Standard Specification for 2-Bromo-3,3,3-Trifluoro-1-Propene (CF<inf>3</inf>CBr=CH<inf >2</inf>)

ABSTRACT
This specification applies to 2-Bromo-3, 3,3-Trifluoro-1-Propene (‘2-BTP’) as a fire-fighting medium. It does not address the fire-fighting equipment or hardware that employs 2-BTP or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.). The storage or transportation of 2-BTP is also not covered.
This specification covers material requirements, sampling, test methods (purity, acidity, water content, nonvolatile residue, suspended matter or sediment, stabilizers), and container, packaging, and package marking.
SCOPE
1.1 This specification covers requirements for 2-Bromo-3,3,3-Trifluoro-1-Propene (“2-BTP”) as a fire-fighting medium.  
1.2 This specification does not address the fire-fighting equipment or hardware that employs 2-BTP or the conditions of employing such equipment (for example, handhelds, fixed installations, etc.).  
1.3 This specification does not address the storage or transportation of 2-BTP. Storage, handling, and transportation issues are addressed in Practice D8061.  
1.4 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.  
1.5 The following safety hazards caveat pertains only to the test methods portion, Section 6, of this specification:  
1.5.1 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific hazards statements are given in Section 4.

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Historical
Publication Date
30-Jun-2016
Current Stage
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Technical specification
ASTM D8060-16 - Standard Specification for 2-Bromo-3,3,3-Trifluoro-1-Propene (CF<inf>3</inf>CBr=CH<inf >2</inf>)
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NOTICE: This standard has either been superseded and replaced by a new version or withdrawn.
Contact ASTM International (www.astm.org) for the latest information
Designation:D8060 −16
Standard Specification for
1
2-Bromo-3,3,3-Trifluoro-1-Propene (CF CBr=CH )
3 2
This standard is issued under the fixed designation D8060; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
4
1. Scope 2.3 U.S. Government Standard:
CFR Title 49, Part 172, Subpart D U.S. Department of
1.1 This specification covers requirements for 2-Bromo-3,
Transportation (DOT), Marking Requirements of Packag-
3,3-Trifluoro-1-Propene (“2-BTP”) as a fire-fighting medium.
ing for Transportation
1.2 This specification does not address the fire-fighting 5
2.4 AHRI Standard:
equipment or hardware that employs 2-BTP or the conditions
2008 Appendix C for Analytical Procedures for AHRI
of employing such equipment (for example, handhelds, fixed
Standard 700-2014
installations, etc.).
3. Terminology
1.3 This specification does not address the storage or
3.1 Definitions of Terms Specific to This Standard:
transportation of 2-BTP. Storage, handling, and transportation
3.1.1 2-BTP, n—2-Bromo-3,3,3-Trifluoro-1-Propene
issues are addressed in Practice D8061.
(CF CBr=CH ); a compound used to inert, extinguish, or
3 2
1.4 The values stated in inch-pound units are to be regarded
suppress a fire or explosion hazard.
as standard. The values given in parentheses are mathematical
3.1.1.1 Discussion—The terminology system for fluorine-
conversions to SI units that are provided for information only
containing compounds (described in detail in ASHRAE Stan-
and are not considered standard.
dard34)providesaconvenientmeanstoreferencethestructure
1.5 The following safety hazards caveat pertains only to the
of individual compounds. By definition for unsaturated
test methods portion, Section 6, of this specification:
compounds, the first digit of the numbering system represents
1.5.1 This standard does not purport to address all of the
the number of unsaturated bonds; the second digit represents
safety concerns, if any, associated with its use. It is the
one less than the number of carbon atoms in the compound
responsibility of the user of this standard to establish appro-
molecule; the third digit, one more than the number of
priate safety and health practices and determine the applica-
hydrogen atoms in the compound molecule; and the fourth
bility of regulatory limitations prior to use. Specific hazards
digit, the number of fluorine atoms in the compound molecule.
statements are given in Section 4.
Unaccounted for valence requirements are assumed to be
chlorine atoms. In those instances where bromine (Br) is
2. Referenced Documents
present in place of part or all of the chlorine, an uppercase
2
2.1 ASTM Standards:
letter B is added after the designation for the parent compound.
D6806 Practice for Analysis of Halogenated Organic Sol-
The number following the letter B represents the number of
vents and Their Admixtures by Gas Chromatography
bromine atoms present. For example, the designation
D8061 Practice for Handling,Transportation, and Storage of
R-1233B1 indicates a compound with one unsaturated bond
2-Bromo-3,3,3-Trifluoro-1-Propene (CF CBr=CH )
3 2 (1), three carbon atoms (2 + 1), two hydrogen atoms (3 - 1),
3
2.2 ASHRAE Standard:
three fluorine atoms (3), and one bromine atom (B1). Since the
ASHRAE 34 Designation and Safety Classification of Re-
number of atoms required based on valence requirements are
frigerants
met, there is no chlorine present. Example: CF CBr=CH is
3 2
equivalent to R-1233B1.
1
This specification is under the jurisdiction of ASTM Committee D26 on
Halogenated Organic Solvents and Fire Extinguishing Agents and is the direct
4. Material Requirements
responsibility of Subcommittee D26.09 on Fire Extinguishing Agents.
4.1 “2-BTP” shall conform to the requirements prescribed
Current edition approved July 1, 2016. Published July 2016. DOI: 10.1520/
D8060-16.
in Table 1 when tested by the appropriate test methods listed in
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Section 6.
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Standards volume information, refer to the standard’s Document Summary page on
4
the ASTM website. Available from U.S. Government Publishing Office, 732 N. Capitol St., NW,
3
Available from American Society of Heating, Refrigerating, and Air- Washington, DC 20401-0001, http://www.gpo.gov.
5
Conditioning Engineers, Inc. (ASHRAE), 1791 Tullie Circle, NE, Atlanta, GA Available from Air-Conditioning, Heating, & Refrigeration Institute, 2111
30329, http://www.ashrae.org. Wilson Blvd., Suite 500, Arlington, VA 22201, http://www.ahrinet.org.
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