 12
8.3.8 Surface, component and exhaust gas temperature test . 12
8.3.9 Long-term storage test . 12
8.3.10 High temperature connection test . 12
8.3.11 Connection cycling tests . 12
Gas loss tests . 12

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oSIST prEN IEC 62282-6-107:2023
IEC CDV 62282-6-107  IEC 2022 – 3 –
INTERNATIONAL ELECTROTECHNICAL COMMISSION
____________

FUEL CELL TECHNOLOGIES –

Part 6-107: Micro fuel cell power systems – Safety –
Indirect water-reactive (Division 4.3) compounds

FOREWORD
1) The International Electrotechnical Commission (IEC) is a worldwide organization for standardization comprising
all national electrotechnical committees (IEC National Committees). The object of IEC is to promote international
co-operation on all questions concerning standardization in the electrical and electronic fields. To this end and
in addition to other activities, IEC publishes International Standards, Technical Specifications, Technical Reports,
Publicly Available Specifications (PAS) and Guides (hereafter referred to as “IEC Publication(s)”). Their
preparation is entrusted to technical committees; any IEC National Committee interested in the subject dealt with
may participate in this preparatory work. International, governmental and non-governmental organizations liaising
with the IEC also participate in this preparation. IEC collaborates closely with the International Organization for
Standardization (ISO) in accordance with conditions determined by agreement between the two organizations.
2) The formal decisions or agreements of IEC on technical matters express, as nearly as possible, an international
consensus of opinion on the relevant subjects since each technical committee has representation from all
interested IEC National Committees.
3) IEC Publications have the form of recommendations for international use and are accepted by IEC National
Committees in that sense. While all reasonable efforts are made to ensure that the technical content of IEC
Publications is accurate, IEC cannot be held responsible for the way in which they are used or for any
misinterpretation by any end user.
4) In order to promote international uniformity, IEC National Committees undertake to apply IEC Publications
transparently to the maximum extent possible in their national and regional publications. Any divergence between
any IEC Publication and the corresponding national or regional publication shall be clearly indicated in the latter.
5) IEC itself does not provide any attestation of conformity. Independent certification bodies provide conformity
assessment services and, in some areas, access to IEC marks of conformity. IEC is not responsible for any
services carried out by independent certification bodies.
6) All users should ensure that they have the latest edition of this publication.
7) No liability shall attach to IEC or its directors, employees, servants or agents including individual experts and
members of its technical committees and IEC National Committees for any personal injury, property damage or
other damage of any nature whatsoever, whether direct or indirect, or for costs (including legal fees) and
expenses arising out of the publication, use of, or reliance upon, this IEC Publication or any other IEC
Publications.
8) Attention is drawn to the Normative references cited in this publication. Use of the referenced publications is
indispensable for the correct application of this publication.
9) Attention is drawn to the possibility that some of the elements of this IEC Publication may be the subject of patent
rights. IEC shall not be held responsible for identifying any or all such patent rights.
International Standard IEC 62282-6-107 has been prepared by IEC technical committee 105:
Fuel cell technologies
The Second Edition of IEC 62282-6-101 and the other new parts of the IEC 62282-6 series
cancel and replace IEC 62282-6-100 published in 2010. This constitutes a technical revision.
The main changes with respect to the previous edition are as follows:
a) IEC 62282-6 series has been restructured and split in such a way as to have general
requirements for the safety of micro fuel cell power systems within IEC 62282-6-101, and
the specific requirements for the individual fuel types within the other parts of the
IEC 62282-6-1XX series.

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– 4 – IEC CDV 62282-6-107  IEC 2022
The text of this standard is based on the following documents:
FDIS Report on voting
105/XX/FDIS 105/XX/RVD

Full information on the voting for the approval of this International Standard can be found in the
report on voting indicated in the above table.
This document has been drafted in accordance with the ISO/IEC Directives, Part 2.
A list of all parts of the IEC 62282 series, under the general title Fuel cell technologies, can be
found on the IEC website.
The committee has decided that the contents of this document will remain unchanged until the
stability date indicated on the IEC website under "http://webstore.iec.ch" in the data related to
the specific document. At this date, the document will be
• reconfirmed,
• withdrawn,
• replaced by a revised edition, or
• amended.
NOTE The attention of National Committees is drawn to the fact that equipment manufacturers and testing
organizations may need a transitional period following publication of a new, amended or revised IEC publication in
which to make products in accordance with the new requirements and to equip themselves for conducting new or
revised tests.
It is the recommendation of the committee that the content of this publication be adopted for implementation nationally
not earlier than 12 months from the date of publication.
A bilingual version of this publication may be issued at a later date.

