ASTM D5564-95(2001)

Standard Test Method for Determination of the Total Ammonia Contained in Sulfonated or Sulfated Oils

SCOPE
1.1 This test method covers determination of the total ammonia contained in sulfonated or sulfated oils.
1.2 The values stated in SI units are to be regarded as the standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

General Information

• Status: Historical
• Publication Date: 14-May-1995
• ICS: 71.080.99 - Other organic chemicals
• Technical Committee: D31 - Leather
• Drafting Committee: D31.08 - Fats and Oils

Relations

• Replaces: ASTM D5564-95 - Standard Test Method for Determination of the Total Ammonia Contained in Sulfonated or Sulfated Oils
• Effective Date: 15-May-1995
• Replaced By: ASTM D5564-95(2006) - Standard Test Method for Determination of the Total Ammonia Contained in Sulfonated or Sulfated Oils
• Effective Date: 01-Apr-2006

Standards Content (Sample)

NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D5564–95 (Reapproved 2001)
Standard Test Method for
Determination of the Total Ammonia Contained in
Sulfonated or Sulfated Oils
This standard is issued under the fixed designation D 5564; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
1. Scope
1.1 This test method covers determination of the total
ammonia contained in sulfonated or sulfated oils.
1.2 The values stated in SI units are to be regarded as the
standard.
1.3 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the
responsibility of the user of this standard to establish appro-
priate safety and health practices and determine the applica-
bility of regulatory limitations prior to use.
2. Referenced Documents
2.1 ASTM Standards:
D 500 Test Methods for Chemical Analysis of Sulfonated
and Sulfated Oils
D 5350 Test Method for Determination of Organically
Combined Sulfuric Anhydride by Titration, Test Method
A
FIG. 1 Apparatus for Determination of Organically Combined
Sulfuric Anhydride, Method A
3. Significance and Use
3.1 This test method of analysis is intended to determine the
4.1.2 Condenser, consisting of a glass tube, 915 mm (36 in.)
totalammoniainasampleofsulfonatedorsulfatedoil,orboth,
in length and 8 mm ( ⁄16 in.) in outside diameter.The lower end
by boiling a water solution of the sample with excess alkali and
of the tube shall be flared and ground to fit the mouth of the
determining by titration the loss in alkali after the boiling.
Erlenmeyer flask.
4.1.3 Glass Beads—Perforated glass beads, made of chemi-
4. Apparatus
cally resistant glass, approximately 4 mm ( ⁄32 in.) in diameter.
4.1 The apparatus required consists of a glass flask provided
Before using, the glass beads shall be boiled thoroughly in
with a glass stopper and an air condenser. The connection
several portions of water or until the wash water reacts neutral
between the flask and the condenser shall be a ground joint.
to a methyl orange indicator.
Perforated glass beads shall be used to prevent bumping.
4.1.1 Flask—An Erlenmeyer flask (Fig. 1) made of a
5. Reagents
borosilicate glass, having a capacity of approximately 300 mL
5.1 Ethyl Ether.
and provided with a glass stopper.
5.2 Methyl Orange Indicator Solution (1 g/L)—Dissolve
0.1 g of methyl orange in 100 mL of water.
1 5.3 Sodium Chloride (NaCl), solid.
This test method is under the jurisdiction ofASTM Committee D31 on Leather
5.4 Sodium Hydroxide, Standard Solution (1 N)—
and is the direct responsibility of Subcommittee D31.08 on Fats and Oils. This test
method was developed in cooperation with the American Leather Chemists Assn.
Accurately prepare and standardize a 1 N sodium hydroxide
(Method H 49-1957).
(NaOH) solution. Express the strength or concentration of the
Current edition approved May 15, 1995. Published July 1995. Originally
solution as mg of KOH per mL; 1 mL of 1 N NaOH solution
published as D 5564 – 94. Last previous edition D 5564 – 94.
Annual Book of ASTM Standards, Vol 15.04. is equivalent to 56.1 mg of KOH.
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
D5564
5.5 Sodium Hydroxide, Standard Solution (0.5 N)— Accu- 7. Calculation
rately prepare and sta
...