ASTM D1319-15
(Test Method)Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
SIGNIFICANCE AND USE
5.1 The determination of the total volume percent of saturates, olefins, and aromatics in petroleum fractions is important in characterizing the quality of petroleum fractions as gasoline blending components and as feeds to catalytic reforming processes. This information is also important in characterizing petroleum fractions and products from catalytic reforming and from thermal and catalytic cracking as blending components for motor and aviation fuels. This information is also important as a measure of the quality of fuels, such as specified in Specification D1655.
SCOPE
1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume % aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315 °C. This test method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.
Note 1: For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D2710.
1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision statement does not apply to narrow boiling petroleum fractions near the 315 °C limit. Such samples are not eluted properly, and results are erratic.
1.3 This test method includes a relative bias section based on Practice D6708 accuracy assessment between Test Method D1319 and Test Method D5769 for total aromatics in spark-ignition engine fuels as a possible Test Method D1319 alternative to Test Method D5769 for U.S. EPA spark-ignition engine fuel regulations reporting. The Practice D6708 derived correlation equation is only applicable for fuels in the total aromatic concentration range from 3.3 % to 34.4 % by volume as measured by Test Method D1319 and the distillation temperature T95, at which 95 % of the sample has evaporated, ranges from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F) when tested according to Test Method D86.
1.3.1 The applicable Test Method D5769 range for total aromatics is 3.7 % to 29.4 % by volume as reported by Test Method D5769 and the distillation temperature T95 values, at which 95 % of the sample has evaporated, when tested according to Test Method D86 is from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F).
1.4 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar sands, has not been determined, and the precision statement may or may not apply to such products.
1.5 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures. The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with a concentration range of 13 to 40 volume percent aromatics, 4 to 33 volume percent olefins, and 45 to 68 volume percent saturates.
1.6 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME), and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed, correct the results to a total-sample basis.
1.7 WARNING—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to mater...
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Designation: D1319 − 15
Standard Test Method for
Hydrocarbon Types in Liquid Petroleum Products by
1
Fluorescent Indicator Adsorption
This standard is issued under the fixed designation D1319; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope* 1.4 The applicability of this test method to products derived
from fossil fuels other than petroleum, such as coal, shale, or
1.1 This test method covers the determination of hydrocar-
tar sands, has not been determined, and the precision statement
bontypesovertheconcentrationrangesfrom5to99volume %
may or may not apply to such products.
aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume %
saturates in petroleum fractions that distill below 315 °C. This
1.5 This test method has two precision statements depicted
test method may apply to concentrations outside these ranges,
in tables. The first table is applicable to unleaded fuels that do
but the precision has not been determined. Samples containing
not contain oxygenated blending components. It may or may
dark-colored components that interfere in reading the chro-
not apply to automotive gasolines containing lead antiknock
matographic bands cannot be analyzed.
mixtures. The second table is applicable to oxygenate blended
(for example, MTBE, ethanol) automotive spark ignition fuel
NOTE 1—For the determination of olefins below 0.3 volume %, other
samples with a concentration range of 13 to 40 volume percent
test methods are available, such as Test Method D2710.
aromatics, 4 to 33 volume percent olefins, and 45 to 68 volume
1.2 This test method is intended for use with full boiling
percent saturates.
range products. Cooperative data have established that the
precisionstatementdoesnotapplytonarrowboilingpetroleum
1.6 The oxygenated blending components, methanol,
fractions near the 315 °C limit. Such samples are not eluted
ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether
properly, and results are erratic.
(TAME), and ethyl-tert-butylether (ETBE), do not interfere
with the determination of hydrocarbon types at concentrations
1.3 This test method includes a relative bias section based
normally found in commercial blends. These oxygenated
on Practice D6708 accuracy assessment between Test Method
components are not detected since they elute with the alcohol
D1319 and Test Method D5769 for total aromatics in spark-
desorbent. Other oxygenated compounds shall be individually
ignition engine fuels as a possible Test Method D1319 alter-
verified. When samples containing oxygenated blending com-
native to Test Method D5769 for U.S. EPA spark-ignition
ponentsareanalyzed,correcttheresultstoatotal-samplebasis.
engine fuel regulations reporting. The Practice D6708 derived
correlation equation is only applicable for fuels in the total
1.7 WARNING—Mercury has been designated by many
aromatic concentration range from 3.3 % to 34.4 % by volume
regulatory agencies as a hazardous material that can cause
as measured by Test Method D1319 and the distillation
central nervous system, kidney and liver damage. Mercury, or
temperature T , at which 95 % of the sample has evaporated,
95
its vapor, may be hazardous to health and corrosive to
ranges from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F) when
materials.Cautionshouldbetakenwhenhandlingmercuryand
tested according to Test Method D86.
mercury containing products. See the applicable product Ma-
1.3.1 The applicable Test Method D5769 range for total
terial Safety Data Sheet (MSDS) for details and EPA’s
aromatics is 3.7 % to 29.4 % by volume as reported by Test
website—http://www.epa.gov/mercury/faq.htm—for addi-
Method D5769 and the distillation temperature T values, at
95
tional information. Users should be aware that selling mercury
which 95 % of the sample has evaporated, when tested
and/or mercury containing products into your state or country
according to Test Method D86 is from 149.1 °C to 196.6 °C
may be prohibited by law.