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oSIST prEN IEC 62282-6-107:2023
IEC CDV 62282-6-107  IEC 2022 – 5 –
1 INTRODUCTION
2 Part 107 provides additional requirements, specific to water-reactive fuel formulations, which
3 apply in addition to the general requirements prescribed by IEC 62282-6-101. Part 107 is
4 intended to be used together with IEC 62282-6-101, and shall not be utilized as a stand-alone
5 standard.
6 Clause and subclause numbers in this part are aligned with IEC 62282-6-101, and are intended
7 to provide additional information and refined requirements, as appropriate.
8

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9 FUEL CELL TECHNOLOGIES –
10
11 Part 6-107: Micro fuel cell power systems – Safety –
12 Indirect water-reactive (Division 4.3) compounds
13
14
15
16 Scope
17 1.1 Fuels and technologies covered by this part
18 Part 107 covers micro fuel cell power systems, micro fuel cell power units and fuel cartridges
19 using hydrogen produced from water-reactive (UN Division 4.3) compounds as fuel. These
20 systems and units use proton exchange membrane fuel cell technologies. The designs may
21 include fuel processing subsystems to derive hydrogen gas from the water-reactive fuel
22 formulation.
23 This Part 107 only applies to water reactive (UN Division 4.3) solid compounds which solely
24 evolve hydrogen gas upon contact with water (or non-hazardous aqueous solutions). This Part
25 107 does not include compounds with a subsidiary hazard risk, or which are not permitted to
26 be transported by air according to the ICAO Technical Instructions.
27 Figure 1 from IEC 62282-6-101 continues to apply.
28 Normative references
29 The normative references included in Clause 2 of IEC 62282-6-101 apply in their entirety to
30 technologies included in Part 107.
31 Terms and definitions
32 The terms and definitions below modify and augment those corresponding terms and definitions
33 in Clause 3 of Part 101 for micro fuel cell power systems and fuel cartridges covered by this
34 Part 107. All terms and definitions in Clause 3 not specifically mentioned here also apply.
35 3.1
36 fuel
37 water-reactive (UN Division 4.3) solid formulation of compounds comprising constituents
38 selected from the following group used as fuel for an indirect PEM micro fuel cell power system:
39 (water reactive) mixtures, metals, alloys, compounds or chemical hydrides of the following
40 materials: sodium, calcium, magnesium, borohydride compounds, silicon, silicon dioxide, iron,
41 nickel, cobalt, aluminium.
42 The formulation may contain a non-hazardous activator to facilitate the production of hydrogen,
43 and/or a stabilizer to modulate or inhibit the production of hydrogen.
44 3.2
45 borohydride compounds
46 sodium or potassium borohydride, or a mixture thereof
47 3.3
48 liquid fuel component
49 Class 8 (corrosive), or non-hazardous, aqueous solutions, which may contain activators,
50 inhibitors, or freezing point suppressors

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IEC CDV 62282-6-107  IEC 2022 – 7 –
51 Note 1 to entry: The liquid fuel components are used to react with the water-reactive fuel to produce hydrogen.
52 3.4
53 fuel by-products
54 Class 8 (corrosive), or non-hazardous compounds produced after hydrogen and/or electricity is
55 produced from fuel
56 3.5
57 activator
58 a substance that facilitates the production of hydrogen from fuel, such as a catalyst
59 3.6
60 stabilizer
61 a substance that modulates or inhibits the production of hydrogen from fuel
62 Safety Principles
63 The safety principles included in Clause 4 of IEC 62282-6-101 apply in their entirety to
64 technologies included in Part 107.
65 General safety requirements
66 5.1 General
67 The general safety requirements of Subclause 5.1 of Part 101 shall apply as written.
68 NOTE The limited quantity exception for cargo transport of fuel cell cartridges containing water reactive fuel is 500
69 grams of solid fuel according to the UN Model Regulations. For passenger carriage in the aircraft cabin or in checked
70 baggage the maximum quantity of water reactive fuel permitted inside the cartridge is 200 grams of solid fuel
71 according to the 2013 edition of the ICAO Technical Instructions.
72 5.2 Chemical Safety Requirements
73 Consistent with Part 101, the following limits shall apply for emission and gas loss
74 measurements for micro fuel cell power systems and fuel cartridges tested under this Part 107.

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a b c
Constituent
Concentration limit Gas loss rate limit Gas loss rate limit
(OPERAT
...

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