ASTM F316-03(2019)
(Test Method)Standard Test Methods for Pore Size Characteristics of Membrane Filters by Bubble Point and Mean Flow Pore Test
Standard Test Methods for Pore Size Characteristics of Membrane Filters by Bubble Point and Mean Flow Pore Test
SIGNIFICANCE AND USE
5.1 This test method may be used to:
5.1.1 Determine the maximum pore size of a filter,
5.1.2 Compare the maximum pore sizes of several filters, and
5.1.3 Determine the effect of various processes such as filtration, coating, or autoclaving on the maximum pore size of a membrane.
5.2 Membrane filters have discrete pores from one side to the other of the membrane, similar to capillary, tubes. The bubble point test is based on the principle that a wetting liquid is held in these capillary pores by capillary attraction and surface tension, and the minimum pressure required to force liquid from these pores is a function of pore diameter. The pressure at which a steady stream of bubbles appears in this test is the bubble point pressure. The bubble point test is significant not only for indicating maximum pore size, but may also indicate a damaged membrane, ineffective seals, or a system leak.
5.3 The results of this test method should not be used as the sole factor to describe the limiting size for retention of particulate contaminants from fluids. The effective pore size calculated from this test method is based on the premise of capillary pores having circular cross sections, and does not refer to actual particle size retention. See Test Method E128 for additional information.
SCOPE
1.1 These test methods cover the determination of two of the pore size properties of membrane filters with maximum pore sizes from 0.1 to 15.0 μm.
1.2 Test Method A presents a test method for measuring the maximum limiting pore diameter of nonfibrous membranes. The limiting diameter is the diameter of a circle having the same area as the smallest section of a given pore (Fig. 1).
FIG. 1 Examples of Limiting Diameters
1.3 Test Method B measures the relative abundance of a specified pore size in a membrane, defined in terms of the limiting diameter.
1.4 The analyst should be aware that adequate collaborative data for bias statements as required by Practice D2777 is not provided. See the precision and bias section for details.
1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
General Information
Relations
Standards Content (Sample)
This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the
Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
Designation: F316 − 03 (Reapproved 2019)
Standard Test Methods for
Pore Size Characteristics of Membrane Filters by Bubble
1
Point and Mean Flow Pore Test
ThisstandardisissuedunderthefixeddesignationF316;thenumberimmediatelyfollowingthedesignationindicatestheyearoforiginal
adoption or, in the case of revision, the year of last revision.Anumber in parentheses indicates the year of last reapproval.Asuperscript
epsilon (´) indicates an editorial change since the last revision or reapproval.
1. Scope D1193 Specification for Reagent Water
D2777 Practice for Determination of Precision and Bias of
1.1 These test methods cover the determination of two of
Applicable Test Methods of Committee D19 on Water
the pore size properties of membrane filters with maximum
E128 Test Method for Maximum Pore Diameter and Perme-
pore sizes from 0.1 to 15.0 µm.
ability of Rigid Porous Filters for Laboratory Use
1.2 Test MethodApresents a test method for measuring the
maximum limiting pore diameter of nonfibrous membranes.
3. Terminology
The limiting diameter is the diameter of a circle having the
3.1 Definitions:
same area as the smallest section of a given pore (Fig. 1).
3.1.1 For definitions of terms used in this standard, refer to
1.3 Test Method B measures the relative abundance of a
Terminology D1129.
specified pore size in a membrane, defined in terms of the
3.2 Definitions of Terms Specific to This Standard:
limiting diameter.
3.2.1 limiting pore diameter, n—diameter of a circle having
1.4 The analyst should be aware that adequate collaborative
the same area as the smallest section of a given pore.
data for bias statements as required by Practice D2777 is not
3.2.2 pore size, n—capillary equivalent pore diameter.
provided. See the precision and bias section for details.
1.5 The values stated in SI units are to be regarded as
TEST METHOD A—MAXIMUM PORE SIZE
standard. No other units of measurement are included in this
standard.
4. Summary of Test Method
1.6 This standard does not purport to address all of the
4.1 The bubble point test for maximum pore size is per-
safety concerns, if any, associated with its use. It is the
formed by prewetting the filter, increasing the pressure of gas
responsibility of the user of this standard to establish appro-
upstream of the filter at a predetermined rate and watching for
priate safety, health, and environmental practices and deter-
gas bubbles downstream to indicate the passage of gas through
mine the applicability of regulatory limitations prior to use.
the maximum diameter filter pores.
1.7 This international standard was developed in accor-
dance with internationally recognized principles on standard-
4.2 The pressure required to blow the first continuous
ization established in the Decision on Principles for the
bubbles detectable by their rise through a layer of liquid
Development of International Standards, Guides and Recom-
covering the filter is called the “bubble point,” and is used to
mendations issued by the World Trade Organization Technical
calculate maximum pore size.
Barriers to Trade (TBT) Committee.
5. Significance and Use
2. Referenced Documents
2 5.1 This test method may be used to:
2.1 ASTM Standards:
5.1.1 Determine the maximum pore size of a filter,
D1129 Terminology Relating to Water
5.1.2 Compare the maximum pore sizes of several filters,
and
1
These test methods are under the jurisdiction of ASTM Committee D19 on
5.1.3 Determine the effect of various processes such as
Water and are the direct responsibility of Subcommittee D19.08 on Membranes and
Ion Exchange Materials.
filtration, coating, or autoclaving on the maximum pore size of
Current edition approved Nov. 1, 2019. Published December 2019. Originally
a membrane.
approved in 1970. Last previous edition approved in 2011 as F316 – 03 (2011).
DOI: 10.1520/F0316-03R19.
5.2 Membrane filters have discrete pores from one side to
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
the other of the membrane, similar to capillary, tubes. The
contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
bubble point test is based on the principle that a wetting liquid
Standards volume information, refer to the standard’s Document Summary page on
the ASTM website. is held in these capillary pores by capillary attraction and
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F316 − 03 (2019)
6.3 Pressure Gauges (and mercury manometer if required),
covering the range of pressures needed for the pore sizes under
investigation (see Table 1).
6.4 Metal Punch, used to cut a su
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