(300.3 °F to 385.8 °F).
1.8 The values stated in SI units are to be regarded as
standard.
1
This test method is under the jurisdiction of ASTM Committee D02 on
1.8.1 Exception—Inch-pound units in parentheses are pro-
Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of
vided for information only.
Subcommittee D02.04.0C on Liquid Chromatography.
Current edition approved Dec. 1, 2015. Published December 2015. Originally
1.9 This standard does not purport to address all of the
approved in 1954. Last previous edition approved in 2
...
This document is not an ASTM standard and is intended only to provide the user of an ASTM standard an indication of what changes have been made to the previous version. Because
it may not be technically possible to adequately depict all changes accurately, ASTM recommends that users consult prior editions as appropriate. In all cases only the current version
of the standard as published by ASTM is to be considered the official document.
Designation: D1319 − 14 D1319 − 15
Standard Test Method for
Hydrocarbon Types in Liquid Petroleum Products by
1
Fluorescent Indicator Adsorption
This standard is issued under the fixed designation D1319; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (´) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the U.S. Department of Defense.
1. Scope*
1.1 This test method covers the determination of hydrocarbon types over the concentration ranges from 5 to 99 volume %
aromatics, 0.3 to 55 volume % olefins, and 1 to 95 volume % saturates in petroleum fractions that distill below 315°C.315 °C. This
test method may apply to concentrations outside these ranges, but the precision has not been determined. Samples containing
dark-colored components that interfere in reading the chromatographic bands cannot be analyzed.
NOTE 1—For the determination of olefins below 0.3 volume %, other test methods are available, such as Test Method D2710.
1.2 This test method is intended for use with full boiling range products. Cooperative data have established that the precision
statement does not apply to narrow boiling petroleum fractions near the 315°C315 °C limit. Such samples are not eluted properly,
and results are erratic.
1.3 This test method includes a relative bias section based on Practice D6708 accuracy assessment between Test Method D1319
and Test Method D5769 for total aromatics in spark-ignition engine fuels as a possible Test Method D1319 alternative to Test
Method D5769 for U.S. EPA spark-ignition engine fuel regulations reporting. The Practice D6708 derived correlation equation is
only applicable for fuels in the total aromatic concentration range from 3.3 % to 34.4 % by volume as measured by Test Method
D1319 and the distillation temperature T , at which 95 % of the sample has evaporated, ranges from 149.1 °C to 196.6 °C
95
(300.3 °F to 385.8 °F) when tested according to Test Method D86.
1.3.1 The applicable Test Method D5769 range for total aromatics is 3.7 % to 29.4 % by volume as reported by Test Method
D5769 and the distillation temperature T values, at which 95 % of the sample has evaporated, when tested according to Test
95
Method D86 is from 149.1 °C to 196.6 °C (300.3 °F to 385.8 °F).
1.4 The applicability of this test method to products derived from fossil fuels other than petroleum, such as coal, shale, or tar
sands, has not been determined, and the precision statement may or may not apply to such products.
1.5 This test method has two precision statements depicted in tables. The first table is applicable to unleaded fuels that do not
contain oxygenated blending components. It may or may not apply to automotive gasolines containing lead antiknock mixtures.
The second table is applicable to oxygenate blended (for example, MTBE, ethanol) automotive spark ignition fuel samples with
a concentration range of 13–40 13 to 40 volume percent aromatics, 4–33 4 to 33 volume percent olefins, and 45–68 45 to 68
volume percent saturates.
1.6 The oxygenated blending components, methanol, ethanol, methyl-tert-butylether (MTBE), tert-amylmethylether (TAME),
and ethyl-tert-butylether (ETBE), do not interfere with the determination of hydrocarbon types at concentrations normally found
in commercial blends. These oxygenated components are not detected since they elute with the alcohol desorbent. Other
oxygenated compounds shall be individually verified. When samples containing oxygenated blending components are analyzed,
correct the results to a total-sample basis.
1.7 WARNING—Mercury has been designated by many regulatory agencies as a hazardous material that can cause central
nervous system, kidney and liver damage. Mercury, or its vapor, may be hazardous to health and corrosive to materials. Caution
should be taken when handling mercury and mercury containing products. See the applicable product Material Safety Data Sheet
(MSDS) for details and EPA’s website—http://www.epa.gov/mercury/faq.htm—for additional information. Users should be aware
that selling mercury and/or mercury containing products into your state or country may be prohibited by law.
1
This test method is under the jurisdiction of ASTM Committee D02 on Petroleum Products, Liquid Fuels, and Lubricants and is the direct responsibility of Subcommittee
D02.04.0C on Liquid Chromatograp
...
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